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A precise method for the determination of total iodine in seawater, which uses a Technicon Auto-Analyser II system and is based on Truesdale and Spencer's (1974) and Truesdale and Smith's (1975) earlier works with a catalytic procedure, is described. The procedure operates over a range of 30–80 μg1?1 of iodine. As requested by Mark (1973), the way in which the procedure can be varied to suit other applications, and therefore ranges, is explained in detail. The standard deviation at the 50 μg1?1 level was found to be 0.12 μ1?1 showing that the method's precision exceeds most, if not all, previously published procedures for this variable. This high degree of resolution makes the procedure suitable for oceanic investigations. The effects of varying the reaction time, the temperature at which the reaction proceeds and the salinity of samples and standards are described. The advantages of using a Technicon Auto-Analyser II system rather than an Auto-Analyser I system are discussed. With slight modification the procedure can also be used in the measurement of river flow where sodium iodide is used as tracer in the dilution method. 相似文献
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Yun Jiang Piers Koefoed Olga Pravdivtseva Heng Chen Chun‐Hui Li Fang Huang Li‐Ping Qin Jia Liu Kun Wang 《Meteoritics & planetary science》2021,56(1):61-76
The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K2O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ41K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K2O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ41K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K2O content and K isotope compositions (0.02–0.05 wt%; δ41K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation. 相似文献
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The distributions of iodate and total inorganic iodine concentrations in the waters on the Texas?CLouisiana shelf in April, June, and August 2004 are described. Iodine?Csalinity graphs show three-end-member mixing involving onshore and offshore surface waters and deep offshore water. The April survey showed simple mixing on the surface, but in the later surveys, iodate concentrations were often much lower than predicted by the mixing curve while those for total inorganic iodine were higher. This demonstrated both iodate reduction in the water and iodide addition, although individual samples did not show equivalent speciation changes. Hydrographically, the system consists of the estuaries of the Mississippi and Atchafalaya rivers as they spill onto the shelf. The waters are stratified seasonally by a robust halocline, leading to hypoxia in the bottom waters from the combined effect of restricted downward diffusion of oxygen and the sinking of the luxuriant growth of phytoplankton induced by riverine nutrient supply. The distributions of iodate and total inorganic iodine are, therefore, interpreted in terms of water?Csediment interaction as the shelf shoals to the north. 相似文献
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The UK is committed to meeting a series of ‘high-level marine objectives’ which are required to satisfy national obligations and to meet international commitments for the marine environment. There are more than 16 such international high-level policy driven obligations and commitments, together with more than 18 European and more than 12 of national origin. In the UK, there is an assumption that the current and planned monitoring will provide evidence to demonstrate achievement against these high-level objectives. 相似文献
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Piers Sellers 《Surveys in Geophysics》1991,12(1-3):85-114
The land surface and atmosphere exchange fluxes of radiation, heat, mass (water and carbon dioxide), momentum and trace constituents over a wide range of time and space scales. These are reviewed in the context of modeling studies, where it has been shown that the vegetation on the Earth's land surface may have a significant influence on the continental climates, and large-scale field experiments, which have been used to obtain a deeper understanding of the processes controlling these exchanges and to explore means of quantifying them using satellite based remote-sensing. It is anticipated that over the next few years, the combination of global models (general circulation models combined with biosphere models) and global data sets (provided by satellites and other synoptic techniques) will yield crucial information on the Earth System and its sensitivity to perturbation. 相似文献
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Chen Zhao Katharina Lodders Hannah Bloom Heng Chen Zhen Tian Piers Koefoed Mria K. Pet&#x; Kun Wang 《Meteoritics & planetary science》2020,55(6):1404-1417
Enstatite chondrites and aubrites are meteorites that show the closest similarities to the Earth in many isotope systems that undergo mass‐independent and mass‐dependent isotopic fractionations. Due to the analytical challenges to obtain high‐precision K isotopic compositions in the past, potential differences in K isotopic compositions between enstatite meteorites and the Earth remained uncertain. We report the first high‐precision K isotopic compositions of eight enstatite chondrites and four aubrites and find that there is a significant variation of K isotopic compositions among enstatite meteorites (from ?2.34‰ to ?0.18‰). However, K isotopic compositions of nearly all enstatite meteorites scatter around the bulk silicate earth (BSE) value. The average K isotopic composition of the eight enstatite chondrites (?0.47 ± 0.57‰) is indistinguishable from the BSE value (?0.48 ± 0.03‰), thus further corroborating the isotopic similarity between Earth's building blocks and enstatite meteorite precursors. We found no correlation of K isotopic compositions with the chemical groups, petrological types, shock degrees, and terrestrial weathering conditions; however, the variation of K isotopes among enstatite meteorite can be attributed to the parent‐body processing. Our sample of the main‐group aubrite MIL 13004 is exceptional and has an extremely light K isotopic composition (δ41K = ?2.34 ± 0.12‰). We attribute this unique K isotopic feature to the presence of abundant djerfisherite inclusions in our sample because this K‐bearing sulfide mineral is predicted to be enriched in 39K during equilibrium exchange with silicates. 相似文献
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