首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:从到   被引次数:从到   他引次数:从到 提示：输入*表示无穷大
全文获取类型
  收费全文   8篇
  免费   0篇
专业分类
大气科学   3篇
地球物理   1篇
地质学   2篇
海洋学   2篇
出版年
  2022年   2篇
  2018年   1篇
  2016年   1篇
  2012年   1篇
  2011年   1篇
  2010年   1篇
  1983年   1篇
排序方式： 共有8条查询结果，搜索用时 203 毫秒
1
1.
The reduction of heavy metals (cadmium, lead and zinc) in the presence of long-chain fatty acids (lauric, oleic and linoleic) in 0.55 mol dm?3 NaCl and 0.03 mol dm?3 NaHCO3 at pH 8.7 has been studied by differential pulse polarography. The increase of the peak height of investigated metals by up to tenfold the value obtained in electrolyte without fatty acid is due to adsorption of metal ions at the electrode surface. The accumulation of metal increases with the increase of adsorption time (at potentials more positive than the reduction potential of the particular metal) and with increase of salinity. The heavy-metal adsorption depends on the concentrations of both metal ions and fatty acids. The interaction of heavy metals with the unsaturated fatty acids in the bulk and/or in the adsorbed layer at different natural interfaces could be of considerable importance in an understanding of the fate and distribution of heavy metals in the natural aquatic environment.  相似文献   
2.
Characterization of atmospheric surfactants in bulk precipitations was carried out by adsorption study at the mercury electrode/solution interface using phase sensitive AC voltammetry. The structure and permeability of the adsorbed organic films at the mercury electrode was tested using the redox processes of lead and cadmium ions as electrochemical tools. The effects of organic matter from the bulk precipitations (rainwater and melted snow) were compared to those obtained for aqueous solutions of model substances: aromatic hydrocarbon (naphtalene), anionic surfactant (sodium dodecylbenzene sulfonate, NDBS), protein (albumine) and selected model substances suggested to be representative of water soluble organic compounds (WSOC) in atmospheric water (monocarboxylic, dicarboxylic, and polyacidic compounds and levoglucosan). It was found that substances like humic acid and 3-hydroxybutanoic acid may play an important role in atmospheric heterogeneous chemistry because of their surface active potential.  相似文献   
3.
Boundary-Layer Meteorology - Statistical properties of turbulence, specifically variances of velocity components, temperature, water vapor, and carbon dioxide densities, are observationally...  相似文献   
4.
Boundary-Layer Meteorology -  相似文献   
5.
The Pannonian Basin, originating during the Early Miocene, is a large extensional basin incorporated between Alpine, Carpathian and Dinaride fold-thrust belts. Back-arc extensional tectonics triggered deposition of up to 500-m-thick continental fluvio-lacustrine deposits distributed in numerous sub-basins of the Southern Pannonian Basin. Extensive andesitic and dacitic volcanism accompanied the syn-rift deposition and caused a number of pyroclastic intercalations. Here, we analyze two volcanic ash layers located at the base and top of the continental series. The lowermost ash from Mt. Kalnik yielded an 40Ar/39Ar age of 18.07?±?0.07?Ma. This indicates that the marine-continental transition in the Slovenia-Zagorje Basin, coinciding with the onset of rifting tectonics in the Southern Pannonian Basin, occurs roughly at the Eggenburgian/Ottnangian boundary of the regional Paratethys time scale. This age proves the synchronicity of initial rifting in the Southern Pannonian Basin with the beginning of sedimentation in the Dinaride Lake System. Beside geodynamic evolution, the two regions also share a biotic evolutionary history: both belong to the same ecoregion, which we designate here as the Illyrian Bioprovince. The youngest volcanic ash level is sampled at the Glina and Karlovac sub-depressions, and both sites yield the same 40Ar/39Ar age of 15.91?±?0.06 and 16.03?±?0.06?Ma, respectively. This indicates that lacustrine sedimentation in the Southern Pannonian Basin continued at least until the earliest Badenian. The present results provide not only important bench marks on duration of initial synrift in the Pannonian Basin System, but also deliver substantial backbone data for paleogeographic reconstructions in Central and Southeastern Europe around the Early–Middle Miocene transition.  相似文献   
6.
The relationship between changes in lipid classes and phytoplankton composition and abundance in the northern Adriatic was studied during spring and summer 2008 at two stations with different nutrient levels, i.e. at the western mesotrophic and eastern oligotrophic areas. Changes in the phytoplankton community depended on temporal surface nutrient depletion and bottom accumulation; that is, microphytoplankton, mainly diatoms Pseudo-nitzschia sp., developed at nutrient richer surface layers of the mesotrophic area in spring and at deeper layers of the oligotrophic site in late summer. In other periods nanophytoplankton dominated. Dissolved organic carbon (DOC) and lipid content were comparable for the two stations, while particulate organic carbon (POC) was richer at the mesotrophic side. Total lipid concentrations varied in the range from 8.0 to 92.2 μg l−1 and from 16.9 to 76.9 μg l−1 in the dissolved and particulate fractions, respectively. DOC and POC contents were in the ranges from 0.77 to 1.58 mg l−1 and from 0.06 to 0.56 mg l−1, respectively. Lipid and organic carbon distribution did not follow phytoplankton progression, indicating decoupling between organic matter production and decomposition throughout the investigation period. The main sources of lipids were marine phytoplankton and bacteria. Low nutrient conditions caused increased biosynthesis of lipids. Also, increasing oligotrophy led to an increasing number of phytoplankton taxa. The synthesis and accumulation of glycolipids by the developed taxa were enhanced during nutrient exhaustion, contributing in late summer, on average, 20.2 and 22.0% at the mesotrophic and oligotrophic stations, respectively, in the particulate fraction. The distribution of bacterial lipids and lipid breakdown products implies that bacterial lipid degradation was significant in spring, while very probably lipid abiotic degradation took place during summer.  相似文献   
7.
This paper highlights the problem of step-length selection for the one-step-ahead prediction of ozone called the data time interval. This is done using a case study-based comparison of two approaches for predicting the maximum daily values of tropospheric ozone. The first approach is the 1-day-ahead prediction and the second is the prediction of the maximum values based on a multi-step-ahead iteration of 1-h predictions. Gaussian process modelling is utilised for this comparison. In particular, evolving Gaussian-process models are used that update on-line with the incoming measurement data. These sorts of models have been successfully used in the past for the prediction of ozone pollution. This paper contributes an assessment of the way that the maximum ozone values are predicted. A comparison of the daily maximum ozone values forecasted by a model based on 1-day-ahead predictions with those obtained by iterated 1-h-ahead predictions of the ozone with predictions at predetermined hours of the day is given. The forecast results are in favour of the on-line model based on hourly predictions when approaching closer to the real maximum values of ozone, and in favour of the daily predictions when they are made on a daily basis.  相似文献   
8.
  相似文献   
1
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号