Size distribution of colloidal trace metals and organic carbon during a coastal bloom in the Baltic Sea   总被引：1，自引：0，他引：1  

Johan Ingri  Susanna Nordling  Jenny Larsson  Jenny Rnnegrd  Nina Nilsson  Ilia Rodushkin  Ralf Dahlqvist  Per Andersson   rjan Gustafsson 《Marine Chemistry》2004,91(1-4):117-130

The physico-chemical speciation of organic carbon and selected metals was measured during a coastal bloom in Ekhagen Bay, Baltic Sea, using ultrafiltration.One important objective with the study was to see if any depletion of trace metals could be measured in the directly bioavailable fraction (<1000 Da, the soluble low molecular weight fraction, LMW) during a plankton bloom. Filters with five different cut-offs were used (1 kD (1000 Da), 5 kD, 10 kD, 100 kD and 0.22 μm) in order to delineate the size distribution of colloidal organic carbon (COC) and trace metals.During the bloom in May, LMW Al, Co, Cu, Mn and Ni concentrations decreased although the colloidal and particulate concentrations were relatively high. Data show that desorption of colloidal and particulate bound trace metals to the LMW fraction was slower than the process depleting the LMW fraction.Estimates of the maximum active uptake of Cu, Ni and Mn by the phytoplankton, and the loss of non-bioactive Al from the LMW fraction, indicate that processes other than active uptake by phytoplankton must contribute to the observed depletion of trace metals in the LMW fraction. Hence, in order to estimate the bioavailable pool of trace metals for plankton during bloom conditions, these other processes must be understood and quantified.Transparent Exopolymeric Particles (TEP, reflecting sugar-rich phytoplankton exudates) increased around eight times during the plankton bloom. We hypothesize that the formation of TEP is a process that might be important for the transfer of trace metals from the LMW to the particulate fraction during the phytoplankton bloom, but the significance of TEP for this depletion in Baltic Sea surface water remains to be shown.  相似文献   

The 2002 reform of the Common Fisheries Policy's system of governance—rhetoric or reality?     

Tim Gray  Jenny Hatchard 《Marine Policy》2003,27(6):545

The 2002 Reform of the Common Fisheries Policy (CFP) was claimed to be a radical overhaul of a failing system. Several EU fish stocks—particularly North Sea cod—had reached dangerously low levels, and there was widespread dissatisfaction with the way in which the CFP was operating. The European Commission took the opportunity of the legal requirement to review some features of the CFP (principally access provisions) in 2002, to undertake a broader reappraisal of the CFP. One of the features of this reappraisal was an attempt to improve the CFP's system of governance by increasing the amount of stakeholder participation, decentralisation, transparency, accountability, effectiveness and coherence. In this paper, the conclusion is reached that this attempt to improve the quality of governance in the 2002 CFP reform package has been more rhetorical than real.  相似文献   

The POC / Th ratio of settling particles isolated using split flow-thin cell fractionation (SPLITT)     

rjan Gustafsson  Jenny Larsson  Per Andersson  Johan Ingri 《Marine Chemistry》2006,100(3-4):314

The common assumption that the ratio between particulate organic carbon (POC) and particulate ²³⁴Th obtained from shallow sediment traps and filterable particles are representative of the ratio in the total particle settling flux should be treated with caution in view of well-known biases associated with tethered shallow sediment traps and the decoupling between size and settling velocity of many natural particle regimes. To make progress toward reliably constraining the POC / ²³⁴Th ratio on truly settling particles, we have tested here a settling collection technique designed to remove any hydrodynamic bias; split flow-thin cell fractionation (SPLITT). These first results from a North Sea fjord and an open Baltic Sea time-series station indicates that the POC / ²³⁴Th ratio on the more complete particle-settling spectrum, isolated with SPLITT, was higher than the POC / ²³⁴Th ratio obtained simultaneously from tethered shallow sediment traps in seven out of seven parallel deployments with an average factor of 210%. The POC / ²³⁴Th ratio from the SPLITT was either in the same range or higher than that obtained on filtered “bulk” particles. To explain this novel data we hypothesize that the slowest settling fraction is organic-matter rich and does not strongly complex ²³⁴Th (i.e., high POC / ²³⁴Th). We suggest that this ultra-slow sinking fraction is better collected by SPLITT than with tethered sediment traps because of minimized hydrodynamic bias.This was tested using the ratio of POC / Al as a tracer of detrital mineral-ballast influenced settling velocity. The higher POC / Al ratios in SPLITT samples relative to in traps is consistent with the hypothesis that SPLITT is better suited for collecting also the slow-settling component of sinking particles. This important slow-settling component appears to here consist primarily of non-APS/TEP components of plankton exudates or other less-strongly ²³⁴Th-complexing organic matter. Further applications of the SPLITT technique are likely to return increasingly new insights on the composition (including “truly settling” POC / ²³⁴Th) of the total spectrum of particles settling out of the upper ocean.  相似文献   

Seismic potential of Southern Italy   总被引：1，自引：2，他引：1  

S. Jenny  S. Goes  D. Giardini  H.-G. Kahle 《Tectonophysics》2006,415(1-4):81-101

To improve estimates of the long-term average seismic potential of the slowly straining South Central Mediterranean plate boundary zone, we integrate constraints on tectonic style and deformation rates from geodetic and geologic data with the traditional constraints from seismicity catalogs. We express seismic potential (long-term average earthquake recurrence rates as a function of magnitude) in the form of truncated Gutenberg–Richter distributions for seven seismotectonic source zones. Seismic coupling seems to be large or even complete in most zones. An exception is the southern Tyrrhenian thrust zone, where most of the African–European convergence is accommodated. Here aseismic deformation is estimated to range from at least 25% along the western part to almost 100% aseismic slip around the Aeolian Islands. Even so, seismic potential of this zone has previously been significantly underestimated, due to the low levels of recorded past seismicity. By contrast, the series of 19 M6–7 earthquakes that hit Calabria in the 18th and 19th century released tectonic strain rates accumulated over time spans up to several times the catalog duration, and seismic potential is revised downward. The southern Tyrrhenian thrust zone and the extensional Calabrian faults, as well as the northeastern Sicilian transtensional zone between them (which includes the Messina Straits, where a destructive M7 event occurred in 1908), all have a similar seismic potential with minimum recurrence times of M ≥ 6.5 of 150–220 years. This potential is lower than that of the Southern Apennines (M ≥ 6.5 recurring every 60 to 140 years), but higher than that of southeastern Sicily (minimum M ≥ 6.5 recurrence times of 400 years). The high seismicity levels recorded in southeastern Sicily indicate some clustering and are most compatible with a tectonic scenario where the Ionian deforms internally, and motions at the Calabrian Trench are small. The estimated seismic potential for the Calabrian Trench and Central and Western Sicily are the lowest (minimum M ≥ 6.5 recurrence times of 550–800 years). Most zones are probably capable of generating earthquakes up to magnitudes 7–7.5, with the exception of Central and Western Sicily where maximum events sizes most likely do not exceed 7.  相似文献   

Clinoform nucleation and growth in coarse-grained deltas, Loreto basin, Baja California Sur, Mexico: a response to episodic accelerations in fault displacement   总被引：1，自引：0，他引：1  

Estelle Mortimer  Sanjeev Gupta†  Patience Cowie 《Basin Research》2005,17(3):337-359

We investigate the controls on the architecture of coarse‐grained delta progradational units (PUs) in the Pliocene Loreto basin (Baja California Sur, Mexico), a half‐graben located on the western margin of the Gulf of California. Dorsey et al. (1997b) argued that delta progradation and transgression cycles in the basin were driven by episodic fault‐controlled subsidence along the basin‐bounding Loreto fault. Here we test this hypothesis by a detailed analysis of the sedimentary architecture of 11 exceptionally well‐exposed, vertically arranged fluvio‐deltaic PUs, each of which shows lateral facies transition from proximal alluvial facies palaeo‐seaward into distal pro‐delta facies. Of these 11 PUs, seven exhibit a lateral transition from a shoal water to Gilbert‐delta facies associations as they are traced palaeo‐seaward. This transition is characterised by down‐transport development of foresets, which grow in height up to 35 m. Foreset units thicken in a basinward direction, with initially an oblique topset–foreset geometry that becomes increasingly sigmoidal. Each delta is capped by a shell bed that records drowning of the delta top. This systematic transition in delta architecture records increasing water depth through time during individual episodes of progradation. A mechanism that explains this transition is an accelerating rate of fault‐controlled subsidence during each PU. During episodes of low slip rate, shoal‐water deltas prograde across the submerged topography of the underlying delta unit. As displacement rate accelerates, increasing bathymetry at the delta front leads to steepening of foresets and initiation of Gilbert deltas. Subsequent delta drowning results from sediment starvation at the shoreline at high slip rates because of sediment trapping upstream. The observed delta architecture suggests that the long‐term (>100 kyr) history of slip on the Loreto fault was characterised by repetitive episodes of accelerating displacement accumulation. Such episodic fault behaviour is most likely to be because of variations in temporal and spatial strain partitioning between the Loreto fault and other faults in the Gulf of California. A physical explanation for the acceleration phenomenon involves evolving frictional properties on the episodically active Loreto fault.  相似文献   

Design principles for origin-destination flow maps     

Bernhard Jenny  Daniel M. Stephen  Ian Muehlenhaus  Brooke E. Marston  Ritesh Sharma  Eugene Zhang 《制图学和地理信息科学》2018,45(1):62-75

Origin-destination flow maps are often difficult to read due to overlapping flows. Cartographers have developed design principles in manual cartography for origin-destination flow maps to reduce overlaps and increase readability. These design principles are identified and documented using a quantitative content analysis of 97 geographic origin-destination flow maps without branching or merging flows. The effectiveness of selected design principles is verified in a user study with 215 participants. Findings show that (a) curved flows are more effective than straight flows, (b) arrows indicate direction more effectively than tapered line widths, and (c) flows between nodes are more effective than flows between areas. These findings, combined with results from user studies in graph drawing, conclude that effective and efficient origin-destination flow maps should be designed according to the following design principles: overlaps between flows are minimized; symmetric flows are preferred to asymmetric flows; longer flows are curved more than shorter or peripheral flows; acute angles between crossing flows are avoided; sharp bends in flow lines are avoided; flows do not pass under unconnected nodes; flows are radially distributed around nodes; flow direction is indicated with arrowheads; and flow width is scaled with represented quantity.  相似文献   

9000 years of changes in peat organic matter composition in Store Mosse (Sweden) traced using FTIR-ATR     

Antonio Martínez Cortizas  Jenny K. Sjöström  Eleonor E. Ryberg  Malin E. Kylander  Joeri Kaal  Olalla López-Costas  Noemi Álvarez Fernández  Richard Bindler 《Boreas: An International Journal of Quaternary Research》2021,50(4):1161-1178

Store Mosse (the ‘Great Bog’ in Swedish) is one of the most extensive bog complexes in southern Sweden (~77 km²), where pioneering palaeoenvironmental research has been carried out since the early 20th century. This includes, for example, vegetation changes, carbon and nitrogen dynamics, peat decomposition, atmospheric metal pollution, mineral dust deposition, dendrochronology, and tephrochronology. Even though organic matter (OM) represents the bulk of the peat mass and its compositional change has the potential to provide crucial ecological information on bog responses to environmental factors, peat OM molecular composition has not been addressed in detail. Here, a 568-cm-deep peat sequence was studied at high resolution, by attenuated reflectance Fourier-transform infrared spectroscopy (FTIR-ATR) in the mid-infrared region (4000–400 cm^–1). Principal components analysis was performed on selected absorbances and change-point modelling was applied to the records to determine the timing of changes. Four components accounted for peat composition: (i) depletion/accumulation of labile (i.e. carbohydrates) and recalcitrant (i.e. lignin and other aromatics, aliphatics, organic acids and some N compounds) compounds, due to peat decomposition; (ii) variations in N compounds and carbohydrates; (iii) residual variation of lignin and organic acids; and (iv) residual variation of aliphatic structures. Peat decomposition showed two main patterns: a long-term trend highly correlated to peat age (r = 0.87), and a short-term trend, which showed five main phases of increased decomposition (at ~8.4–8.1, ~7.0–5.6, ~3.5–3.1, ~2.7–2.1 and ~1.6–1.3 ka) – mostly corresponding to drier climate and its effect on bog hydrology. The high peat accumulation event (~5.6–3.9 ka), described in earlier studies, is characterized by the lowest degree of peat decomposition of the whole record. Given that FTIR-ATR is a quick, non-destructive, cost-effective technique, our results indicate that it can be applied in a systematic way (including multicore studies) to peat research and provide relevant information on the evolution of peatlands.  相似文献   

A non‐collisional,accretionary Sveconorwegian orogen – Comment     

Charlotte Möller  Bernard Bingen  Jenny Andersson  Michael B. Stephens  Giulio Viola  Anders Scherstén 《地学学报》2013,25(2):165-168

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The effect of maturation on the configurations of acyclic isoprenoid acids in sediments     

A.S. Mackenzie  R.L. Patience  D.A. Yon  J.R. Maxwell 《Geochimica et cosmochimica acta》1982,46(5):783-792

Within a variety of sedimentary rocks of differing maturity, the configurations of a suite of acyclic isoprenoid acids have been examined by gas Chromatographic (in a few cases also by combined gas chromatography-mass spectrometry) analysis of their diastereoisomeric methyl and (?)-menthyl esters. The samples include the Eocene Messel (Germany) and Green River (U.S.) shales, the Permian Irati shale (Brazil) and a number of Lower Toarcian shales from the Paris Basin. The isomer distributions show that isomerisation occurs at the chiral centres with increasing maturation (to increase the number of isomers) and that the rate of isomerisation increases for centres (C-2,C-3) closest to the carboxyl group. These results suggest that adsorption of the carboxyl group to a catalyst surface may control the isomerisation rates by way of access to the catalyst.  相似文献   

Elucidation of the Alum Shale kerogen structure using a multi-disciplinary approach     

Sunil Bharati  Richard L. Patience  Steve R. Larter  Guy Standen  Iain J. F. Poplett 《Organic Geochemistry》1995,23(11-12)

The significance and validity of integrating data obtained from a variety of analytical techniques to understand, elucidate and model kerogen's complex chemical structure is reported here using degradative (open and closed system pyrolysis, chemical oxidation), non-degradative (¹³C CP/MAS NMR) and optical (incident white light and blue light) methods. Seven Cambrian Alum Shale samples, ranging in maturity from immature to post-mature with respect to petroleum generation, were studied and were chosen for their simple geological history, uniform organic matter type and high organic carbon content. The Alum Shale kerogens, which primarily consist of algal organic matter, liberate low molecular weight gaseous and aromatic compounds on pyrolysis and give mostly branched dicarboxylic acids on chemical oxidation. ¹³C NMR spectroscopy shows that the Alum Shale kerogens are anomalously rich in oxygen-bearing functional groups (such as C = O, ArCO, CHO, CH_xO), most of which apparently remain intact within the kerogen macro-molecule (KMM) through the diagenetic and catagenetic stages. Fragments released by different degradative techniques are quantified and the aromaticity (f_a), O/C and relative proportions of various carbon types estimated by ¹³C NMR. A synthesis of these data has allowed us to better understand the chemistry of the Alum Shale kerogen.  相似文献