The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage. 相似文献
Long-term measurement of carbon metabolism of old-growth forests is critical to predict their behaviors and to reduce the uncertainties of carbon accounting under changing climate. Eddy covariance technology was applied to investigate the long-term carbon exchange over a 200 year-old Chinese broad-leaved Korean pine mixed forest in the Changbai Mountains (128°28′E and 42°24′N, Jilin Province, P. R. China) since August 2002. On the data obtained with open-path eddy covariance system and CO2 profile measurement system from Jan. 2003 to Dec. 2004, this paper reports (i) annual and seasonal variation of FNEE, FGPP and RE; (ii) regulation of environmental factors on phase and amplitude of ecosystem CO2 uptake and release Corrections due to storage and friction velocity were applied to the eddy carbon flux.
LAI and soil temperature determined the seasonal and annual dynamics of FGPP and RE separately. VPD and air temperature regulated ecosystem photosynthesis at finer scales in growing seasons. Water condition at the root zone exerted a significant influence on ecosystem maintenance carbon metabolism of this forest in winter.
The forest was a net sink of atmospheric CO2 and sequestered −449 g C·m−2 during the study period; −278 and −171 gC·m−2 for 2003 and 2004 respectively. FGPP and FRE over 2003 and 2004 were −1332, −1294 g C·m−2. and 1054, 1124 g C·m−2 respectively. This study shows that old-growth forest can be a strong net carbon sink of atmospheric CO2.
There was significant seasonal and annual variation in carbon metabolism. In winter, there was weak photosynthesis while the ecosystem emitted CO2. Carbon exchanges were active in spring and fall but contributed little to carbon sequestration on an annual scale. The summer is the most significant season as far as ecosystem carbon balance is concerned. The 90 days of summer contributed 66.9, 68.9% of FGPP, and 60.4, 62.1% of RE of the entire year.
IntroductionThe area of eastern Liaoning is an importantmetal and nonmetal metallogenetic district in China,and the Liaohe group is one of the most importantstrata that hosts Pb, Zn, Au, B and Mg etcstratabound deposits. Up to now many geo1ogistssuch as Z… 相似文献
As regards the eddies occurring in the origination region of the Kuroshio (west of 130° E), the earliest informations were reported by R. Shigematsu (1932) and K. Koenuma (1936) respectively. From the data observed in the twenties, they pointed out that there was a warm eddy located to the right side of the Kuroshio in the Luzon Strait. Using the data obtained from the fourties through the sixties, Nitani further convinced the existence of the warm eddy. During the latest two decades, observations of the area south of the Nansei Islands on board of R/V Chofu Maru (1965, '66, '67) and Hakuho Maru (1974, '75) also revealed the existence of warm and cold eddies, but few works on "eddies" are reported, so far as we know. 相似文献
The Asian monsoon is an important component of the global climate system. Seasonal variations in wind, rainfall, and temperature associated with the Asian monsoon systems affect a vast expanse of tropical and subtropical Asia. Speleothem-derived summer monsoon variation in East Asia was previously found to be closely associated with millennial-scale change in temperature in the North Atlantic region between 75 and 10 ka. New evidence recovered from East Asia, however, suggests that the teleconnection between summer monsoon in East Asia and temperature change in the North Atlantic region may have significantly reduced during 120 to ~ 110 ka, a period directly after the full last interglaciation and corresponding roughly to marine oxygen isotope stage 5d. This reduction may be due to the low ice volume in the North Hemisphere at that time, which makes the millennial-scale change in temperature in the North Atlantic region less effective in influencing the Asian summer monsoon. This is important for investigating the mechanisms controlling the Asian summer monsoon and the paleoclimatic teleconnection between East Asia and the North Atlantic region, and for predicting monsoon-associated precipitation in East Asia under a global-warming trend. 相似文献
