Offshore marine conservation policies in the North East Atlantic: Emerging tensions and opportunities     

Elizabeth M. De Santo  Peter J.S. Jones 《Marine Policy》2007

An inherent tension exists between legal approaches to nature conservation and fisheries management in the European Union, as the former remains the remit of Member States while the latter is under the exclusive legislative jurisdiction of the European Community (EC). This tension is of particular importance when addressing the conservation of habitats or species that are under threat from fishing activities. This article examines recent developments in offshore marine conservation in the North-East Atlantic in light of the legislative developments and political frameworks that are currently evolving. By analysing the emergency closure of the Darwin Mounds area of cold-water corals and the UK pair-trawl ban, it becomes evident that the precautionary principle is a key factor in the tension between fisheries management and marine nature conservation, and is not always taken into account.  相似文献   

Some chemical characteristics of the brines in Bannock and Tyro Basins: salinity, sulphur compounds, Ca, F, pH, A_t, PO₄, SiO₂, NH₃     

Davide Bregant  Giulio Catalano  Giuseppe Civitarese  Anna Luchetta 《Marine Chemistry》1990,31(1-3)

Results of the chemical investigation on the Bannock and Tyro Basins are reported.Both basins were found to be hypersaline ( 10 times higher than salinity of normal seawater) and anoxic. In all investigated basins a region of transition, a few meters thick, was identified at depths > 3327 dbar. It is characterized by a sharp gradient of salinity, and all concentrations of analysed species increase strongly except for dissolved oxygen and nitrate, which immediately drop to zero. This region appears as a sharp boundary that prevents mixing. As a result, in the presence of organic matter, an anoxic condition developed with the complete depletion of dissolved oxygen. At the same time, hydrogen sulphide and ammonium accumulated within the brine. Between the Bannock and the Tyro brines differences occur in the measured concentrations of H₂S, SO²⁻₄, Ca²⁺ and NH₃. There are some differences also within the Bannock area sub-basins.The Libeccio sub-basin, in the Bannock area, contains a double-layered brine: the upper layer is 140 dbar thick and the lower layer is 300 dbar thick. A second interface between upper and lower brines develops at a depth of 3500 dbar. Nearly all of the measured concentrations vs. depth show the double layer, with the exception of ammonium, the concentration of which remains nearly constant throughout the anoxic column. Profiles of the other species analyzed show remarkable differences on passing from the upper to the lower brine. Hydrogen sulphide, sulphate and fluoride concentrations appear constant and then increase at the second interface. The calcium concentration is also constant in the upper brine, but decreases at the second interface. Total alkalinity and phosphate concentrations show a maximum peak just below the first interface. However, after passing through the second interface all the chemical parameters exhibit an almost constant behaviour down to the bottom.Hypersaline conditions are attributed to the dissolution of Messinian evaporite, and anoxia is suggested to originate from the oxidation of organic matter present in sediments and from the absence of bottom water circulation in such a deep and enclosed environment.The chemical conditions can be summarized as follows: in the Libeccio Basin the values for the species analysed have the ranges: 39–321 psu for ‘salinity’, 8.2−6.5 for pH, 2.7–4.0 mM for total alkalinity, 0.2-0 mM for dissolved oxygen, 0–1669 μM for hydrogen sulphide, 0–198 μM for thiol, 31–99 mM for sulphate, 11–21 mM for calcium, 7–100 μM for fluoride, 0.2–3080 μM for ammonium, 5.8-0 μM for nitrite, 0.2–12 μM for phosphate and 8–130 μM for silicate.  相似文献   

Light curves of SZ Piscium for 1977 and 1978     

Joel A. Eaton  Franco Scaltriti  M. Cerruti-Sola  M. B. K. Sarma  B. D. Ausekar  Santo Catalano  Marcello Rodono 《Astrophysics and Space Science》1982,82(2):289-306

We present a relatively completeV-band light curve of SZ Psc for 1978 and a partial light curve for 1977. From the 1978 light curve we derive a new time of primary minimum, JD2443823.674±0.001, and a Russell-model solution,i=75°.8±0°.1,r _h =0.096±0.003,r _c =0.351±0.001, andL _h =0.253±0.002. The hotter component of this system is a F5-8 main-sequence star, the cooler component a K3-4 star well above the main sequence. The system is detached with the larger component filling only 82% of its Roche lobe. The distortion wave in this RS CVn-type binary seems not to migrate regularly as do those in many other such systems, but rather seems to change phase and amplitude more erratically. Between 1977 and 1978 its phase stayed practically constant while its amplitude decreased by a factor of three. We discuss the implications of this behavior for the spot model of RS CVn-type activity. We find that the traditional comparison star for SZ Psc, HD 219018, is very likely a constant star contrary to a recent suggestion that it is variable. Its brightness and colors,V=7.705, (B-V)=0.628, and (V-I) _c =0.688, are those of a G2V star.Visiting Astronomer, Kitt Peak National Observatory, which is operated by AURA, Inc., under contract with the National Science Foundation, and Visiting Astronomer, Prarie Observatory, University of Illinois.  相似文献   

On the secular variations of Io and Titan     

C. Blanco  S. Catalano 《Icarus》1975,25(4):585-587

A long-term variation of the magnitude at mean opposition is shown to exist for Io and Titan. The variation of Io seems to be correlated with the orbital period of Jupiter, the maximum light occurring at perihelion.  相似文献   

Beyond world cities: Central America in a global space of flows   总被引：1，自引：0，他引：1  

Ed Brown  Peter J. Taylor  & Gilda Catalano 《Area》2002,34(2):139-148

Central America is a region without a world city. Traditionally, the region's national projects have been based upon openness to the world economy: how do the region's contemporary transnational projects connect to the world economy under the new conditions of openness that is contemporary globalization? Focusing upon advanced producer services, three connections into the world city network are identified: global service firms operating directly in Central American cities, local service firms operating indirectly through extra-regional world cities and global service firms operating through Latin American regional offices. Miami is confirmed as the primary world city through which Central America connects into the world economy  相似文献   

Paleogeography and structure of the central Mediterranean: Sicily and its offshore area   总被引：1，自引：0，他引：1  

R. Catalano  P. Di Stefano  A. Sulli  F.P. Vitale 《Tectonophysics》1996,260(4):291-323

The geology of the mainland and offshore of Sicily is illustrated by a few geologic sections and seismic profiles across the late Cenozoic orogenic belt of central and western Sicily and across the Sardinia Channel and Sicily Straits. This belt is the result of several tectonic events. Deformation involved mainly the sedimentary cover of the old African continental margin characterized by a broad basinal domain, flanked along its external (southern) margin by a shallow-water carbonate platform attached to Africa in the Triassic. Compressional deformation started in the more internal basinal rock assemblages overlying a thinned crust. The most important structural characteristic of the early phase of thrusting is the duplex pile forming the bulk of the chain in Central Western Sicily. The structure consists of a basal allochthon, made up of Permian to Middle Triassic layers, an intermediate duplex wedge, composed of competent Mesozoic carbonates, and a roof complex, including Upper Mesozoic-Lower Tertiary less competent rocks. Large-scale clockwise rotation of the thrusts accompanied transpressional movements in the hinterland during the Pliocene. Right oblique reverse faults modified the previous tectonic contacts between the allochthons in the hinterland zones. Contemporaneous south-directed imbrications affected the southern external areas, progressively incorporating foreland and piggyback basins. Development of the Gela Thrust System appears to be linked to the transpressional event; its accretion is also related to contemporaneous underthrusting at deeper levels of Mesozoic carbonate substratum. The older buried thrust sheets were pushed up to the surface breaching the deformed Tertiary cover of the Gela TS. Northwards in the belt post-Messinian normal growth faults opened half graben whose sedimentary fill underwent structural inversion. Alternation of extension and compression tectonics characterizes the Sicilian continental margin in the last million years.  相似文献   

Uranyl adsorption onto montmorillonite: Evaluation of binding sites and carbonate complexation   总被引：2，自引：0，他引：2  

Jeffrey G. Catalano  Gordon E. Brown Jr. 《Geochimica et cosmochimica acta》2005,69(12):2995-3005

The fate and transport of uranium in contaminated soils and sediments may be affected by adsorption onto the surface of minerals such as montmorillonite. Extended X-ray absorption fine structure (EXAFS) spectroscopy has been used to investigate the adsorption of uranyl (UO₂²⁺) onto Wyoming montmorillonite. At low pH (∼4) and low ionic strength (10⁻³ M), uranyl has an EXAFS spectrum indistinguishable from the aqueous uranyl cation, indicating binding via cation exchange. At near-neutral pH (∼7) and high ionic strength (1 M), the equatorial oxygen shell of uranyl is split, indicating inner-sphere binding to edge sites. Linear-combination fitting of the spectra of samples reacted under conditions where both types of binding are possible reveals that cation exchange at low ionic strengths on SWy-2 may be more important than predicted by past surface complexation models of U(VI) adsorption on related montmorillonites. Analysis of the binding site on the edges of montmorillonite suggests that U(VI) sorbs preferentially to [Fe(O,OH)₆] octahedral sites over [Al(O,OH)₆] sites. When bound to edge sites, U(VI) occurs as uranyl-carbonato ternary surface complexes in systems equilibrated with atmospheric CO₂. Polymeric surface complexes were not observed under any of the conditions studied. Current surface complexation models of uranyl sorption on clay minerals may need to be reevaluated to account for the possible increased importance of cation exchange reactions at low ionic strengths, the presence of reactive octahedral iron surface sites, and the formation of uranyl-carbonato ternary surface complexes. Considering the adsorption mechanisms observed in this study, future studies of U(VI) transport in the environment should consider how uranium retardation will be affected by changes in key solution parameters, such as pH, ionic strength, exchangeable cation composition, and the presence or absence of CO₂.  相似文献   

Palaeomagnetism and deformation of the Mesozoic continental margin in Sicily     

J.E.T. Channell  R. Catalano  B. D&#x;argenio 《Tectonophysics》1980,61(4):391-407

The pre-orogenic morphology of the west Sicilian Mesozoic continental margin was characterised by platforms and basins elongated more or less parallel to the ancient junction between ocean and continent. The deformation of this continental margin during the Miocene gave rise to a number of thrust sheets which were transported southwards where they rest against the stable Iblean plateau. Eight thrust sheets have been sampled for palaeomagnetism in order to establish the amount of rotation, relative to Iblei, which occurred during emplacement. Clockwise rotations of large magnitude appear to have taken place, and these rotations are considered to be related to the emplacement of the Calabrian—Peloritani structure onto this continental margin.  相似文献   

Trends and correlations in annual extreme precipitation indices for mainland Portugal, 1941–2007     

M. Isabel P. de Lima  Fátima Espírito Santo  Alexandre M. Ramos  Ricardo M. Trigo 《Theoretical and Applied Climatology》2015,119(1-2):55-75

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Structure and oxidation state of hematite surfaces reacted with aqueous Fe(II) at acidic and neutral pH     

Jeffrey G. Catalano  Paul Fenter  Zhan Zhang 《Geochimica et cosmochimica acta》2010,74(5):1498-182

Structural changes and surface oxidation state were examined following the reaction of hematite (0 0 1), (0 1 2), and (1 1 0) with aqueous Fe(II). X-ray reflectivity measurements indicated that Fe(II) induces changes in the structure of all three surfaces under both acidic (pH 3) and neutral (pH 7) conditions. The structural changes were generally independent of pH although the extent of surface transformation varied slightly between acidic and neutral conditions; no systematic trends with pH were observed. Induced changes on the (1 1 0) and (0 1 2) surfaces include the addition or removal of partial surface layers consistent with either growth or dissolution. In contrast, a <1 nm thick, discontinuous film formed on the (0 0 1) surface that appears to be epitaxial yet is not a perfect extension of the underlying hematite lattice, being either structurally defective, compositionally distinct, or nanoscale in size and highly relaxed. Resonant anomalous X-ray reflectivity measurements determined that the surface concentration of Fe(II) present after reaction at pH 7 was below the detection limit of approximately 0.5-1 μmol/m² on all surfaces. These observations are consistent with Fe(II) oxidative adsorption, whereby adsorbed Fe(II) is oxidized by structural Fe(III) in the hematite lattice, with the extent of this reaction controlled by surface structure at the atomic scale. The observed surface transformations at pH 3 show that Fe(II) oxidatively adsorbs on hematite surfaces at pH values where little net adsorption occurs, based on historical macroscopic Fe(II) adsorption behavior on fine-grained hematite powders. This suggests that Fe(II) plays a catalytic role, in which an electron from an adsorbed Fe(II) migrates to and reduces a lattice Fe(III) cation elsewhere, which subsequently desorbs in a scenario with zero net reduction and zero net adsorption. Given the general pH-independence and substantial mass transfer involved, this electron and atom exchange process appears to be a significant subsystem within macroscopic pH-dependent Fe(II) adsorption.  相似文献