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1.
Abstract— The low temperature fine‐grained material in unequilibrated chondrites, which occurs as matrix, rims, and dark inclusions, carries information about the solar nebula and the earliest stages of planetesimal accretion. The microdistribution of primordial noble gases among these components helps to reveal their accretionary and alteration histories. We measured the Ne and Ar isotopic ratios and concentrations of small samples of matrix, rims, and dark inclusions from the unequilibrated carbonaceous chondrites Allende (CV3), Leoville (CV3), and Renazzo (CR2) and from the ordinary chondrites Semarkona (LL3.0), Bishunpur (LL3.1), and Krymka (LL3.1) to decipher their genetic relationships. The primordial noble gas concentrations of Semarkona, and—with certain restrictions—also of Leoville, Bishunpur, and Allende decrease from rims to matrices. This indicates a progressive accretion of nebular dust from regions with decreasing noble gas contents and cannot be explained by a formation of the rims on parent bodies. The decrease is probably due to dilution of the noble‐gas‐carrying phases with noble‐gas‐poor material in the nebula. Krymka and Renazzo both show an increase of primordial noble gas concentrations from rims to matrices. In the case of Krymka, this indicates the admixture of noble gas‐rich dust to the nebular region from which first rims and then matrix accreted. This also explains the increase of the primordial elemental ratio 36Ar/ 20Ne from rims to matrix. Larger clasts of the noble‐gas‐rich dust form macroscopic dark inclusions in this meteorite, which seem to represent unusually pristine material. The interpretation of the Renazzo data is ambiguous. Rims could have formed by aqueous alteration of matrix or—as in the case of Krymka—by progressive admixture of noble gas‐rich dust to the reservoir from which the Renazzo constituents accreted. The Leoville and Krymka dark inclusions, as well as one dark inclusion of Allende, show noble gas signatures different from those of the respective host meteorites. The Allende dark inclusion probably accreted from the same region as Allende rims and matrix but suffered a higher degree of alteration. The Leoville and Krymka dark inclusions must have accreted from regions different from those of their respective rims and matrices and were later incorporated into their host meteorites. The noble gas data imply a heterogeneous reservoir with respect to its primordial noble gas content in the accretion region of the studied meteorites. Further studies will have to decide whether these differences are primary or evolved from an originally uniform reservoir.  相似文献   
2.
Mafic to intermediate enclaves are evenly distributed throughoutthe dacitic 1991–1995 lava sequence of Unzen volcano,Japan, representing hundreds of mafic recharge events over thelife of the volcano. This study documents the morphological,textural, chemical, and petrological characteristics of theenclaves and coexisting silicic host lavas. The eruptive productsdescribed in this study appear to be general products of magmamingling, as the same textural types are seen at many othervolcanoes. Two types of magmatic enclaves, referred to as Porphyriticand Equigranular, are easily distinguished texturally. Porphyriticenclaves display a wide range in composition from basalt toandesite, are glass-rich, spherical and porphyritic, and containlarge, resorbed, plagioclase phenocrysts in a matrix of acicularcrystals and glass. Equigranular enclaves are andesitic, non-porphyritic,and consist of tabular, medium-grained microphenocrysts in amatrix glass that is in equilibrium with the host dacite magma.Porphyritic enclaves are produced when intruding basaltic magmaengulfs melt and phenocrysts of resident silicic magma at theirmutual interface. Equigranular enclaves are a product of a moreprolonged mixing and gradual crystallization at a slower coolingrate within the interior of the mafic intrusion. KEY WORDS: mafic enclaves; quenched mafic inclusions; magma mingling; Unzen volcano; Unzen Scientific Drilling Project; resorbed plagioclase  相似文献   
3.
Abstract– We report concentrations and isotopic compositions of He, Ne, and Ar measured with high spatial resolution along a radial traverse of a silicon carbide (SiC) quadrant of the Genesis mission concentrator target. The Ne isotopic composition maps instrumental fractionation as a function of radial position in the target: the maximum observed isotopic fractionation is approximately 33‰ per mass unit between the center and periphery. The Ne fluence is enhanced by a factor of 43 at the target center and decreases to 5.5 times at the periphery relative to the bulk solar wind fluence. Neon isotopic profiles measured along all four arms of the “gold cross” mount which held the quadrants in the concentrator target demonstrate that the concentrator target was symmetrically irradiated during operation as designed. We used implantation experiments of Ne into SiC and gold to quantify backscatter loss and isotopic fractionation and compared measurements with numerical simulations from the code “stopping and range of ions in matter.” The 20Ne fluence curve as a function of radial distance on the target may be used to construct concentration factors relative to bulk solar wind for accurate corrections for solar wind fluences of other light elements to be measured in the concentrator target. The Ne isotopic composition as a function of the radial distance in the SiC quadrant provides a correction for the instrumental mass‐dependent isotopic fractionation by the concentrator and can be used to correct measured solar wind oxygen and nitrogen isotopic compositions to obtain bulk solar wind isotopic compositions.  相似文献   
4.
Post‐glacial, neritic cool‐water carbonates of the Western Mediterranean Sea were examined by means of hydroacoustic data, sediment surface sampling and vibrocoring to unravel geometries and to reconstruct sedimentary evolution in response to the last sea‐level rise. The analysed areas, located on the Alboran Ridge, in the Bay of Oran, and at the southern shelf of the island of Mallorca, are microtidal and bathed by oligotrophic to weakly mesotrophic waters. Seasonal water temperature varies between 13 °C and 27 °C. Echosounder profiles show that the Bay of Oran and the southern shelf of Mallorca are distally steepened ramps, while the Alboran Ridge forms a steep‐flanked rugged plateau around the Alboran Island. In the three areas, an up to 10 m thick post‐glacial sediment cover overlies an unconformity. In Oran and Mallorca, stacked lowstand wedges occur in water depths of 120 to 130 m. On the Alboran Ridge and in the Bay of Oran, highstand wedges occur at 35 to 40 m. Up to 5 m long cores of upper Pleistocene to Holocene successions were recovered in water depths between 40 and 81 m. Deposits contain more than 80% carbonate, with mixed carbonate‐volcaniclastics in the lower part of some cores in Alboran. The carbonates consist of up to 53% of aragonite and up to 83% of high magnesium calcite. Radiocarbon dating of bivalve shells, coralline algae and serpulid tubes indicates that deposits are as old as 12 400 cal yr bp . The carbonate factories in the three areas are dominated mostly by red algae, but some intervals in the cores are richer in bivalves. A facies rich in the gastropod Turritella, reflecting elevated surface productivity, is restricted to the Mallorca Shelf. Rhodoliths occur at the sediment surface in most areas at water depths shallower than 70 m; they form a 10 to 20 cm thick veneer overlying rhodolith‐poor bioclastic sediments which, nonetheless, contain abundant red algal debris. This rhodolith layer has been developing for the past 800 to 1000 years. Similar layers at different positions in the cores are interpreted as reflecting in situ growth of rhodoliths at times of reduced net sedimentation. Sedimentary successions in the cores record the post‐glacial sea‐level rise and the degree of sediment exposure to bottom currents. Deepening‐upward trends in the successions are either reflected by shallow to deep facies transitions or by a corresponding change of depth‐indicative red algae. There are only weak downcore variations of carbonate mineralogy, which indicate that no dissolution or high magnesium to low magnesium calcite neomorphism occurs in the shallow subsurface. These new data support the approach of using the Recent facies distribution for interpretation of past cool‐water, low‐energy, microtidal carbonate depositional systems. Hydroacoustic data show that previous Pleistocene transgressive and highstand inner ramp deposits and wedges were removed during sea‐level lowstands and accumulated downslope as stacked lowstand wedges; this suggests that, under conditions of high‐amplitude sea‐level fluctuations, the stratigraphic record of similar cool‐water carbonates may be biased.  相似文献   
5.
Abstract– We report Si concentrations in the metal phases of iron meteorites. Analyses were performed by secondary ion mass spectrometry using a CAMECA 1270 ion probe. The Si concentrations are low (0.09–0.46 μg g?1), with no apparent difference in concentration between magmatic and nonmagmatic iron meteorites. Coexisting kamacite and Ni‐rich metal phases have similar Si contents. Thermodynamic calculations show that Fe,Ni‐metal in equilibrium with silicate melts at temperatures where metal crystallizes should contain approximately 100 times more Si than found in iron meteorites in this work. The missing Si may either occur as tiny silicate inclusions in metal or it may have diffused as Si‐metal into surrounding silicates at low temperatures. In both cases, extensive low‐temperature diffusion of Si in metal is required. It is therefore concluded that low Si in iron meteorites is a result of subsolidus reactions during slow cooling.  相似文献   
6.
The hydrogen-to-carbon monoxide (H2/CO) emission ratio of anthropogenic combustion sources was determined from more than two years of quasi-continuous atmospheric observations in Heidelberg (49°24' N, 8°42' E), located in the polluted Rhein-Neckar region. Evaluating concurrent mixing ratio changes of H2 and CO during morning rush hours yielded mean molar H2/CO ratios of 0.40 ± 0.06, while respective results inferred from synoptic pollution events gave a mean value of 0.31 ± 0.05 mole H2/mole CO. After correction for the influence of the H2 soil sink on the measured ratios, mean values of 0.46 ± 0.07 resp. 0.48 ± 0.07 mole H2/mole CO were obtained, which are in excellent agreement with direct source studies of traffic emissions in the Heidelberg/Mannheim region (0.448 ± 0.003 mole H2/mole CO). Including results from other European studies, our best estimate of the mean H2/CO emission ratio from anthropogenic combustion sources (mainly traffic) ranges from 0.45 to 0.48 mole H2/mole CO, which is about 20% smaller than the value of 0.59 mole H2/mole CO which is frequently used as the basis to calculate global H2 emissions from anthropogenic combustion sources.  相似文献   
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9.
Aerosol–cloud–radiation interactions represent one of the largest uncertainties in the current climate assessment. Much of the complexity arises from the non-monotonic responses of clouds, precipitation and radiative fluxes to aerosol perturbations under various meteorological conditions. In this study, an aerosol-aware WRF model is used to investigate the microphysical and radiative effects of aerosols in three weather systems during the March 2000 Cloud Intensive Observational Period campaign at the US Southern Great Plains. Three simulated cloud ensembles include a low-pressure deep convective cloud system, a collection of less-precipitating stratus and shallow cumulus, and a cold frontal passage. The WRF simulations are evaluated by several ground-based measurements. The microphysical properties of cloud hydrometeors, such as their mass and number concentrations, generally show monotonic trends as a function of cloud condensation nuclei concentrations.Aerosol radiative effects do not influence the trends of cloud microphysics, except for the stratus and shallow cumulus cases where aerosol semi-direct effects are identified. The precipitation changes by aerosols vary with the cloud types and their evolving stages, with a prominent aerosol invigoration effect and associated enhanced precipitation from the convective sources. The simulated aerosol direct effect suppresses precipitation in all three cases but does not overturn the aerosol indirect effect. Cloud fraction exhibits much smaller sensitivity(typically less than 2%) to aerosol perturbations, and the responses vary with aerosol concentrations and cloud regimes. The surface shortwave radiation shows a monotonic decrease by increasing aerosols, while the magnitude of the decrease depends on the cloud type.  相似文献   
10.
In this paper, the feasibility of using magnetic resonance imaging (MRI) to study water infiltration into a heterogeneous soil is examined, together with its difficulties and limitations. MRI studies of ponded water infiltration into an undisturbed soil core show that the combination of one- and two-dimensional imaging techniques provides a visual and non-destructive means of monitoring the temporal changes of soil water content and the moisture profile, and the movement of the wetting front. Two-dimensional images show air entrapment in repetitive ponded infiltration experiments. During the early stages of infiltration, one-dimensional images of soil moisture profiles clearly indicate preferential flow phenomena. The observed advance of wetting fronts can be described by a linear relationship between the square root of infiltration time (√t) and the distance of the wetting front from the soil surface. Similarly, the cumulative infiltration is also directly proportional to √t. Furthermore, from the MRI infiltration moisture profiles, it is possible to estimate the parameters that feature in infiltration equations. © 1997 by John Wiley & Sons, Ltd.  相似文献   
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