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1.
To determine the estrogenicity of effluents from sewage treatment plants (STPs) to larval fish, 2-day-old sunshine bass were exposed to effluents from three STPs serving New York City (NYC), varying in size and treatment level. Estrogenic response was evaluated by measuring vitellogenin (VTG) and estrogen receptor (ER) expression in cytosolic fractions of whole body homogenates. Concentrations of the presumptive endocrine disruptors in the effluents were also measured. VTG and ER levels in sewage-exposed fish were 3-5 times that observed in controls. Combined concentrations of estradiol and estrone ranged from 5 to 13 ng/l and nonylphenol-ethoxylate metabolites (NPEOs: 4-nonylphenol, and 1-, 2-, and 3-nonylphenol-ethoxylates) ranged from 180 to 470 microg/l in chlorinated effluent. Results indicate that both ER and VTG can be used as biomarkers for endocrine disruption in larval fish, and that 4-day exposure to sewage effluent is sufficient to elicit significant expression of these markers in sunshine bass larvae. The extremely higher concentrations of NPEOs found in effluent relative to hormones (approximately 40,000-fold) indicates that surfactant metabolites may be contributing significantly to the estrogenic effects observed.  相似文献   
2.
Freshly prepared homogenates were used to assess the relative ability of winter flounder (Pseudopleuronectes americanus) liver and intestinal mucosal cells to metabolize the polycyclic aromatic hydrocarbon (PAH) benzo[a]pyrene (BaP) and its proximate carcinogenic metabolite, BaP-7,8-dihydrodiol (7,8-Diol). Data obtained from homogenates prepared from fish previously fed β-naphthoflavone (BNF) indicated that both tissues had similar abilities to metabolize either BaP or 7,8-Diol on a per gram of protein basis. Metabolite profiles produced indicate that water-soluble metabolite formation is favored at low doses. These findings support the hypothesis that the intestine plays an important role in first-pass metabolism of dietary carcinogens in the winter flounder.  相似文献   
3.
Radiative recombination of N and O provides a significant source for auroral emission in the γ and δ bands of NO with selective population of vibrational levels in the A2Σ+ and C2Π states. This mechanism may account for emissions detected near 2150 Å. Models are derived for the auroral ionosphere and include estimates for the concentrations of N and NO. The concentration of NO is estimated to have a value of about 108 cm?1 near 140 km in an IBC III aurora. The corresponding density for N is about 5 × 107cm?3 and the concentration ratio NO+O2+ has a value of about 5.5.  相似文献   
4.
Models are developed for the photochemistry of a CO2H2ON2 atmosphere on Mars and estimates are given for the concentrations of N, NO, NO2, NO3, N2O5, HNO2, HNO3, and N2O as a function of altitude. Nitric oxide is the most abundant form of odd nitrogen, present with a mixing ratio relative to CO2 of order 10?8. Deposition rates for nitrite and nitrate minerals could be as large as 3× 105 N equivalent atoms cm?2 sec?1 under present conditions and may have been higher in the past.  相似文献   
5.
Oxidation of CH4 provides the major source for atmospheric H2 which is removed mainly by reaction with OH. Biological activity at the Earth's surface appears to represent at most a minor sink for H2. Anthropogenic activity is a significant source for both H2 and CO in the present atmosphere and may be expected to exert a growing influence in the future. Models are presented which suggest a rise in the mixing ratio of H2 from its present value of 5.6 × 10?7 to about 1.8 × 10?6 by the year 2100. The mixing ratio of CO should grow from 9.7 × 10?8 to 2.3 × 10?7 over the same time period and there should be a rise in CH4 by about a factor of 1.5 associated with anthropogenically induced reductions in tropospheric OH.  相似文献   
6.
This paper reviews key characteristics of kimberlites on the Ekati property, NWT, Canada. To date 150 kimberlites have been discovered on the property, five of which are mined for diamonds. The kimberlites intrude Archean basement of the central Slave craton. Numerous Proterozoic diabase dykes intrude the area. The Precambrian rocks are overlain by Quaternary glacial sediments. No Phanerozoic rocks are present. However, mudstone xenoliths and disaggregated sediment within the kimberlites indicate that late-Cretaceous and Tertiary cover (likely <200 m) was present at the time of emplacement. The Ekati kimberlites range in age from 45 to 75 Ma. They are mostly small pipe-like bodies (surface area mostly <3 ha but up to 20 ha) that typically extend to projected depths of 400–600 m below current surface. Pipe morphologies are strongly controlled by joints and faults. The kimberlites consist primarily of variably bedded volcaniclastic kimberlite (VK). This is dominated by juvenile constituents (olivine and lesser kimberlitic ash) and variable amounts of exotic sediment (primarily mud), with minor amounts of xenolithic wall-rock material (generally <5%). Kimberlite types include: mud-rich resedimented VK (mRVK); olivine-rich VK (oVK); sedimentary kimberlite; primary VK (PVK); tuffisitic kimberlite (TK) and magmatic kimberlite (MK). The presence and arrangement of these rock types varies widely. The majority of bodies are dominated by oVK and mRVK, but PVK is prominent in the lower portions of certain kimberlites. TK is rare. MK occurs primarily as precursor dykes but, in a few cases, forms pipe-filling intrusions. The internal geology of the kimberlites ranges from simple single-phase pipes (RVK or MK), to complex bodies with multiple, distinct units of VK. The latter include pipes infilled with steep, irregular VK blocks/wedges and at least one case in which the pipe is occupied by well-defined sub-horizontal VK phases, including a unique, 100-m-thick graded sequence. The whole-rock compositions of VK samples suggest significant loss of kimberlitic fines during eruption followed by variable dilution by surface sediment and concurrent incorporation of kimberlitic ash. Diamond distribution within the kimberlites reflects the amount and nature of mantle material sampled by individual kimberlite phases, but is modified considerably by eruption and depositional processes. The characteristics of the Ekati kimberlites are consistent with a two-stage emplacement process: (1) explosive eruption/s causing vent clearing followed by formation of a significant tephra rim/cone of highly fragmented, olivine-enriched juvenile material with varying amounts of kimberlitic ash and surface sediments (predominantly mud); and (2) infilling of the vent by direct deposition from the eruption column and/or resedimentation of crater rim materials. The presence of less fragmented, juvenile-rich PVK in the lower portions of certain pipes and the intrusion of large volumes of MK to shallow levels in some bodies suggest emplacement of relatively volatile-depleted, less explosive kimberlite in the later stages of pipe formation and/or filling. Explosive devolatilisation of CO2-rich kimberlite magma is interpreted to have been the dominant eruption mechanism, but phreatomagmatism is thought to have played a role and, in certain cases, may have been dominant.  相似文献   
7.
The study investigated the global and regional phylogeography of the yellowtail kingfish Seriola lalandi by examining genetic diversity and population genetic structure of this species at inter-and intra-ocean level and on a regional scale. DNA fragments of two mitochondrial genes, cytochrome b (Cytb) and cytochrome c oxidase subunit I (COI) and one nuclear gene, recombination activating gene 1 (RAG1), were sequenced to investigate the global-scale phylogeography of this species. The population genetic structure within the South Pacific, as well as along the South African coastline, was examined further using six microsatellite markers. Three distinct clades were identified for S. lalandi, which correspond with previously described subspecies of the North-East Pacific, North-West Pacific and the Southern Hemisphere. Within the latter, additional divergence was observed between the South Pacific and the South-East Atlantic regions. Divergence estimates were indicative of a Pacific origin for S. lalandi populations, because of Pleistocene vicariant events. Microsatellite analyses revealed overall significant genetic differentiation between South African and South Pacific samples. This corroborates recent findings on the global phylogeography of the species. No population differentiation was observed within South Africa, indicating high levels of gene flow.  相似文献   
8.
A numerical investigation is conducted of the nocturnal heat island over Columbus, Ohio, a relatively flat mid-latitude city. Specifically, a cross-sectional steady-state numerical model to simulate the (thermal) structure of the nocturnal urban boundary layer is developed from a one-dimensional, time-dependent model due to Estoque. The model is applied to Columbus for special periods in September 1968 and March 1969 during which comparable experimental data were collected. The numerical simulations agree well with the observed data with respect to the detailed spatial form of the surface-based thermal boundary layer across the city. The use of the model for other metropolitan areas, for ascertaining the relative effect of city size and building geometry on the development of the thermal boundary layer, and for determining the effect of alternate land-use strategies on the thermal stratification are also discussed.Digest of portion of a dissertation submitted to the Pennsylvania State University in partial fulfillment of the requirements for the degree of Doctor of Philosophy.Presented in part at the Air Pollution, Turbulence and Diffusion Symposium, Las Cruces, New Mexico, 7–10 December 1971.On assignment from the National Oceanic and Atmospheric Administration (NOAA), U.S. Department of Commerce.  相似文献   
9.
Direct photolysis of O3 and quenching of O(1D) by N2 provide abundant sources of fast oxygen atoms for the Earth's lower atmosphere. The concentration of atoms with energy above 0.7 eV may exceed the concentration of O(1D) for all altitudes below 18 km and these atoms may play an important role in lower atmospheric chemistry. Distribution functions for O(3P) are given for the energy interval 0.1-1.3 eV, for a range of altitudes from 0 to 62 km.  相似文献   
10.
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