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1.
R. L. Frost J. Kristof G. N. Paroz J. T. Kloprogge 《Physics and Chemistry of Minerals》1999,26(3):257-263
Upon intercalation of both ordered (low defect) and disordered (high defect) kaolinites with acetamide, two types of interaction
are observed. Firstly, hydrogen bonding between the NH2 groups of the acetamide with the siloxane oxygens is formed, as evidenced by the formation of two new bands at 3400 and 3509
cm–1. Secondly, the appearance of additional bands at ∼3600 cm–1 in both the infrared and Raman spectra of the acetamide intercalates is attributed to a second type of hydrogen bonding by
the interaction of the C=O group and the inner surface hydroxyls. Changes in the intensity of the hydroxyl deformation modes
in the 895 to 940 cm–1 region are attributed to the changes in the hydrogen bonding of the kaolinite surfaces. It is proposed that the hydrogen
bonding between the adjacent kaolinite layers is replaced with hydrogen bonding between both kaolinite surfaces and the acetamide
molecule. Changes in the molecular structure of acetamide are observed upon intercalation. The amide 1 band is lost and replaced
with a well-defined NH2 deformation vibration. The loss of the amide 1 band is attributed the hydrogen bond formation between the amide hydrogens
and the siloxane surface. The bands of the C=O group at 1680 and 1740 cm–1 become a single band at 1680 cm–1. The amide 2 band remains unchanged. The lack of intensity of the 1740 cm–1 band is attributed to the formation of hydrogen bonding between the inner surface hydroxyl groups and the carbonyl group.
Received: 4 February 1998/ Revised, accepted: 30 June 1998 相似文献
2.
Soil surface roughness (SSR) is an important factor in controlling sediment and runoff generation, influencing directly a wide spectrum of erosion parameters. SSR is highly variable in time and space under natural conditions, and characterizing SSR to improve the parameterization of hydrological and erosion models has proved challenging. Our study uses recent technological and algorithmic developments in capturing and processing close aerial sensing data to evaluate how high-resolution imagery can assist the temporally and spatially explicit monitoring of SSR. We evaluated the evolution of SSR under natural rainfall and growing vegetation conditions on two arable fields in Denmark. Unmanned aerial vehicle (UAV) photogrammetry was used to monitor small field plots over 7 months after seeding of winter wheat following conventional and reduced tillage treatments. Field campaigns were conducted at least once a month from October until April, resulting in nine time steps of data acquisition. Structure from motion photogrammetry was used to derive high-resolution point clouds with an average ground sampling distance of 2.7 mm and a mean ground control point accuracy of 1.8 mm. A comprehensive workflow was developed to process the point clouds, including the detection of vegetation and the removal of vegetation-induced point cloud noise. Rasterized and filtered point clouds were then used to determine SSR geostatistically as the standard deviation of height, applying different kernel sizes and using semivariograms. The results showed an influence of kernel size on roughness, with a value range of 0.2–1 cm of average height deviation during the monitoring period. Semivariograms showed a measurable decrease in sill variance and an increase in range over time. This research demonstrated multiple challenges to measuring SSR with UAV under natural conditions with increasing vegetation cover. The proposed workflow represents a step forward in tackling those challenges and provides a knowledge base for future research. © 2020 John Wiley & Sons, Ltd. 相似文献
3.
Kristof Plankensteiner Bernd M. Rode Tomas Mikoviny Armin Hansel Georg Fischer Helmut O. Rucker 《Icarus》2007,187(2):616-619
Saturn's moon Titan has been considered as one of the few places in our Solar System, where atmospheric and surface conditions could have produced organic compounds essential as precursors for an evolution of life. The Cassini-Huygens mission has provided new data on Titan's atmosphere and surface, which enabled us to simulate the chemical processes occurring under these conditions. Possible lightning events on Titan cannot only produce higher hydrocarbons, but also allow surface water ice to participate in the reaction scenario, resulting in CHO, CHN, and CHON compounds including several molecules relevant for the formation of amino acids and nucleic acids. 相似文献
4.
Anton J. J. Van Rompaey Gert Verstraeten Kristof Van Oost Gerard Govers Jean Poesen 《地球表面变化过程与地形》2001,26(11):1221-1236
In this paper a spatially distributed model for the calculation of sediment delivery to river channels is presented (SEDEM: SEdiment DElivery Model). The model consists of two components: (1) the calculation of a spatial pattern of mean annual soil erosion rates in the catchment using a RUSLE (Revised Soil Erosion Equation) approach; and (2) the routing of the eroded sediment to the river channel network taking into account the transport capacity of each spatial unit. If the amount of routed sediment exceeds the local transport capacity, sediment deposition occurs. An existing dataset on sediment yield for 24 catchments in central Belgium was used to calibrate the transport capacity parameters of the model. A validation of the model results shows that the sediment yield for small and medium sized catchments (10–5000 ha) can be predicted with an average accuracy of 41 per cent. The predicted sediment yield values with SEDEM are significantly more accurate than the predictions using a lumped regression model. Moreover a spatially distributed approach allows simulation of the effect of different land use scenarios and soil conservation techniques. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
5.
Delineating salt-affected soils in the ganges plain by digital analysis of landsat data 总被引：1，自引：0，他引：1
A. N. Singh S. J. Kristof M. F. Baumgardner 《Journal of the Indian Society of Remote Sensing》1979,7(1):35-39
A study has been conducted to determine the feasibility of delineating salt-affected soils using computer-aided analysis of Landsat-1 data in an area of the Ganges Plain. The multispectral scanner data have been obtained on 2nd December 1972 Landsat pass. Both supervised and unsupervised classification techniques are used. Four spectral classes of salt-affected soils have been separated. The results indicate that Landsat data can be successfully used for differentiating salt-affected soils. 相似文献
6.
7.
Iris Peeters Kristof Van Oost Gerard Govers Gert Verstraeten Tom Rommens Jean Poesen 《Earth and Planetary Science Letters》2008,265(1-2):138-152
Soil erosion processes have been studied intensively throughout the last decades and rates have been measured at the plot scale as well as at larger scales. However, the relevance of this knowledge for the modelling of long-term landscape evolution remains a topic of considerable debate. Some authors state that measurements of current rates are irrelevant to landscape evolution over a longer time span, as they are inconsistent with some fundamental characteristics of landscapes, such as the fact that the long-term sediment delivery ratio needs to be equal to 1 and that extrapolation of current rates would imply that all soils in Europe should have disappeared by now (e.g. Parsons, A.J., Wainwright, J., Brazier, R.E., Powell, D.M., 2006. Is sediment delivery a fallacy? Earth Surface Processes and Landforms 31, 1325–1328). In this study, we investigate if and to what extent estimates of long-term erosion rates are consistent with information obtained over much shorter time spans for the Loam Belt of Belgium.In a first step, observed short-term and long-term patterns in the Belgian loess area are compared statistically by classifying the study area into landscape element classes and comparing average erosion values per class. This analysis shows that the erosion intensities on the two temporal scales are of the same order of magnitude for each landscape element class. Next, the spatially distributed model WaTEM LT (Water and Tillage Erosion Model Long Term) is calibrated based on the available short-term data by optimising average erosion values for the same landscape element classes. Finally, the calibrated model is used to simulate long-term landform evolution, and is validated using long-term data based on soil profile truncation. We found that the model allows simulating landscape evolution on a millennial time scale using information derived from short-term erosion and deposition data. However, it is important that land use is taken into account for the calibration in order to obtain realistic patterns on a longer time scale. Our analysis shows that, at least for the study area considered, data obtained on erosion and deposition rates over various temporal scales have the same orders of magnitude, thereby demonstrating that measurements of current rates of processes can be highly relevant for interpreting long-term landscape evolution. 相似文献
8.
Soil erosion, transport and deposition by water drastically affect the distribution of soil organic carbon (SOC) within a landscape. Moreover, soil redistribution may have a large impact on the exchange of carbon (C) between the pedosphere and the atmosphere. One of the large information gaps within this research domain, concerns the fate of SOC after erosion by water. According to different (mainly laboratory) studies, soil redistribution leads to aggregate breakdown, thereby exposing the contained SOC to mineralization. Our study aims to quantify the extent to which such increased mineralization occurs in a real field situation. Carbon dioxide (CO2)‐efflux was measured in the field after an important erosion event for a continuous period of 112 days. The specific situation on the field ensured that almost none of eroded SOC was exported from the field. Measurements of CO2‐efflux were done in areas with sediment deposition, as well as in comparable areas without sedimentation. Comparison of these measurements allowed the net effect of soil deposition on CO2‐efflux to be assessed. Field data were complemented by measurements on incubated, undisturbed soil core samples, in order to disentangle the contribution of environmental factors (moisture, temperature) from any erosional effect on CO2‐efflux. Results of these measurements on the field showed that CO2‐efflux was regulated by a complex interplay of different factors (mostly soil porosity, soil moisture and soil temperature). In combination with the incubation measurements, it could be concluded that the processes of erosion and transport indeed led to an increased mineralization of SOC, as a result of aggregate breakdown and exposure of previously encapsulated SOC. This effect was, however, much smaller than observed in previous laboratory studies. Moreover, it was only important in the first weeks, immediately after the erosion event. The calculated net erosional effect on CO2‐efflux represented a mere 1·6% of total SOC, originally present in the soil. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
9.
Bastian Baranski Theodor Foerster Bastian Schäffer Kristof Lange 《Transactions in GIS》2011,15(Z1):125-142
A lot of effort has been invested in Spatial Data Infrastructures (SDIs) during the last decade regarding interoperable standards for services and data. But still the scalability and performance of SDI services is reported to be crucial especially if they are accessed concurrently by a high number of users. Furthermore, laws and provisions such as the INSPIRE directive specify challenging requirements regarding the performance, availability and scalability of SDI services. This article presents a Hybrid Cloud architecture for matching INSPIRE‐related Quality of Service (QoS) requirements, without investing in rarely used hardware in advance, by occupying external third‐party resources on a pay‐as‐you‐go basis. The presented Hybrid Cloud is a composition of a local IT‐infrastructure (Private Cloud) and the computational resources of third‐party vendors (Public Cloud). The local infrastructure is laid out to handle the average main load of a service and in lasting peak times additional resources of external providers are allocated and integrated on demand into the local infrastructure to provide sufficient service quality automatically. A proof‐of‐concept implementation of the proposed Hybrid Cloud approach is evaluated and benchmarked with respect to INSPIRE‐related QoS requirements. 相似文献
10.
The compatibility of the fast-tachocline scenario with a flux-transport dynamo model is explored. We employ a flux-transport dynamo model coupled with simple feedback formulae relating the thickness of the tachocline to the amplitude of the magnetic field or to the Maxwell stress. The dynamo model is found to be robust against the nonlinearity introduced by this simplified fast-tachocline mechanism. Solar-like butterfly diagrams are found to persist and, even without any parameter fitting, the overall thickness of the tachocline is well within the range admitted by helioseismic constraints. In the most realistic case of a time- and latitude-dependent tachocline thickness linked to the value of the Maxwell stress, both the thickness and its latitudinal dependence are in excellent agreement with seismic results. In nonparametric models, cycle-related temporal variations in tachocline thickness are somewhat larger than admitted by helioseismic constraints; we find, however, that introducing a further parameter into our feedback formula readily allows further fine tuning of the thickness variations. 相似文献