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Gordana Pavlovic Delko Barisic Ivanka Lovrencic Visnja Orescanin Esad Prohic 《Environmental Geology》2005,47(4):475-481
This paper attempts to determine the impact of former Pb-Zn-Ba mining activities in Slovenian drainage basin on overbank sediments of the Sava river (West Croatia). Among the four studied sequences (S7, S8, S9, S10), the most upstream profile S7 showed the most pronounced impact of ore mining. Mercury was enriched more than 100-fold; Pb and Zn had a strong positive correlation (r > 0.99). Two factor models clearly revealed the Pb-Ba-Hg association in the lower-lying carbonate (CA) population of all four profiles, but only in the overlying silicate (SI) population of profile S7. Factor analysis confirmed this association in the total sediment (90 samples) as well as separately in the CA (33 samples) and SI (57 samples) populations. Based on a comparison with an undisturbed soil profile, the vertical distribution of 137Cs in profile S7 was interpreted to be the combination of caesium deposition caused by a flood in 1964 and by post-depositional redistribution. 相似文献
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Sediments of the Krka River Estuary on the eastern Adriatic coast have been analysed for trace metals after sediment fractionation by sequential leaching. Trace concentrations of Mn, Cu, Pb, Zn, Ni, Co, Cr, V and Ga have been determined by atomic emission spectroscopy. The distribution patterns of the investigated elements follow the expected geochemical partitionings, while minor variations may be caused by early diagenetic effects and variable sediment texture. Taking into account the natural background levels of the investigated elements, the sediments reflect, at present, no significant industrial pollution or anthropogenic input of trace metals into the estuary. 相似文献
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This paper examines disposal of metals and the origin, characteristics, and distribution of sedimentary organic matter (SOM) in a Mediterranean karstic estuary in the north-eastern Adriatic. This environment offers a real-time, small model system for studies of geochemical processes in microtidal Mediterranean estuaries that are infilling with sediments and classified as river-dominated disequilibrium estuaries. The results have shown that the longitudinal distribution of heavy metals in sediments follows the sedimentation dynamics and deposition pattern of river-borne, clay mineral particles. The highest concentration of metals was found in the restricted upper part of the estuary, characterized by rapid deposition of clay particles and terrestrial sedimentary organic matter, and decreases toward the open sea. The vertical distribution of metals in sediment cores depends on the prevailing pH and Eh conditions. Significant increases of the concentrations of metals in the uppermost strata are the result of recent anthropogenic inputs. The share of the terrestrial component in SOM, estimated by N/Corg atomic ratios and δ13C values, decreases with distance from the river mouth. The small vertical variation in δ13C values of SOM indicates that a fast sedimentation rate overrides the diagenetically determined decomposition. The results obtained indicate that river-borne inorganic particles, natural terrigenous organic material, and anthropogenic metal loads are trapped in sediments of the estuarine system. Under the prevailing conditions, there is negligible transport towards the open sea. 相似文献
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Dynamic flow systems and transport of contaminants in karstic aquifers result from the actions of physical and chemical processes involving aqueous systems containing certain contaminants. These processes are elaborated, and pertinent mathematical and chemical equations are discussed, herein. Contaminant transport in karstic aquifers can be mathematically expressed by the basic equations evaluated primarily for the flow in porous, highly permeable aquifers. The effects of advection, hydrodynamic dispersion, and dilution are elaborated as physical processes that effect the movement of contaminants through groundwater in permeable rocks. Physical and chemical mechanisms that govem contaminant movement and groundwater flow through fractured media are proposed as the basis of an approximate scenario of contaminant transport through karstified carbonate rocks. 相似文献
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Factors that govern heavy metal concentration in sediments were examined by a combined analytical, geochemical, and geological approach. The constrains encountered in the determination of the anthropogenic influence are exposed. The region examined was the Krka River estuary located in the typical karst region of the eastern Adriatic, Yugoslavia.Sedimentological research revealed that: the Krka River (main water supplier) is almost free of suspended terrigenous material; the main supplier of suspended terrigenous matter of flysch origin is a small torrent-type Gudua Creek, and that this fine grained terrigenous material is sedimented mostly in the central enlarged part of the estuary, the Prokljan Lake.Three different groups of heavy metals were identified in recent sediments. Increased concentrations of nickel and zinc were found in estuarine sediments due to strongnatural enrichment in source rocks. Manganese and chromium were found to benaturally enriched and depleted in surface layer respectively, due to the different postdepositional geochemical behavior. Lead and copper concentrations were found to be increased in surface sediments in the central part of the estuary, apparently from anthropogenic source. 相似文献
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Four overbank profiles from the three terraces of different age were sampled in 10 to 20 cm intervals for the bulk content of major and minor (Ca, Mg, Fe, Ti, Al, Na, K and P) and trace (Mo, Cu, Pb, Zn, Ni, Co, Mn, As, U, Th, Sr, Cd, Sb, V, La, Cr, Ba, W, Zr, Ce, Sn, Y, Nb, Ta, Sc, Li, Rb and Hf) elements in the minus 0.125 mm fraction. Univariate statistics together with analysis of variance discriminated between the lower-lying carbonate (CA) population dominantly composed of carbonates and the overlying silicate (SI) population being dominantly of silicate mineralogy. This stratified pattern resulted from the intensive erosive action of melting glaciers exerted on limestones and dolomites in the alpine region, followed by local inputs mainly of silicate composition. Elements exhibiting the greatest between-population variability are Ca and Mg being enriched in the CA population and Fe, Mn, P, Sr, Al, Na, K, Li, Rb, Y, Zr, Ni, Cr and Ti being enriched in the SI population. Anomalously high Hg, Pb and Ba concentrations (maximum values: 6,500±2,860 ppb, 225±13 ppm and 1,519±91 ppm, respectively) in the lowermost part of the profile S7, which is nearest to the Croatian-Slovenian border, derive from the mineralized Slovenian catchment area. This profile also contains trimodal frequency distributions of Fe, Mn and P whose highest concentrations coincide with increased values of Zn and Cu which are bimodally distributed. Geochemical patterns of majority of elements in all four profiles consistently reflect the average compositions of the upstream drainage basins. 相似文献
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