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1.
Fine-grained peraluminous synkinematic leuco-monzogranites (SKG), of Cambro-Ordovician age, occur as veins and sills (up to 20–30 m thick) in the Deep Freeze Range, within the medium to high-grade metamorphics of the Wilson Terrane. Secondary fibrolite + graphite intergrowths occur in feldspars and subordinately in quartz. Four main solid and fluid inclusion populations are observed: primary mixed CO2+H2O inclusions + Al2SiO5 ± brines in garnet (type 1); early CO2-rich inclusions (± brines) in quartz (type 2); early CO2+CH4 (up to 4 mol%)±H2O inclusions + graphite + fibrolite in quartz (type 3); late CH4+CO2+N2 inclusions and H2O inclusions in quartz (type 4). Densities of type 1 inclusions are consistent with the crystallization conditions of SKG (750°C and 3 kbar). The other types are post-magmatic: densities of type 2 and 3 inclusions suggest isobaric cooling at high temperature (700–550°C). Type 4 inclusions were trapped below 500°C. The SKG crystallized from a magma that was at some stage vapour-saturated; fluids were CO2-rich, possibly with immiscible brines. CO2-rich fluids (±brines) characterize the transition from magmatic to post-magmatic stages; progressive isobaric cooling (T<670°C) led to a continuous decrease off O 2 can entering in the graphite stability field; at the same time, the feldspars reacted with CO2-rich fluids to give secondary fibrolite + graphite. Decrease ofT andf O 2 can explain the progressive variation in the fluid composition from CO2-rich to CH4 and water dominated in a closed system (in situ evolution). The presence of N2 the late stages indicates interaction with external metamorphic fluids.Contribution within the network Hydrothermal/metamorphic water-rock interactions in crystalline rocks: a multidisciplinary approach on paleofluid analysis. CEC program: Human Capital and Mobility  相似文献   
2.
The MoSE project (construction of mobile barrier to safeguard the Lagoon of Venice) entails changes to the structure of the lagoon's inlets. This could have consequences for the areas near the inlets and for the dynamics of the lagoon ecosystem as a whole. In order to predict the effects of the proposed alterations on the hydrodynamics of the lagoon, a well-tested hydrodynamic-dispersion model was applied. Simulations were carried out considering both idealised and realistic tide and wind scenarios.  相似文献   
3.
K/Ar and fission track age measurements were performed on lava samples of Monte Amiata volcano (Central Italy) which is formed by a sequence of lava flows and lava domes ranging in composition from trachybasalts to high-SiO2 quartzlatites. The ages obtained, except for the oldest volcanic products, range from 290,000 to 180,000 years. Excess40Ar was found in some mineral separates, especially biotite, causing apparent rather old ages. The correct ages were calculated by means of K/Ar isochrons, and were found to be very similar to the ages calculated on sanidine separates. The volcanic activity that built up the outcropping Monte Amiata units seems to have lasted a relatively short time.  相似文献   
4.
The Sardinia-Corsica batholith was structured in the late stage of the Hercynian orogenesis. The granitoids intrude mainly metamorphic complexes grading from zeolite up to amphibolite facies. The batholith is heterogeneous consisting of complexes with different affinity, chemical composition, age and degree of deformation. The present paper reports major-and trace-element data for selected samples coming only from Sardinian outcrops.

The rocks range from gabbro-diorite to tonalite, monzogranite and leucogranite. The two latter lithologies are the most abundant, gabbrodiorites and tonalites occurring in minor amounts and mainly in northern-central Sardinia. Over 75% of the granitoids contain microgranular enclaves of magmatic origin. The age of the rocks falls in the interval between 307 and 281 Ma. Sr isotope initial ratios are high, ranging between 0.7083 and 0.7107.

REE, Rb, Sr, Ba, Zr, Th, Ta, Hf, Co and Sc abundances were determined on selected samples. All elements follow three types of trends vs. CaO, which is used as differentiation index. Two trends show positive and negative correlations while the third one shows a bell-shaped pattern. LREE have different degrees of enrichment (La = 20−120× ch) and HREE show variable fractionation with prevailing (Tb/Yb)n<1. The two peraluminous samples have very different geochemical characteristics.

From the geochemical point of view all the rocks coming from the Sardinian segment of the batholith display a typical calc-alkaline chemical character showing the imprint of both “normal and mature” continental arc geodynamic environments.

Geochemical trends suggest some petrogenetic constraints. The complete sequence of differentiation can be neither the product of crystal/liquid fractionation processes starting from a single basic parent magma nor the product of an AFC process. On the contrary, a two-stage model can be proposed. In the first stage a mafic melt of subcrustal origin interacted with monzogranitic magmas derived from 25–35% degree of melting of a crustal biotite amphibolitic source. Such a mixing process acted together with a crystal/liquid fractionation process to give tonalites and granodiorites. In the second stage lesser degrees of melting of the same crustal source could give the late-stage leucogranitic masses.

A possible scenario, able to take into account field and geochemical data, can be suggested for the genesis of this suite and we propose it as a working model for future investigations.  相似文献   

5.
The Antarctic Ross Orogen was built up during the early Paleozoic in the framework of the convergence between the Paleo-Pacific oceanic plate and the Gondwana continental margin. Models for the Ross Orogen in northern Victoria Land are based on terranes having a variable provenance with respect to the margin. However, recent studies provide evidence for the occurrence of different pieces of the lithospheric puzzle: (i) the Wilson continental magmatic arc, representing the main part of the active Gondwana margin, (ii) the Bowers arc–backarc system, (iii) the Admiralty crustal ribbon including continental material of the Wilson forearc, and (iv) the newly discovered, Cambrian oceanic magmatic Tiger arc, along the Ross Sea coast. An updated model is presented in which, after the Early Cambrian magmatic activity of the Wilson arc, a retreat of the subduction zone in the Early–Middle Cambrian gave way to boudinage of the Wilson forearc, trenchward arc migration, opening of the Bowers backarc basin and inception of the outboard Tiger subduction zone. Renewed convergence resulted in the development of the Middle Cambrian Bowers arc, closure of the backarc and deep underthrusting of portions of it at the Middle–Late Cambrian. Finally, in the latest Cambrian to earliest Ordovician, fast exhumation was coupled in the north with erosion and sediment shed to the northeast, and with extension and potassic magmatism in central and southern Victoria Land.  相似文献   
6.
The hydraulic regime-based zonation scheme of the Lagoons of Marano and Grado (Italy) has been derived by means of numerical models. A finite element modelling system has been used to describe the water circulation taking in account different forces such as tide, wind and rivers. The model has been validated by comparing the simulation results against measured water levels, salinity and water temperature data collected in several stations inside the lagoons. The analysis of water circulation, salinity and spatial distribution of passive tracers released at the inlets, led to a physically-based division of the lagoons system into six subbasins. The derived classification scheme is of crucial value for understanding the renewal capacity and pollutants distribution patterns in the lagoon.  相似文献   
7.
The Water Framework Directive (2000/60/EC) requires member states to classify and enhance the ecological quality of water bodies in accordance with their type. To estimate the effect on type of the natural variability of lagoons, we applied a two-dimensional hydrodynamic model to the lagoon of Venice. The model calculated the mean annual spatial distributions of two variables: salinity and residence time. The standard deviation of salinity was also included, in order to estimate the variation of salinity values around the mean, which is associated with the instability of the mean salinity value.A highly detailed numerical grid was calibrated and high-frequency tributary discharge data were used.The simulations, under realistic forcing conditions, are based on the years 2003 and 2005. The former was characterized by low precipitation, around 30% less than the typical value.A comparison of model results and measurements shows the high reliability of the model in reproducing the spatial distribution and temporal evolution of salinity.We found strong inter-annual variation in salinity, standard deviation of salinity and residence time. The effect on the typing process is that the most representative types shift from one category to another.On the basis of the spatial patterns of the variables and their superposition, we identified types that described the bulk of the lagoon.This numerical tool offers support for lagoon management on various levels, in terms of both WFD requirements and other applications, by: (1) providing unbiased and objective zoning indications for the basin; (2) evaluating the response of water quality elements; (3) establishing the reference status of a water body; and (4) establishing a hierarchical division of a lagoon that can be used to select an appropriate number of sampling stations for monitoring.  相似文献   
8.
Summary The oxygen and strontium isotope compositions of the Cambro-Ordovician granitoids cropping out in the Wilson Terrane (Granite Harbour Intrusives–GHI) constrain the petrological evolution of the magmatism in Antarctica, related to the Ross Orogeny. The measured δ18OWR values of these intrusives define three different compositional groups: the metaluminous rocks (MAG), with δ18OWR ranging from 6.9 (olivine gabbro) to 11.4‰ (monzogranite); the unaltered peraluminous granites (PAG), having δ18OWR values ranging from 10.6 to 13.2‰, and the foliated peraluminous leucogranites (SKG), characterised by δ18OWR values above 14‰. The analysis of equilibrium mineral assemblages indicates that the high δ18OWR values are magmatic and unaffected by low-temperature processes. A few peraluminous granites sampled in the vicinity of Cenozoic intrusions show anomalously low δ18OWR, due to meteoric-hydrothermal alteration. The isotopic data indicate that the coeval and spatially related metaluminous mafic and felsic intrusives forming the GHI were not comagmatic: the mafic and intermediate rocks were likely derived from lower crustal contamination of a pristine basaltic magma; their δ18OWR values were also increased during emplacement, due to the interaction with the adjacent 18O-rich hydrous felsic magmas (mixing). Oxygen isotope data indicate that the crustal sources producing the Granite Harbour intrusives were not homogeneous: the felsic metaluminous intrusives were produced by partial melting of fertile rock with possible igneous origin, whereas partial melting of a metapelitic source rock is claimed for the genesis of the peraluminous granites. Received February 9, 2001; revised version accepted August 10, 2001  相似文献   
9.
A detailed in situ isotopic (U–Pb, Lu–Hf) and geochemicalstudy of zircon populations in a composite sequence of foliatedto massive Cambro-Ordovician intrusions in the Deep Freeze Range(North Victoria Land, Antarctica), has highlighted great complexityin zircon systematics. Zircons in deformed granitoids and tonalitesdisplay complex internal textures, a wide spread of concordantU–Pb ages (between 522 and 435 Ma) and unusual trace-elementcompositions (anomalous enrichment of light rare earth elements,U, Th and Y) within single zircon grains. In contrast, zirconsfrom undeformed samples display a limited range of U–Pbages and trace-element compositions. Zircons from all age andtextural populations in most of the deformed and undeformedsamples show a relatively narrow range of Hf values, suggestingthat the Lu–Hf system remained undisturbed. Inferred emplacementages cover a time interval of about 30 Myr: from 508 to 493Ma for the oldest strongly foliated synkinematic Howard Peaksmegacrystic monzogranites and high-K calc-alkaline mafic tointermediate rocks of the ‘Corner Tonalite’ unit;from about 489 to 481 Ma for the younger massive shoshoniticmafic dyke suite and the high-K calc-alkaline Keinath granite.The observed isotopic and chemical variations in zircon areattributed to a sub-solidus recrystallization under hydrousconditions and varying temperature, in a setting characterizedby a transpressional to extensional stress regime. KEY WORDS: Antarctica; Cambro-Ordovician intrusives; Ross Orogen; zircon U–Pb geochronology  相似文献   
10.
The high-grade metamorphic complex of northern Sardinia consists of a strongly deformed sequence of migmatitic ortho- and paragneisses interlayered with minor amphibolites preserving relic eclogite parageneses. The protolith ages and geochemical characteristics of selected gneiss samples were determined, providing new constraints for reconstructing the Palaeozoic geodynamic evolution of this sector of the Variscan chain. The orthogneisses are metaluminous to peraluminous calcalkaline granitoids with crustal Sr and Nd isotopic signatures. One orthogneiss from the high-grade zone and one metavolcanite from the volcanic belt in southern Sardinia were dated by LAM-ICPMS (and SHRIMP) zircon geochronology. The inferred emplacement ages of the two samples are 469 ± 3.7 and 464 ± 1 Ma, respectively. The analysed paragneisses are mainly metawackes with subordinate metapelites and rare metamarls. Three paragneiss samples were dated: zircon ages scatter between 3 Ga and about 320 Ma, with a first main cluster from 480 to 450 Ma, and a second one from about 650 to 550. Variscan zircon ages are rare and mostly limited to thin rims and overgrowths on older grains. These data indicate that the high-grade complex principally consists of middle Ordovician orthogneisses associated with a thick metasedimentary sequence characterised by a maximum age of deposition between 480 and 450 Ma. The association of nearly coeval felsic-mafic magmatic rocks with immature siliciclastic sedimentary sequences points to a back-arc setting in the north Gondwana margin during the Early Palaeozoic. The Variscan metamorphic evolution recorded by the high-grade gneisses (Ky-bearing felsic gneisses and mafic eclogites) testifies to the transformation of the Late Ordovician–Devonian passive continental margin into an active margin in the Devonian–Early Carboniferous.Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users.  相似文献   
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