Effect of some additives on synthesis of zeolite from coal fly ash   总被引：3，自引：0，他引：3  

Deyi Wu  Bohua Zhang  Li Yan  Hainan Kong  Xinze Wang 《International Journal of Mineral Processing》2006,80(2-4):266-272

Hydrothermal conversion of fly ash into zeolites was conducted and the effects of the addition of sodium halide and waste solutions produced after zeolitization of fly ash, as well as the adjustment of the Si/Al ratio prior to synthesis process on the formation and cation exchange capacity (CEC) of zeolite product were evaluated. Both the addition of NaCl and NaF ameliorated the crystallinity and CEC of synthesized zeolite, but NaF had a better improvement effect. Na⁺ was considered to enhance the crystallization of zeolite, while F⁻ favored the dissolution of fly ash. The type of zeolite formed depended on the Si/Al ratio of the starting material prior to the nucleation and crystallization of zeolite. The adjustment of the Si/Al ratio of fly ash by addition of Na₂SiO₄ and Al(OH)₃ changed the type and CEC of zeolite. Waste solutions contained large amount of Si and little Al due to the formation of a zeolite named NaP1 in zeolite terminology with the Joint Committee of Powder Diffraction Standard (JCPDS) code of 39-0219. The alkalinity decreased largely. As a result, the CEC value of zeolite products synthesized with waste solution as alkali source decreased. The supplementation of new alkali to adjust the alkalinity of waste solution could enhance the CEC of synthesized product. It was concluded that: (1) addition of sodium halide and adjustment of the Si/Al ratio prior to synthesis can improve the quality of zeolite; (2) waste solutions produced following the zeolitization of fly ash can be reused as an alkali source in the activation of fly ash; zero-emission of waste solution in the synthesis of zeolite from fly ash is possible.  相似文献   

琼北火山及断裂的活动性——氡、钍气体放射性示踪   总被引：2，自引：1，他引：2       下载免费PDF全文

高清武  上官志冠  胡金文 《地震地质》2003,25(2):280-288

琼北火山区是中国的主要火山群之一。笔者应用HDS - 1型快速数字闪烁测氡仪对琼北火山群马鞍岭和雷虎岭段的火山及断裂活动性进行了勘测和研究 ,对荣山 -岭南断裂进行了重点测量 ,查明了该断裂的具体位置 ,研究了火山及断裂的气体释放特征。发现Rn(氡 ) ,Th(钍 )的变化与断裂构造有密切关系 ,在Ⅰ ,Ⅱ测线上Th ,Rn异常对断裂的反映相当好。根据Th ,Rn的展布特征和浓度变化比较深入地分析了断裂的活动性。在雷虎岭西南 ,荣山 -岭南断裂活动性最强 ,而且 ,自西北向东南断裂规模及活动性均有增强的趋势。此外 ,还对火山的活动性进行了讨论和分析  相似文献   

Isostatic status in North China (1)
Method and local compensation     

Rui Feng  Jun Wang  Shuzhen Zheng  Guifang Huang  Huifen Yan  Hainan Zhou  Ruoshui Zhang 《地震学报(英文版)》1988,1(4):73-84

Following Airy and Pratt principles, five kinds of local-compensation models are analysed and a rapid 3-D gravity formula is utilized to calculate isostatic anomalies for 66 models with different parameters. It is noted that isostatic gravity maps appear nearly identical in their main patterns and features. The optimum compensation model in North China is one of modified Airy models in which the different density distribution in the surface, upper crust and lower crust is taken into account and the standard crustal thickness is about 50km. The position of the complete compensation interface is located in the upper mantle. The North China platform as a whole is under sub-isostatic equilibrium status with an isostatic anomaly of about 18·10⁻⁵ m/s² on an average. The distribution of isostatic gravity anomaly shows an obvious blockwise pattern. Most positive anomaly areas occur over the eastern part, the Jiao-Liao Block, Mt. Yan block and northern margin of the Hebei-Shandong block, whereas a negative area occurs in the Shanxi graben. The comparison of models indicates that the Moho discontinuity is not suitable to be taken as a compensation interface, and the compensation effects in Airy model are better than that in Pratt model, which is consistent with the feature of dominant layered structure and less lateral inhomogeneity in crust. Some results about composite compensation, the basic characteristics of isostatic anomaly and deep stucture will be published later in the second part of this paper. Wang Bowen took part in some work in this paper.  相似文献   

砖混结构楼房的控制爆破拆除技术          下载免费PDF全文

龚汉松 《探矿工程》1994,(1):59-61

以实例介绍了砖混结构楼房的控制爆破拆除技术，对楼房拆除爆破的坍塌方式、爆破参数及安全技术进行了分析和探讨。  相似文献   

海南岛“邦溪—晨星蛇绿岩片”的时代及其构造意义—Sm—Nd同位素制约   总被引：25，自引：4，他引：21  

李献华  周汉文  丁式江  李寄嵎  张仁杰  张业明  葛文春 《岩石学报》2000,16(3):425-432

本文报道了邦溪和晨星两个地区变质基性岩的 Sm - Nd同位素定年结果。Sm - Nd等时线年龄 333± 12 Ma代表了变质基性岩的形成年龄。这些变质基性岩高度亏损 Th、Nb、Ta和轻稀土元素 ,εNd(t)≈ 7,与洋中脊玄武岩类似 ,形成于大洋环境。本文将这些洋中脊型变质基性岩称之为“邦溪 -晨星蛇绿岩片”,它们与金沙江 -双沟 - Song Ma蛇绿岩在形成时代上基本一致 ,代表了东古特提斯洋的残片。邦溪 -晨星蛇绿岩片在早三叠世华南 (包括海南岛北部 )和印支块体 (包括海南岛中南部 )块体碰撞拼合时构造侵位在大陆上 ,成为“石碌混杂岩”的一部分  相似文献   

Changes in the characteristics of precipitation over northern Eurasia     

Guanhuan Wen  Gang Huang  Kaiming Hu  Xia Qu  Weichen Tao  Hainan Gong 《Theoretical and Applied Climatology》2015,119(3-4):653-665

  相似文献   

The intensified impact of El Niño on late-summer precipitation over East Asia since the early 1990s     

Piao  Jinling  Chen  Wen  Chen  Shangfeng  Gong  Hainan  Chen  Xiaolong  Liu  Bo 《Climate Dynamics》2020,54(11):4793-4809

Climate Dynamics - This study reveals a pronounced enhancement of the relationship between the winter El Niño and the following late-summer precipitation over East Asia since the early 1990s....  相似文献   

细基江篱繁枝变种在不同水层中的栽培试验     

刘思俭  揭振英  黄天文  邹东嬰  吴镜河 《广东海洋大学学报》1989,(Z1)

本文报道了为改变我国华南沿海目前在半咸淡水塘中进行地播式裁培细基江篱繁枝变种单产低的状况而进行的不同水层夹苗栽培和施肥增产试验,证明了越靠近水面江篱藻体生长越快,越接近底部藻钵生长越差,提出如果在水塘中单纯裁培江篱则水塘深度应保持20～30厘米,如果水深超过1米以上,则应采用浮筏式夹苗栽培,并在水中混养鱼虾等。浸泡施肥试验证明,在短短的40天裁培过程施肥藻体比不施肥藻体增产23％,说明了施肥的重要性。  相似文献   

东北地区湿度梯度下的表土植硅体的空间分布规律     

刘洪妍  王海南  介冬梅  刘利丹  高桂在  李德晖  李楠楠  冷程程  李晨露 《第四纪研究》2019,(1):76-88

植硅体的现代过程研究是恢复古环境的基础,探讨表土植硅体分布及组合特征对环境因子的响应尤为重要。沿中国东北地区年均温为4 ℃等温线采集70块表土样品,研究了单一温度因素控制下表土植硅体的空间分布规律,以期获得不同类型植硅体对降水的响应。研究结果表明:所有表土样品中植硅体丰富且数量较多,主要有棒型、尖型、块状、扇型、扁平状、短鞍型、帽型、哑铃型、齿型、三棱柱型、导管型、硅质突起、硅化气孔、弓型和多面表皮植硅体;且主要以短细胞、棒型、尖型为主,其平均百分含量之和高达80.77%,块状、扁平状、扇型次之,其他类型的植硅体含量较少。方差分析结果表明:棒型、三棱柱型、硅质突起、哑铃型和扁平状在大兴安岭、松嫩平原和长白山之间存在显著性差异,且棒型、三棱柱型、硅质突起的百分含量与年降水量具有极显著的正相关性,哑铃型的百分含量与年降水量具有极显著的负相关性。总之,年均温为4 ℃等温线上70块表土样品中植硅体类型基本相同,但不同类型植硅体的百分含量存在差异,说明本研究区域内表土植硅体组合特征对降水的响应较为敏感。  相似文献   

水动力条件对沉积物-水界面氧通量的影响   总被引：2，自引：0，他引：2  

郑阳华  邹浩东  何强  李宏  张青  陈德敏  艾海男 《湖泊科学》2018,30(6):1552-1559

氧环境决定了水体沉积物中各种生命所需元素的最终归趋,沉积物-水界面是水相与沉积物相氧传递的重要场所,而水动力条件是影响沉积物-水界面氧传递的重要因素.选择三峡库区一级支流御临河为研究对象,根据长年监测数据建立实验室模型,采用声学多普勒流速测试仪及微电极测试系统构建了非侵入式涡度相关测试系统,探究了不同水动力条件对沉积物-水界面氧通量的影响.结果表明：水体静止状态下沉积物-水界面溶解氧浓度随时间的增加而减少,非静止状态下随时间的增加而增加;沉积物-水界面氧通量随水体流速的增加而增加.根据氧通量求解对应流速下垂直涡动扩散系数并进行线性拟合,当水体流速为0.01~0.14 m/s时,垂直涡动扩散系数与水体流速的相关性最好,此时沉积物-水界面氧通量的传递以涡动扩散为主导.  相似文献