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北京市有机氯农药填图与风险评价 总被引：2，自引：0，他引：2
采用1个样/km2的密度、1个分析组合样/16km2的方法,对北京市784km2范围内的土壤、大气干湿沉降物、大气颗粒物中HCH、DDT的含量和空间分布特征进行有机氯农药填图.查明2000年北京市地表土壤HCH和DDT的平均含量分别为8.80±11.83ng/g、108.99±301.90ng/g.2006年大气干湿沉降物中HCH和DDT平均含量分别为10.09±9.60ng/g、12.99±13.51ng/g,HCH和DDT的年沉降通量分别为996.57±939.96g/a·km2、1291.53±1342.28g/a·km2.2006年大气颗粒物PM10和PM2.5中的HCH含量分别为0.294±0.205ng/m3和0.217±0.137ng/m3,DDT的平均含量分别为1.037±1.301ng/m3和0.522±0.773ng/m3,显著高于2002-2003年度大气颗粒物中HCH(PM100.01786ng/m3,PM250.01731ng/m3)和DDT(PM100.01672ng/m3,PM2.50.02353ng/m3)的含量,表明北京市或周边地区仍在使用含HCH和DDT化学成分的农药.以2000年北京地表土壤和2006年大气干湿沉降物中HCH和DDT的含量为基础,对2020年土壤中HCH和DDT的时空演变的预测显示,即使干湿沉降物中HCH和DDT的沉降通量每年以5%的速率递减,到2020年土壤中HCH和DDT的环境质量仍不能显著改善,而控制和削减北京及周边地区含HCH和DDT成分农药的使用将是改善北京地表土壤环境质量的关键措施. 相似文献
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作物对土壤中重金属的吸收受作物种类、采集部位及土壤理化性质等多方面因素的影响。近年来,金衢盆地土壤酸化面积逐年增大,酸化程度逐渐加深,其对土壤-作物系统中重金属元素的活动影响尚不明确。本文基于金衢盆地典型地区264组根系土壤-稻米样品分析数据,开展土壤、作物的重金属含量特征及其影响因素的研究,重点讨论了土壤pH对作物吸收重金属的影响。结果表明：①264件土壤中多数重金属元素的变异系数大于0.5,As、Cd、Cr、Cu、Ni和Zn元素之间呈显著正相关（P<0.01）。土壤Cd超标样品23件,超标率为8.7%;As、Cr、Cu、Hg、Ni、Pb和Zn超标样品均未超过2件。②稻米中Cu、Zn与Cd含量呈显著正相关,Cd的富集系数（BCF）高于植物营养元素Cu、Zn。③稻米中Zn和Cu在P<0.1水平上与pH值呈显著正相关。Cd、Cr、Hg的BCF与pH值之间存在一定的负相关性。研究认为,适当调低土壤的酸碱度会削减土壤中Cd、Hg等重金属元素的活性,从而减少农作物对重金属的吸收转运。研究结果可为当地粮食安全生产决策提供科学数据,为土地管护提供参考依据。 相似文献
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干旱戈壁荒漠区地处我国西北部地区,天山、北山、祁连山三大多金属成矿带横贯其中,成矿条件优越,找矿尤其是找隐伏矿的潜力巨大,但受风成砂土的影响,很难获知覆盖层下方的矿化信息.穿透性地球化学已被证实是有效寻找隐伏矿的方法,其被定义为能探测深部隐伏矿体发出的直接信息的勘查地球化学理论与方法技术.笔者在花牛山铅锌矿开展土壤微细粒全量测量、金属活动态测量(水溶态测量、黏土吸附态测量、铁锰氧化物态测量)和地电化学测量多种穿透性地球化学勘查方法实测工作,结果表明,5种测量方法分析数据主成矿元素(铅、锌)异常衬度高,变异系数大,富集成矿可能性大,地球化学异常与深部隐伏矿体位置吻合,相比较而言,土壤微细粒全量测量效果最好,黏土吸附态测量、铁锰氧化物态测量和地电化学测量效果较好,水溶态测量效果稍差;所选方法技术针对干旱戈壁荒漠区寻找隐伏铅锌矿是有效的.气固介质中内生条件下的纳米金属微粒的发现为利用土壤作为采样介质的穿透性地球化学方法技术(土壤微细粒测量、金属活动态测量)提供了理论基础.电提取泡塑载体中大量的微米级的黏土矿物颗粒发现,以及微量元素异常与铁、铝等常量元素异常高度一致,初步推断地电化学测量提取过程是对黏土矿物颗粒选择性吸附过程. 相似文献
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额尔齐斯河流域及某稀有多金属矿废水铀、钍含量分布及其环境影响 总被引：5，自引：0，他引：5
运用简易、快捷、灵敏的ICP-MS法直接测定稀有多金属矿以及河水样品中的铀钍含量,并推算其与比放射性活度之间的定量关系,客观评价了某稀有多金属矿废水中的放射性水平以及额尔齐斯河流域的放射性污染现状。研究表明,某稀有多金属选矿废水铀含量可达78．311μg/L,钍含量达0．627μg/L。额尔齐斯河流域各支流河水铀、钍平均含量分别为0．584μg/L、0．025μg/L,其干流河水钍平均含量为0．019μg/L,而铀平均含量达2．234μg/L,远高于世界河水铀平均含量0．309μg/L。 相似文献
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柴达木盆地西部北区E13地层普遍发育了很好的碎屑岩,储层物性与成岩作用密切相关.为了认清柴西北区E13有利储层的分布规律,在岩心观察、显微分析和各种分析化验的基础上,划分了本区成岩作用序列,并通过热力学分析进一步研究了成岩作用的控制因素.研究发现,本区主要存在四次较大规模的成岩作用,第一次是白云石胶结及交代作用,第二次是方解石的胶结与交代作用,第三次是胶结物的溶解,第四次是晚期硬石膏的胶结及交代作用,而油气充注发生在溶解作用之后硬石膏胶结作用之前.另外,压实和压溶作用贯穿整个成岩作用过程.各种成岩作用都是在一定的热力学体系下进行的,通过细致的热力学推导,绘制出包含方解石、白云石和硬石膏等矿物相在内的五组分相图,从而得到了成岩环境的地球化学特征. 相似文献
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The coupled hull, mooring and riser analysis techniques in time domain are widely recognized as the unique approach to predict the accurate global motions. However, these complex issues have not been perfectly solved due to a large number of nonlinear factors, e.g. forces nonlinearity, mooring nonlinearity, motion nonlinearity and so on. This paper investigates the coupled effects through the numerical uncoupled model, mooring coupled model and fully coupled model accounting mooring and risers based on a novel deep draft multi-spar which is especially designed for deepwater in 2009. The numerical static-offset, free-decay, wind-action tests are executed, and finally three hours simulations are conducted under 100-year return period of GOM conditions involving wave, wind and current actions. The damping contributions, response characteristics and mooring line tensions are emphatically studied. 相似文献
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应用FTIR-XRD-XRF分析测试技术研究新型仿制绿松石的矿物学特征 总被引：4，自引：3，他引：1
近年来绿松石及其仿制品的鉴定工作较多局限于应用傅里叶变换红外光谱对仿制品进行简单的筛选,前人报道的仿制绿松石的矿物组成主要为单一的矿物相(如异极矿、三水铝石、磷铝石、羟硅硼钙石、菱镁矿等)。本文应用傅里叶变换红外光谱(FTIR)、X射线粉晶衍射(XRD)与X射线荧光光谱(XRF)对当前珠宝市场上几种新型仿制绿松石进行了初步分类,并对不同类别的仿制绿松石的具体矿物组成、物相及晶型特征作了对比研究。结果表明,这些新型仿制绿松石可分为三大类:一类主要由硅酸盐(斜硅钙石)与碳酸盐(方解石)两种矿物组成;另一类为白云石与方解石两种碳酸盐矿物的混合相;第三类以硅酸盐类为主要矿物,并含有钡长石、辉石与石英。显然,新型仿制绿松石的矿物组成明显相异于传统仿制品,可见仿制绿松石的矿物组成日趋多样性、复杂化,该现状必然对新型仿制样品的物相鉴定提出了更高的要求。 相似文献
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为了进一步印证以往观测反推得到的广东地区雷暴云多偶极性电荷结构的结论,利用加入了起放电参数化方案的WRF模式,模拟了广东在2017年5月8日发生的一次飑线过程,并对这次飑线过程中一个雷暴单体成熟期的电荷结构演变特征进行分析,通过分析动力、云水含量、各水成物粒子混合比及携带电荷情况,讨论了电荷结构的形成及演变机制。结果表明,成熟阶段的单体,电荷结构从三极性逐渐演变为偶极性。这是因为在成熟初期,霰粒子在有效液态水含量适中且温度较高的地方与冰晶/雪花粒子发生了非感应碰撞,因此底部霰粒子携带正电,雷暴云底部形成次正电荷区,电荷结构为三极性。而在成熟后期,由于丰富的云水含量,使冰粒子的凇附过程增强,霰不断增加,冰晶和雪花不断被消耗,温度较暖区域与霰共存的冰晶和雪花急剧减少,使得该区域大小冰粒子的非感应碰撞起电急剧减少,此处霰粒子不能再通过非感应碰撞获得正电荷,底部次正电荷区随之消失,雷暴云的电荷结构转变为偶极性。此结果和以往观测反推得到的结论不同,这表明,对南方雷暴电荷结构还需继续深入认识。 相似文献
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XU Bin-bin ZHANG Dong-li ZHANG Pei-zhen ZHENG Wen-jun BI Hai-yun TIAN Qing-ying ZHANG Yi-peng XIONG Jian-guo LI Zhi-gang 《地震地质》2019,41(3):587-602
Slip rate is one of the most important parameters in quantitative research of active faults. It is an average rate of fault dislocation during a particular period, which can reflect the strain energy accumulation rate of a fault. Thus it is often directly used in the evaluation of seismic hazard. Tectonic activities significantly influence regional geomorphic characteristics. Therefore, river evolution characteristics can be used to study tectonic activities characteristics, which is a relatively reliable method to determine slip rate of fault. Based on the study of the river geomorphology evolution process model and considering the influence of topographic and geomorphic factors, this paper established the river terrace dislocation model and put forward that the accurate measurement of the displacement caused by the fault should focus on the erosion of the terrace caused by river migration under the influence of topography. Through the analysis of the different cases in detail, it was found that the evolution of rivers is often affected by the topography, and rivers tend to migrate to the lower side of the terrain and erode the terraces on this side. However, terraces on the higher side of the terrain can usually be preserved, and the displacement caused by faulting can be accumulated relatively completely. Though it is reliable to calculate the slip rate of faults through the terrace dislocation on this side, a detailed analysis should be carried out in the field in order to select the appropriate terraces to measure the displacement under the comprehensive effects of topography, landform and other factors, if the terraces on both sides of the river are preserved. In order to obtain the results more objectively, we used Monte Carlo method to estimate the fault displacement and displacement error range. We used the linear equation to fit the position of terrace scarps and faults, and then calculate the terrace displacement. After 100, 000 times of simulation, the fault displacement and its error range could be obtained with 95%confidence interval. We selected the Gaoyan River in the eastern Altyn Tagh Fault as the research object, and used the unmanned air vehicle aerial photography technology to obtain the high-resolution DEM of this area. Based on the terrace evolution model proposed in this paper, we analyzed the terrace evolution with the detailed interpretation of the topography and landform of the DEM, and inferred that the right bank of the river was higher than the left bank, which led to the continuous erosion of the river to the left bank, while the terraces on the right bank were preserved. In addition, four stages of fault displacements and their error ranges were obtained by Monte Carlo method. By integrating the dating results of previous researches in this area, we got the fault slip rate of(1.80±0.51)mm/a. After comparing this result with the slip rates of each section of Altyn Tagh Fault studied by predecessors, it was found that the slip rate obtained in this paper is in line with the variation trend of the slip rate summarized by predecessors, namely, the slip rate gradually decreases from west to east, from 10~12mm/a in the middle section to about 2mm/a at the end. 相似文献