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The laboratory characterization of a field-operable surface-enhanced Raman scattering sensor (SERS optode) is presented for the detection of aromatic hydrocarbons in seawater. The sensor has been developed for deployment with a robust underwater spectrograph. To meet the demands of the harsh seawater application, sol-gel derived SERS substrates were used. The calibration curves of six PAHs were determined to be of Langmuir adsorption isotherm type with limits of detection ranging from the microg l(-1) to ng l(-1) level. The experimentally determined adsorption constants varied strongly with the molecular weight of the analytes and correlated with their solubility. A mixture of five PAHs dissolved in seawater was investigated to demonstrate the utility of this method for screening. Emphasis was put on the interference from suspended particulate matter (SPM). The Raman measurement with backscattering configuration was shown to be immune against turbidities up to 1000 NTU. The physico-chemical interference arising from adsorption by the sediment was measured on-line by adding sediment to a PAH-spiked solution. According to the calibration curve, the PAH concentration decrease corresponded to more than 98% of the analyte being scavenged by the sediment.  相似文献   
2.
There is growing recognition of the importance of ecosystem-based approaches for adaptation to climate change—it is a cost-effective measure that has multiple benefits and can overcome many of the drawbacks of more common engineering adaptation options. Viet Nam has a rich biodiversity and is also one of the most vulnerable countries impacted by climate change. Climate change policies have been adopted at national and local levels as well as by sector, making Viet Nam one of the nations to most systematically fulfill their obligation under the United Nations Framework Convention on Climate Change. Consequently, we have used Viet Nam as a case study, to assess the integration of ecosystem-based approach to adaptation to climate change. We found that ecosystem-based adaptation is being implemented in some projects but, overall, is inadequately considered by Viet Nam’s climate change policies. Instead, policies predominantly rename infrastructure projects as climate change adaptation and focus on hard solutions for disaster reduction, rather than responding to long-term climate change through ecosystem-based adaptation. Moreover, ecosystem-based adaptation projects have focused on only a few relevant types of ecosystems. Viet Nam should revise its existing climate change policies and sectoral strategies to integrate ecosystem-based adaptation across different scales of governance. As other nations develop adaptation policies at different scales, the lesson from Viet Nam is that engineering measures need to be balanced with ecosystem-based adaptation for more affordable and effective responses to climate change.  相似文献   
3.
越南西北部莱州地区新生代煌斑岩地球化学特征及其成因   总被引:1,自引:1,他引:0  
越南西北部菜州地区出露的新生代煌斑岩岩脉对理解特提斯造山带东段的深部岩石圈特征和演化具有重要的地质意义.本文报道莱州地区煌斑岩的元素地球化学和Sr-Nd-Pb同位素组成特征,探讨其岩石成因.该地区煌斑岩属于钙碱性,钾质-超钾质煌斑岩特征.地球化学特征对比表明,菜州地区煌斑岩与哀牢山断裂带碱性岩具有相似的地球化学特征,但与海南和越南南部火山岩存在明显差异.分析结果表明,煌斑岩具有高的87Sr/86Sr比值、低143Nd/144Nd比值和高放射性成因Pb同位素组成特征.岩石的微量元素组成特征指示,形成煌斑岩的地幔源区可能经历过流体交代作用或沉积物组分的加入.低208Pb*/206Pb*比值暗示地幔源区富集事件是近期发生的,可能与晚古生代-早中生代印支地块向扬子地块俯冲事件有关.  相似文献   
4.
Total organic carbon fluxes of the Red River system (Vietnam)   总被引:1,自引:0,他引:1       下载免费PDF全文
Riverine transport of organic carbon from terrestrial ecosystems to the oceans plays an important role in the global carbon cycle. The Red River is located in Southeast Asia where river discharge, sediment loads and fluxes of elements (carbon, nitrogen and phosphorus) associated with suspended solids have been dramatically altered over past decades as a result of reservoir impoundment and land use, population, and climate change. Dissolved organic carbon (DOC) and particulate organic carbon (POC) concentrations were measured monthly at four stations of the Red River system from January 2008 to December 2010. The results reveal that POC changed synchronically with total suspended solids (TSS) concentration and with the river discharge, whereas no clear trend was observed for DOC concentration. The mean value of total organic carbon (TOC = DOC + POC) flux in the delta of the Red River was 31.5 × 1013 ± 4.0 × 1013 MgC.yr?1 (range 27.9–35.8 × 1013 MgC.yr?1 which leads to a specific TOC flux of 2012 ± 255 kgC.km?2.yr?1 during this 2008–2010 period. About 80% of the TOC flux was transferred to the estuary during the rainy season as a consequence of the higher river water discharge. The high mean value of the POC:Chl‐a ratio (1585 ± 870 mgC.mgChl‐a?1) and the moderate C:N ratio (7.3 ± 0.1) in the water column system suggest that organic carbon in the Red River system is mainly derived from erosion and soil leaching in the basin. The effect of two new dam impoundments in the Red River was also observable with lower TOC fluxes in 2010 compared with 2008. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   
5.
Skolotnev  S. G.  Sanfilippo  A.  Peyve  A. A.  Muccini  F.  Sokolov  S. Yu.  Sani  C.  Dobroliubova  K. O.  Ferrando  C.  Chamov  N. P.  Pertsev  A. N.  Gryaznova  A. S.  Sholukhov  K. N.  Bich  A. S. 《Doklady Earth Sciences》2020,491(1):131-134
Doklady Earth Sciences - The geological and geophysical data acquired during cruise 45 of R/V Akademik Nikolaj Strakhov regarding the structure of the Doldrums megatransform system in the Central...  相似文献   
6.
Doklady Earth Sciences - New data on the morphology, chemical composition, and age of the ferromanganese crusts of the Doldrums Fracture Zone, Central Atlantic, collected during the 45th cruise of...  相似文献   
7.
Skolotnev  S. G.  Sanfilippo  A.  Peyve  A. A.  Nestola  Y.  Sokolov  S. Yu.  Petracchini  L.  Dobrolybova  K. O.  Basch  V.  Pertsev  A. N.  Ferrando  C.  Ivanenko  A. N.  Sani  C.  Razumovskii  A. A.  Muccini  F.  Bich  A. S.  Palmiotto  C.  Brusilovsky  Y. V.  Bonatti  E.  Sholukhov  K. N.  Cuffaro  M.  Veklich  I. A.  Ligi  M.  Dobrolybov  V. N. 《Doklady Earth Sciences》2021,497(1):191-194
Doklady Earth Sciences - The geological and geophysical data obtained during the 50th cruise of R/V Akademik Nikolaj Strakhov on the Charlie Gibbs megatransform system structure...  相似文献   
8.
Ivanova  E. V.  Skolotnev  S. G.  Borisov  D. G.  Demidov  A. N.  Bich  A. S.  Gippius  F. N.  Gryaznova  A. S.  Dobroliubova  K. O.  Zinger  T. F.  Korshunov  D. M.  Levchenko  O. V.  Mashura  V. V.  Muccini  F.  Nemchenko  N. V.  Peyve  A. A.  Pertsev  A. N.  Sani  K.  Sanfilippo  A.  Simagin  N. V.  Sokolov  S. Yu.  Ferrando  C.  Chamov  N. P.  Shakhovskoy  I. B.  Sholukhov  K. N. 《Oceanology》2020,60(3):424-426
Oceanology - Herein we provide information on the integrated geological, geophysical, sedimentological, paleoceanographic, hydrophysical and biological investigations in the Central Atlantic during...  相似文献   
9.
Potential evapotranspiration (ETP) is an important part of a climatic water balance and a crucial variable in many kinds of models in computing actual evapotranspiration. The objective of this study was to find a reasonable approach of ETP calculation for a height‐differentiated landscape in subtropical climate. From the pool of diverse approaches, six common methods [Hamon, Priestley–Taylor, Thornthwaite, Blaney–Criddle, Turc and Food and Agricultural Organization Irrigation and Drainage Paper No. 56 (FAO‐56)] were selected. With the meteorological data for long‐term period (1964–2008), the calculation of ETP values was performed for 12 different meteorological stations in the Red River basin. Among the applied ETP calculation methods, the Turc and the FAO‐56 methods agreed well at most stations and represent best the expectations for the ETP values of the Thao and Da subbasins. The findings of our investigations indicate that in highly structured (land use and elevation) regions, not all methods provide satisfying results. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
10.
The Dalat zone in southern Vietnam comprises a Cretaceous Andean-type magmatic arc with voluminous granitoids and contemporary volcanic rocks. On the basis of petrographical and mineralogical studies, the granitoids were subdivided into three suites: Dinhquan, Deoca and Cana. Rocks of the Dinhquan suite are hornblende–biotite diorites, granodiorites and minor granites. The Cana suite encompasses mainly leucocratic biotite-bearing granites with scarce hornblende. The Deoca suite is made up of granodiorites, monzogranites and granites. Geochemically, the granitoids are of subalkaline affinity, belong to the high-K, calc-alkaline series, and most of them display typical features of I-type granites. This paper presents the new Rb–Sr mineral and U–Pb zircon and titanite age data for the granitoids, which establish the ages of the plutonic suites as: the Dinhquan at ~112–100 Ma, Cana at ~96–93 Ma and Deoca at ~92–88 Ma. These ages are significantly different from earlier publications, and indicate that the earliest magmatism in the Dalat zone began at ~112 Ma ago, that is ~30–50 Ma later than previously thought. Our geochronological data are also support the continuation of an Andean-type arc running from SE China via southern Vietnam to SW Borneo.  相似文献   
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