The reliability of analytical data for tributyltin (TBT) in sea water and its implications on water quality criteria     

James W. Readman  Laurence D. Mee 《Marine environmental research》1991,32(1-4)

To investigate the reliability of analytical data for tributyltin (TBT) in sea water, split water samples were distributed to ten laboratories in six countries. The sub-surface samples comprised: (i) an offshore (0·5 km) water sample, (ii) the same sample but spiked with an undisclosed quantity of TBT standard compound (175 ng TBT⁺ liter⁻¹), and (iii) a sample taken from a yacht marina. The seven acceptable data sets were in good agreement for the spiked sample (178 ± 26 ng TBT⁺ liter⁻¹) but showed a greater variation in concentrations reported for the yacht marina sample (366 ± 93 ng TBT⁺ liter⁻¹). Atomic absorption and gas chromatographic-flame photometric detection techniques produced results of similar accuracy and precision. Samples acidified with 1 ml of 10% (v/v) acetic acid appeared stable for more than 2 weeks when stored refrigerated and in darkness. Analyses of the offshore seawater sample revealed TBT contamination (9 ± 7 ng TBT⁺ liter⁻¹) indicating dispersion of the compound to the shelf waters off Monaco. The spread in values reported by the laboratories demonstrates inherent difficulties in obtaining good precision below approximately 20 ng TBT⁺ liter⁻¹. This observation is discussed with respect to the setting and enforcing of water quality standards.  相似文献   

The origin and biogeochemistry of organic matter in surface sediments of Lake Shihwa and Lake Hwaong     

Eun -Ji Won  Hyen -Goo Cho  Kyung -Hoon Shin 《Ocean Science Journal》2007,42(4):223-230

To understand the origin and biogeochemistry of the organic matter in surface sediments of Lake Shihwa and Lake Hwaong, organic nitrogen, inorganic nitrogen, labile organic carbon, and residual organic carbon contents as well as stable isotope ratios for carbon and nitrogen were determined by KOBr-KOH treatment. Ratios of organic carbon to organic nitrogen (C_org/N_org) (mean = 24) were much higher than ratios of organic carbon to total nitrogen (C_org/N_tot) (mean=12), indicating the presence of significant amounts of inorganic nitrogen in the surface sediments of both lakes. Stable isotope ratios for organic nitrogen were, on average, 5.2‰ heavier than ratios of inorganic nitrogen in Lake Shihwa, but those same ratios were comparable in Lake Hwaong. This might be due to differences in the origin or the degree of degradation of sedimentary organic matter between the two lakes. In addition, stable isotope ratios for labile organic carbon were, on average, 1.4‰ heavier than those for residual organic carbon, reflecting the preferential oxidation of¹³C-enriched organic matter. The present study demonstrates that KOBr-KOH treatment of sedimentary organic matter can provide valuable information for understanding the origin and degradation state of organic matter in marine and brackish sediments. This also suggests that the ratio of C_org/N_org and stable isotope ratios for organic nitrogen can be used as indexes of the degree of degradation of organic matter.  相似文献   

Hydrometallurgical processing and recovery of molybdenum trioxide from spent catalyst   总被引：5，自引：0，他引：5  

Kyung Ho Park  B. Ramachandra Reddy  D. Mohapatra  Chul-Woo Nam 《International Journal of Mineral Processing》2006,80(2-4):261-265

Hydrometallurgical processing of spent hydrodesulphurisation (HDS) catalyst for the recovery of molybdenum using sodium carbonate and hydrogen peroxide mixtures was investigated. The results indicated that the recovery of molybdenum was largely dependent on the concentrations of Na₂CO₃ and H₂O₂ in the reaction medium, which controls the acidity of the leach liquor and carry over of impurities such as Al, Ni, P, Si and V. Leaching process was exothermic and leaching efficiency of molybdenum decreased with increasing solid to liquid ratio. Large scale leaching of spent catalyst, under optimum conditions: 20% pulp density, 85 g/L Na₂CO₃, 10 vol.% H₂O₂ and 1 h reaction, resulted a leaching efficiency of 84% Mo. The obtained leach liquor contained (g/L): Mo — 22.0, Ni — 0.015 and Al — 0.82, P — 1.1, Si — 0.094 and minor quantities of V — 8 mg/L, As and Co — < 1 mg/L. Recovery of Mo from leach solution as MoO₃ of 97.30% purity was achieved by ammonium molybdate precipitation method.  相似文献   

Yeosu dinosaur track sites of Korea: The youngest dinosaur track records in Asia     

In Sung Paik  Min Huh  Kye Hun Park  Koo Geun Hwang  Kyung Sik Kim  Hyun Joo Kim 《Journal of Asian Earth Sciences》2006,28(4-6):457-468

Eighty two dinosaur trackways were newly discovered in Upper Cretaceous lacustrine deposits on islands in the vicinity of Yeosu, Korea. Most dinosaur tracks occur in marginal lake deposits with polygonal desiccation cracks. The dinosaur tracks at the Yeosu site include 65 ornithopod trackways, 16 theropod trackways and one sauropod trackway. The prevalence of ornithopod tracks and the limited occurrence of sauropod tracks at the Yeosu site evidently reflect decreased sauropod diversity in the Upper Cretaceous. All ornithopod trackways represent bipeds, and most of the ornithopod tracks are similar to Caririchnium from other sites of the Korean peninsula. All fossil wood specimens collected in the study area represent conifers (three species of cupressaceous and two species of taxodiaceous conifers, and a new species) except for one, which is a discotyledon. It is thus inferred that the southwestern part of the Korean Peninsula was primarily covered with mesic forests with taxodiaceous trees during the Late Cretaceous. The K–Ar age of the Yeosu tracksite is determined as 81–65 Ma (Camapnian to Maastrichtian). It indicates that the Yeosu track site contains the last records of dinosaurs living in Asia. Consequently, semi-arid palaeoclimatic conditions, together with a large lake as a persistent water source and rich vegetation of gymnosperm trees as food, resulted in the preservation of abundant dinosaur tracks in the Upper Cretaceous on the Korean Peninsula.  相似文献   

Seismic analysis of base-isolated liquid storage tanks using the BE–FE–BE coupling technique     

Moon Kyum Kim  Yun Mook Lim  Seong Yong Cho  Kyung Hwan Cho  Kang Won Lee 《Soil Dynamics and Earthquake Engineering》2002,22(9-12):1151-1158

A three-dimensional soil–structure–liquid interaction problem is numerically simulated in order to analyze the dynamic behavior of a base-isolated liquid storage tank subjected to seismic ground motion. A dynamic analysis of a liquid storage tank is carried out using a hybrid formulation, which combines the finite shell elements for structures and the boundary elements for liquid and soil. The system is composed of three parts: the liquid–structure interaction part, the soil–foundation interaction part, and the base-isolation part. In the liquid–structure interaction part, the tank structure is modeled using the finite elements and the liquid is modeled using the internal boundary elements, which satisfy the free surface boundary condition. In the soil–foundation interaction part, the foundation is modeled using the finite elements and the half-space soil media are modeled using the external boundary elements, which satisfy the radiation condition in the infinite domain. Finally, above two parts are connected with the base-isolation system to solve the system's behavior. Numerical examples are presented to demonstrate the accuracy of the developed method, and an earthquake response analysis is carried out to demonstrate the applicability of the developed technique. The properties of a real LNG tank located in the west coast of Korea are used. The effects of the ground and the base-isolation system on the behavior of the tank are analyzed.  相似文献   

Optimal design of viscoelastic dampers using eigenvalue assignment   总被引：1，自引：0，他引：1  

Sang‐Hyun Lee  Dong‐In Son  Jinkoo Kim  Kyung‐Won Min 《地震工程与结构动力学》2004,33(4):521-542

In this study a procedure for determining the optimum size and location of viscoelastic dampers is proposed using the eigenvalue assignment technique. Natural frequencies and modal damping ratios, required to realize a given target response, are determined first by the convex model. Then the desired dynamic structural properties are realized by optimally distributing the damping and stiffness coefficients of viscoelastic dampers using non‐linear programming based on the gradient of eigenvalues. This optimization method provides information on the optimal location as well as the magnitude of the damper parameters. The proposed procedure is applied to the retrofit of a 10‐story shear frame, and to a three‐dimensional structure with an asymmetric plan. The analysis results confirm that the responses of model structures retrofitted by the proposed method correspond well with the given target response. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Probabilistic approach for active control of structures: experimental verification     

Jae‐Seung Hwang  Kyung‐Won Min  Sang‐Hyun Lee  Hongjin Kim 《地震工程与结构动力学》2005,34(3):207-225

In our previous study (Earthquake Engineering and Structural Dynamics 2003; 32 :2301), we have developed a probabilistic algorithm for active control of structures. In the probabilistic control algorithm, the control force is determined by the probability that the structural energy exceeds a specified target critical energy, and the direction of a control force is determined by the Lyapunov controller design method. In this paper, an experimental verification of the proposed probabilistic control algorithm is presented. A three‐story test structure equipped with an active mass driver (AMD) has been used. The effectiveness of the control algorithm has been examined by exciting the test structure using a sinusoidal signal, a scaled El Centro earthquake and a broadband Gaussian white noise; and, especially, experiments on control have been performed under different conditions to that of system identification in order to prove the stability and robustness of the proposed control algorithm. The experimental results indicate that the probabilistic control algorithm can achieve a significant response reduction under various types of ground excitations even when the modeling error exists. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Assessing the vegetation canopy influences on wind flow using wind tunnel experiments with artificial plants     

YOUNGJOO HONG  DONGYEOB KIM  SANGJUN IM 《Journal of Earth System Science》2016,125(3):499-506

Wind erosion causes serious problems and considerable threat in most regions of the world. Vegetation on the ground has an important role in controlling wind erosion by covering soil surface and absorbing wind momentum. A set of wind tunnel experiments was performed to quantitatively examine the effect of canopy structure on wind movement. Artificial plastic vegetations with different porosity and canopy shape were introduced as the model canopy. Normalized roughness length (Z ₀/H) and shear velocity ratio (R) were analyzed as a function of roughness density (λ). Experiments showed that Z ₀/H increases and R decreases as λ reaches a maximum value, λ _max, while the values of Z ₀/H and R showed little change with λ value beyond as λ _max.  相似文献   

朝鲜半岛古元古代摩天岭群的碎屑锆石U-Pb年龄及其地质意义   总被引：2，自引：1，他引：1  

廖鑫  张晓晖  金胜贤  朴雄  郑哲寿 《岩石学报》2016,32(10):2981-2992

克拉通内部活动带变质沉积建造蕴藏了早期超大陆形成中地体聚-散动力学过程的重要信息,碎屑锆石年代学则是揭示这种信息的最佳工具之一。针对华北(中-朝)克拉通最具代表性的古元古代活动带(辽-吉-朝活动带)中巨量沉积建造精细表征方面的空白区域,本文开展了朝鲜半岛检德地区摩天岭群的碎屑锆石年代学研究。SIMS U-Pb定年结果显示,北大川组变火山碎屑岩样品的锆石年龄谱记录了约2.53Ga的主要年龄峰值和约2.19Ga的最年轻峰值,说明北大川组开始沉积的时代应该晚于2.2Ga。南大川组变沉积岩样品碎屑锆石记录的最年轻峰值年龄为约2.02Ga,说明南大川组的沉积时代应该不早于2.02Ga;其锆石年龄谱记录了一个主要年龄峰值区域(2.02~2.18Ga)、一个次要年龄峰值(约2.46Ga)和一些2.78~3.30 Ga的古老年龄,指示其物质源区主要为同区古元古代地质体和邻近地体上的太古宙变质基底。区域对比表明,摩天岭群与中国境内辽吉活动带中的辽河群及集安群/老岭群具有基本一致的碎屑锆石年龄谱,说明它们不仅是同一时代的产物,而且分享类似的物质源区。这些时代一致、物源相近的沉积建造可以为甄别古元古代辽-吉-朝活动带的大地构造属性提供重要参考。与沉积年龄相近的碎屑锆石占据主导的碎屑锆石年龄谱反映了汇聚板块边缘各类盆地的典型特征,而相悖于大部分碎屑锆石年龄远大于地层沉积年龄的裂谷型盆地。  相似文献   

朝鲜~19亿年侵入岩的岩石类型与构造背景初探   总被引：5，自引：5，他引：0  

彭澎  王冲  杨正赫  金正男 《岩石学报》2016,32(10):2993-3018

朝鲜半岛北部广泛发育~19亿年侵入岩,这些岩浆岩可以分为三个系列,分别为似斑状花岗岩系列(多为I型,以妙香山岩体为代表,年龄1900~1840Ma)、S型花岗岩系列(以嘉山岩体为代表,本文获得1862±5Ma锆石U-Pb年龄)和正长岩系列(以龙浦岩体为代表,本文获得1857±2Ma锆石U-Pb年龄)。似斑状花岗岩系列(I型花岗岩)大致对应朝鲜地质学家定义的Myohyangsan(妙香山)杂岩,以发育钾长石巨斑为特征,与麻粒岩相变质的火山岩-沉积岩系关系密切;S型花岗岩系列大致对应Ryonhwasan(莲花山)杂岩,以发育石榴石和堇青石等矿物为特征,与麻粒岩相变质的副变质岩共生:这说明前者可能与变质火山岩系相关,而后者可能和副变质岩相关。正长岩系列,朝鲜地质学家称为Sakju(朔州)杂岩,分布较为局限,仅见于朔州以及博川-定州之间,也见于邻区辽东,多为岩株。这三个系列岩浆岩稍早或者同期于角闪岩相-麻粒岩相变质(本文获得甑山"群"变质锆石U-Pb年龄1844±2Ma)。邻区辽东-吉南及胶东地区也发育这三个系列岩浆岩,但这两个地区~21亿年岩浆作用更为广泛。朝鲜半岛南部发育大量同期岩浆岩,但岩石类型以似斑状花岗岩为主,并发育紫苏花岗岩和斜长岩。我们推测,朝鲜半岛南北两侧基底属性存在差异,可能对应不同的古陆(华北与华南古陆)。综合分析表明,朝鲜~19亿年前广泛发育I型和S型花岗岩,并有幔源岩浆作用,同时发育正长岩类,并且这些岩浆活动与区域高级变质作用时代接近。考虑到本区存在太古宙基底,我们推测本区在古元古代可能处于类似现今活动大陆边缘弧背景。  相似文献