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Historically, paired watershed studies have been used to quantify the hydrological effects of land use and management practices by concurrently monitoring 2 similar watersheds during calibration (pretreatment) and post‐treatment periods. This study characterizes seasonal water table and flow response to rainfall during the calibration period and tests a change detection technique of moving sums of recursive residuals (MOSUM) to select calibration periods for each control–treatment watershed pair when the regression coefficients for daily water table elevation were most stable to minimize regression model uncertainty. The control and treatment watersheds were 1 watershed of 3–4‐year‐old intensely managed loblolly pine (Pinus taeda L.) with natural understory, 1 watershed of 3–4‐year‐old loblolly pine intercropped with switchgrass (Panicum virgatum), 1 watershed of 14–15‐year‐old thinned loblolly pine with natural understory (control), and 1 watershed of switchgrass only. The study period spanned from 2009 to 2012. Silvicultural operational practices during this period acted as external factors, potentially shifting hydrologic calibration relationships between control and treatment watersheds. MOSUM results indicated significant changes in regression parameters due to silvicultural operations and were used to identify stable relationships for water table elevation. None of the calibration relationships developed using this method were significantly different from the classical calibration relationship based on published historical data. We attribute that to the similarity of historical and 2010–2012 leaf area index on control and treatment watersheds as moderated by the emergent vegetation. Although the MOSUM approach does not eliminate the need for true calibration data or replace the classic paired watershed approach, our results show that it may be an effective alternative approach when true data are unavailable, as it minimizes the impacts of external disturbances other than the treatment of interest.  相似文献   
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A first preliminary interlaboratory trial was planned to prepare ISO/DIS 12010: Water quality – determination of short chain polychlorinated alkanes (SCCP) in water – method using GC/MS and electron capture negative ionisation (ECNI). The task was to determine the sum of short chain polychlorinated n‐alkanes with carbon chain lengths of C10–C13 and a chlorine content between 49 and 67% in water by GC‐ECNI‐MS and quantification by multiple linear regression described in ISO/DIS 12010 as the compulsory method. Distributed samples were obtained from a real water extract spiked with a target concentration of 0.4 µg/mL sum of SCCP, i.e. the environmental quality target level according to the Water Framework Directive. The interlaboratory trial included the calibration, a column chromatographic clean up, a concentration step and an integration of chromatographic unresolved humps as well as the quantification with multiple linear regression. Reproducibility standard deviations between 21.5 and 22.9% were achieved by 17 participating laboratories from four countries. The method outlined no significant difference of the results between the standard solution and a real water matrix extract. On the basis of this succeeded preliminary interlaboratory trial the final interlaboratory trial for validation of ISO 12010 was prepared in autumn 2010.  相似文献   
4.
Abstract

In the Southwestern intermountain and high plains areas, precipitation is seasonal, with the major part of the rainfall occurring in the summer. Most winter precipitation occurs as low-intensity rain or snow along slow-moving cold fronts. Most summer precipitation occurs as short-duration, high-intensity thunderstorms from purely convective buildup or from convective cells developing along a weak fast-moving cold front. Almost all runoff occurs from the summer convective storms.

Since runoff-producing precipitation is of primary interest at the Southwest Watershed Research Center, Agricultural Research Service, Tucson, Arizona, the convective storms have been most thoroughly analyzed. Duration, intensity, areal extent, movement, character, and return frequencies for varying volumes and intensities of these convective storms are analyzed from records from dense networks of recording rain gages in four study areas in Arizona and New Mexico. The primary study areas are the 58-square-mile Walnut Gulch Experimental Watershed at Tombstone, Arizona, and the 67-squaremile Alamogordo Creek Watershed near Santa Rosa, New Mexico. Three “record” storms of differing character occurring in 1960 and 1961 on Alamogordo Creek Watershed and one “record” storm in 1961 on the Wlanut Gulch Watershed are analyzed and compared in detail.  相似文献   
5.
As in many other areas, the perennial cord grass Spartina anglica C.E. Hubbard has been extremely successful at colonising the English and Irish south coasts, but it is dying back for reasons that are not completely understood. The present study considers the relationship between die-back and metal concentrations in estuarine sediment. No obvious impact of the metal contamination on the S. anglica growth/die-back could be detected in the study zone, Poole Harbour, although the die-back did seem to have substantially influenced the metal concentrations in the sediments of the estuary. Based on core profiles, the remaining patches of S. anglica still retain elevated concentrations and the overall cadmium concentrations in the sediments have risen since 1925. However, considerable quantities of the cadmium stored in the sediment by S. anglica appear to have been washed out rapidly in the die-back zones. Should serious erosion of the saltmarsh occur, triggered for example by sea-level rise, then sudden and high levels of cadmium release may cause harmful effects to marine biota.  相似文献   
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Transport by southeastern rivers has insignificant influence on the lead concentration of southeastern shelf waters. If the rate of mobilization and transport of lead by these rivers is representative of uncontaminated fluvial transport during the Pleistocene, only about 5% of the prehistoric output of lead to the North Atlantic can be accounted for by river input.Lead concentrations in southeastern shelf waters are similar to those of North Atlantic Water from the upper 1000 m, which is probably similar to the intrusion source water for the shelf. Atmospheric inputs to the shelf of the same magnitude as observed for the Western North Atlantic are difficult to reconcile given the residence time of shelf waters and their lead concentration unless the rate of loss of lead to shelf sediments is about the same as the atmospheric flux.  相似文献   
8.
In a project to classify livestock grazing intensity using participatory geographic information systems (PGIS), we encountered the problem of how to synthesize PGIS-based maps of livestock grazing intensity that were prepared separately by local experts. We investigated the utility of evidential belief functions (EBFs) and Dempster's rule of combination to represent classification uncertainty and integrate the PGIS-based grazing intensity maps. These maps were used as individual sets of evidence in the application of EBFs to evaluate the proposition that " This area or pixel belongs to the high, medium, or low grazing intensity class because the local expert(s) says (say) so ". The class-area-weighted averages of EBFs based on each of the PGIS-based maps show that the lowest degree of classification uncertainty is associated with maps in which "vegetation species" was used as the mapping criterion. This criterion, together with local landscape attributes of livestock use may be considered as an appropriate standard measure for grazing intensity. The maps of integrated EBFs of grazing intensity show that classification uncertainty is high when the local experts apply at least two mapping criteria together. This study demonstrates the usefulness of EBFs to represent classification uncertainty and the possibility to use the EBF values in identifying and using criteria for PGIS-based mapping of livestock grazing intensity.  相似文献   
9.
Al-Qilt catchment, located east of both the Ramallah and Jerusalem districts is strongly influenced by waste waters discharged from Israeli settlements and Palestinian urban centers. In this research, our aim was to verify the chemical status of the surface sediments from the Al-Qilt catchment during 2008/2009. For this purpose, 36 surface sediment samples were collected and analyzed with ICP/MS within the fraction of below 63 μm. The extent of contamination of trace metals from Al-Qilt sediments sites were measured by evaluating the contamination factors (CF) from digestion by aqua regia and additionally by sequential extraction steps using the BCR-method. On the basis of the calculated CF, sediments appear particularly contaminated with Zn, Cu, Ag, Sn, Cd, Hg, Bi, and B. Three regions, Wadi Sweanit, Ras Al-Qilt, and Qalandiah have been identified as critical points of contamination. Trace metal inputs to the Al-Qilt catchment need to be kept under strict control in the future since Ras Al-Qilt is considered as one of the important springs in the area and is used for domestic purposes. Moreover, it will be susceptible to pollution if no action is taken to decrease the pollution at the upstream of Al-Qilt.  相似文献   
10.
The study of the expansion of the solar wind out of a system of coronal holes is continued. To this end, we consider the numerical integration of partial differential equations for problems with icosahedral symmetry, in general. First, employing Weyl theory, orbifold coordinates are introduced. Second, the icosahedral coordinates are discussed in detail. Third, following an analysis of the properties of these coordinates and the derivation of a few expressions useful for grid construction, various alternatives for the distribution of lattice points required for numerical integration are considered. A comparison of these numerical grids motivates the choice of a specific grid optimized for the numerical integration carried out in the accompanying paper by Kalish et al.(2002). This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
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