Starburst activity in a ROSAT narrow emission-line galaxy     

Katherine F. Gunn  I. M. MHardy  O. Almaini  T. Shanks  T. J. Sumner  T. W. B. Muxlow  A. Efstathiou  L. R. Jones  S. M. Croom  J. C. Manners  A. M. Newsam  K. O. Mason  S. B. G. Serjeant  M. Rowan-Robinson 《Monthly notices of the Royal Astronomical Society》2001,324(2):305-312

We present multiwaveband photometric and optical spectropolarimetric observations of the R =15.9 narrow emission-line galaxy R117_A which lies on the edge of the error circle of the ROSAT X-ray source R117. The overall spectral energy distribution of the galaxy is well modelled by a combination of a normal spiral galaxy and a moderate-strength burst of star formation. The far-infrared and radio emission is extended along the major axis of the galaxy, indicating an extended starburst.
On positional grounds, the galaxy is a good candidate for the identification of R117, and the observed X-ray flux is very close to what would be expected from a starburst of the observed far-infrared and radio fluxes. Although an obscured high-redshift QSO cannot be entirely ruled out as contributing some fraction of the X-ray flux, we find no candidates to K =20.8 within the X-ray error box, and so conclude that R117_A is responsible for a large fraction, if not all, of the X-ray emission from R117.
Searches for indicators of an obscured AGN in R117_A have so far proven negative; deep spectropolarimetric observations show no signs of broad lines to a limit of 1 per cent and, for the observed far-infrared and radio emission, we would expect 10 times greater X-ray flux if the overall emission were powered by an AGN. We therefore conclude that the X-ray emission from R117 is dominated by starburst emission from the galaxy R117_A.  相似文献   

Anoxic nitrification: Evidence from Humber Estuary sediments (UK)   总被引：3，自引：0，他引：3  

Rebecca Bartlett  Robert J.G. Mortimer  Katherine Morris 《Chemical Geology》2008,250(1-4):29-39

Conventional understanding of the nitrogen cycle in marine sediments has changed in recent years with the discovery of an alternative pathway for ammonia oxidation via the reduction of manganese oxides (during anoxic nitrification). In anoxic sediments, the potential for manganese oxides to serve as oxidant for nitrification may be considerable yet previous work on manganese-rich sediments has suggested anoxic nitrification may not be significant. In this study, the potential for anoxic nitrification in a range of sediment types was investigated. Laboratory incubation of sediment from three sites on the Humber Estuary, a microbially diverse environment, showed anoxic accumulation of nitrate, nitrite and dinitrogen gas, with and without the addition of synthetic manganese oxides. Incubation experiments confirmed anoxic nitrification as microbially mediated, with heat-killed controls yielding negative results. The anoxic nitrification reaction significantly depleted ammonia concentrations, and occurred simultaneously with manganese-, iron- and sulphate reduction, and methanogenesis. Taken in conjunction with other studies, results suggest anoxic nitrification may not only be dependent on total manganese concentrations but on manganese dynamics. Anoxic nitrification may be explained as a non-steady state reaction, dependent on the recent stability of a sediment system. Physical perturbation of sediments may cause the redistribution and/or introduction of manganese oxides and promote anoxic nitrification. The significance and persistence of anoxic nitrification is likely to depend on the frequency and magnitude of sediment perturbation, which explains why the reaction varies so widely across studied sites, and why it may not occur in some manganese-rich sediment.  相似文献   

The impact of salt water inflows on the distribution of polycyclic aromatic hydrocarbons in the deep water of the Baltic Sea     

Gesine Witt  Wolfgang Matthus 《Marine Chemistry》2001,74(4):246

Salt-water inflows into the Baltic Sea are important events for renewing the deep and bottom waters of the deep basins of the Baltic Sea. These events occur only at irregular intervals. The last strong event was in January 1993 followed by minor inflows in winter 1993/1994. As a result of these inflows, the deep water of the central Baltic basins was completely renewed.Based on extensive observations of polycyclic aromatic hydrocarbons (PAHs) in water, fluffy layer material and surface sediments between 1992 and 1998, the transformation of PAHs and the modification of their distribution in the Baltic deep water is discussed in connection with the spreading of the inflowing highly saline and oxygen-rich water along its pathway from the sills into the central basins. In the course of the inflows in 1993/1994, the PAH concentration in the deep water of the different basins increased significantly. The concentrations were elevated, at least by a factor of 2 and as much as seven to eight times (for the four-ring PAHs) compared to the previous and the following years. Two hypotheses for the causes were discussed: the inflowing salt water may have entrained more highly polluted surface water in the western Baltic Sea, or it may have entrained contaminated fluffy layer material or sediment particles along the route of transport.  相似文献   

Cross-shelf distribution of copepods and the role of event-scale winds in a northern California upwelling zone     

Katherine M. Papastephanou  Stephen M. Bollens  Anne M. Slaughter 《Deep Sea Research Part II: Topical Studies in Oceanography》2006,53(25-26):3078

Cross-shelf distribution and abundance of copepod nauplii and copepodids were measured during three summer upwelling seasons (2000–2002) in a coastal upwelling zone off northern California. These 3 years varied considerably in the intensity of winds, abundance of chlorophyll, and water temperature. The cruises in 2000 were characterized by relaxation conditions, with generally high levels of chlorophyll and high water temperature. The cruises in 2001 and 2002 were dominated by strong and persistent upwelling events, leading to lower chlorophyll and water temperatures. The copepod assemblage was dominated by Oithona spp., Acartia spp. and Pseudocalanus spp., with Metridia pacifica (lucens), Microsetella rosea, Oncaea spp. and Tortanus discaudatus also common during all 3 years. The cross-shelf distribution of copepods was generally shifted offshore during upwelling and onshore during relaxation events, although some variability between species occurred. Abundance of all life stages generally exhibited a negative correlation with cross-shelf transport averaged over at least 1–4 days and lagged by 0–3 days, indicating lower abundances during and immediately after active upwelling. However, copepod nauplii seemed to respond positively to wind events lasting 1–5 days followed by a period of relaxation lasting 6 or 7 days. These rapid rates of change in abundance are probably too great to be due to in situ growth and reproduction alone; physical processes must also play a role. These results suggest a highly dynamic relationship between copepods and upwelling events off northern California, with species-specific responses to upwelling to be expected.  相似文献   

Trends in the solubility of iron,aluminium, manganese and phosphorus in aerosol collected over the Atlantic Ocean     

A.R. Baker  T.D. Jickells  M. Witt  K.L. Linge 《Marine Chemistry》2006

The solubility of iron, aluminium, manganese and phosphorus has been determined in aerosol samples collected between 49°N and 52°S during three cruises conducted in the Atlantic Ocean as part of the European Union funded IRONAGES programme. Solubilities (defined at pH 4.7) determined for Fe and Al in samples of Saharan dust were significantly lower (medians 1.7% and 3.0%, respectively) than the solubilities of these metals in aerosols from other source regions (whole dataset medians 5.2% and 9.0%, respectively). Mn solubility also varied with aerosol source, but the median solubility of Mn in Saharan dust was very similar to the median for the dataset as a whole (55% and 56%, respectively). The observed solubility of aerosol P was ∼ 32%, with P solubility in Saharan aerosol perhaps as low as 10%. Laboratory studies have indicated that aerosol Fe solubility is enhanced by acid processing. No relationship could be found between Fe solubility and the concentrations of acid species (non-seasalt SO₄²⁻, NO₃⁻) nor the net acidity of the aerosol, so we are unable to confirm that this process is significant in the atmosphere. In terms of the supply of soluble Fe to oceanic ecosystems on a global scale, the observed higher solubility for Fe in non-Saharan aerosols is probably not significant because the Sahara is easily the dominant source of Fe to the Atlantic. On a smaller scale however, higher solubility for aerosol Fe may alter our understanding of Fe cycling in regions such as the remote Southern Ocean.  相似文献   

Influence of physiology and climate on δD of leaf wax n-alkanes from C₃ and C₄ grasses     

Francesca A. Smith  Katherine H. Freeman 《Geochimica et cosmochimica acta》2006,70(5):1172-1187

We measured hydrogen isotope compositions (δD) of high-molecular-weight n-alkanes (C₂₇-C₃₃) from grasses grown in greenhouses and collected from the US Great Plains. In both cases, n-alkanes from C₄ grasses are enriched in D by more than 20‰ relative to those from C₃ grasses. The apparent enrichment factor (ε_C29-GW) between C₂₉n-alkane and greenhouse water is −165 ± 12‰ for C₃ grasses and −140 ± 15‰ for C₄ grasses. For samples from the Great Plains, δD values of C₂₉n-alkanes range from −280 to −136‰, with values for C₄ grasses ca. 21‰ more positive than those for C₃ grasses from the same site. Differences in C₃ and C₄ grass n-alkane δD values are consistent with the shorter interveinal distance in C₄ grass leaves, and greater back-diffusion of enriched water from stomata to veins, than in C₃ grass leaves. Great Plains’ grass n-alkane isotopic ratios largely reflect precipitation δD values. However, the offset or apparent fractionation between n-alkanes and precipitation is not uniform and varies with annual precipitation and relative humidity, suggesting climatic controls on lipid δD values. The dryer sites exhibit smaller absolute apparent fractionation indicative of D-enrichment of source waters through transpiration and/or soil evaporation. To explore the relationship between climate and n-alkane δD values, we develop three models. (1) The ‘direct analog’ model estimates δD_C29 values simply by applying the apparent enrichment factors, ε_C29-GW, observed in greenhouse grasses to precipitation δD values from the Great Plains. (2) The ‘leaf-water’ model uses a Craig-Gordon model to estimate transpirational D-enrichment for both greenhouse and field sites. The transpiration-corrected enrichment factors between C₂₉ and bulk leaf-water, ε_C29-GW, calculated from the greenhouse samples (−181‰ for C₃ and −157‰ for C₄) are applied to estimate δD_C29 values relative to modeled bulk leaf-water δD values. (3) The ‘soil- and leaf-water’ model estimates the combined effects of soil evaporation, modeled by analogy with a flow-through lake, and transpiration on δD_C29 values. Predictions improve with the addition of the explicit consideration of transpiration and soil evaporation, indicating that they are both important processes in determining plant lipid δD values. D-enrichment caused by these evaporative processes is controlled by relative humidity, suggesting that important climatic information is recorded in leaf wax n-alkane δD values. Calibration studies such as this one provide a baseline for future studies of plant-water-deuterium systematics and form the foundation for interpretation of plant wax hydrogen isotope ratios as a paleo-aridity proxy.  相似文献   

δC of low-molecular-weight organic acids generated by the hydrous pyrolysis of oil-prone source rocks     

Robert F Dias  Katherine H FreemanMichael D Lewan  Stephen G Franks 《Geochimica et cosmochimica acta》2002,66(15):2755-2769

Low-molecular-weight (LMW) aqueous organic acids were generated from six oil-prone source rocks under hydrous-pyrolysis conditions. Differences in total organic carbon-normalized acid generation are a function of the initial thermal maturity of the source rock and the oxygen content of the kerogen (OI). Carbon-isotope analyses were used to identify potential generation mechanisms and other chemical reactions that might influence the occurrence of LMW organic acids. The generated LMW acids display increasing ¹³C content as a function of decreasing molecular weight and increasing thermal maturity. The magnitudes of observed isotope fractionations are source-rock dependent. These data are consistent with δ¹³C values of organic acids presented in a field study of the San Joaquin Basin and likely reflect the contributions from alkyl-carbons and carboxyl-carbons with distinct δ¹³C values. The data do not support any particular organic acid generation mechanism. The isotopic trends observed as a function of molecular weight, thermal maturity, and rock type are not supported by either generation mechanisms or destructive decarboxylation. It is therefore proposed that organic acids experience isotopic fractionation during generation consistent with a primary kinetic isotope effect and subsequently undergo an exchange reaction between the carboxyl carbon and dissolved inorganic carbon that significantly influences the carbon isotope composition observed for the entire molecule. Although generation and decarboxylation may influence the δ¹³C values of organic acids, in the hydrous pyrolysis system described, the nondestructive, pH-dependent exchange of carboxyl carbon with inorganic carbon appears to be the most important reaction mechanism controlling the δ¹³C values of the organic acids.  相似文献   

A GIS Analysis to Evaluate Areas Suitable for Crushed Stone Aggregate Quarries in New England,USA     

Robinson  Gilpin R.  Kapo  Katherine E.  Raines  Gary L. 《Natural Resources Research》2004,13(3):143-159

Aggregate is a low unit-value mineral commodity. Costs to move aggregate from the mine site to the point of use is a large fraction of the resource cost to users. Production sites for aggregate occur where suitable source materials exist and where transportation and market conditions are favorable. The increasing demand for aggregate and the difficulty of developing and permitting new sites and of renewal of permits on existing sites of aggregate production indicates that aggregate will be supplied from sources yet to be developed or delineated in many areas. Site development and permitting for aggregate production is difficult because many land management plans and zoning actions fail to anticipate prospective source areas for aggregate in a way that is consistent with both the source rock quality and the transportation and socioeconomic factors that define the economic viability of the industry. Spatial analysis provides a method to integrate both geology and economic (transportation and marketplace) parameters in a regional model. Weights of evidence (WofE) analysis has been used to measure the spatial correlation of geologic map, transportation network, and population data with current production sites for crushed stone aggregate in the New England region of the northeastern United States. Weighted logistic regression (WLR) is used with the WofE results to rank areas in terms of their relative suitability for production of crushed stone. Spatial analysis indicates that 85% of the 106 crushed stone aggregate quarries in New England are sited within 1.6 km (1 mile) of either a principal highway or rail line in the region. Seventy-eight percent of crushed stone aggregate quarries are sited in census tracts with population densities exceeding 100 people/mile². These relations illustrate the importance of proximity to both transportation corridors and developing areas where aggregate is predominately used. Only one active crushed stone quarry is located in a census tract with a population density less than 15 people/mile², reflecting the lack of sufficient market demand in many rural areas to develop an operation there. However, since 1990, almost all new quarries have been developed in census tracts with population densities less than 200 people/mile², indicating the difficulty of permitting new quarry sites in highly populated areas. Crushed stone aggregate is produced predominately from three hard rock types that are distributed widely in New England; 28% of sites use granitic rock, 25% use carbonate rocks, and 25% use mafic rock types that are categorized as trap rock by the aggregate industry. The other crushed stone aggregate sources include a variety of fine-grained metamorphic rock types. Carbonate rocks and Jurassic basalt (the primary trap rock source) are the most prevalent source rocks on an area-weighted basis. Spatial analysis can be used on a regional scale to rank areas by their relative suitabilityfor crushed stone aggregate production based on geology, transportation, and population parameters. The results of this regional analysis can identify areas for more detailed evaluation. As transportation or population features change, the model can be revised easily to reflect these changes.  相似文献   

Molecular formulae of marine and terrigenous dissolved organic matter detected by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry     

Boris P. Koch  Matthias Witt  Thorsten Dittmar 《Geochimica et cosmochimica acta》2005,69(13):3299-3308

The chemical structure of refractory marine dissolved organic matter (DOM) is still largely unknown. Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR-MS) was used to resolve the complex mixtures of DOM and provide valuable information on elemental compositions on a molecular scale. We characterized and compared DOM from two sharply contrasting aquatic environments, algal-derived DOM from the Weddell Sea (Antarctica) and terrigenous DOM from pore water of a tropical mangrove area in northern Brazil. Several thousand molecular formulas in the mass range of 300-600 Da were identified and reproduced in element ratio plots. On the basis of molecular elemental composition and double-bond equivalents (DBE) we calculated an average composition for marine DOM. O/C ratios in the marine samples were lower (0.36 ± 0.01) than in the mangrove pore-water sample (0.42). A small proportion of chemical formulas with higher molecular mass in the marine samples were characterized by very low O/C and H/C ratios probably reflecting amphiphilic properties. The average number of unsaturations in the marine samples was surprisingly high (DBE = 9.9; mangrove pore water: DBE = 9.4) most likely due to a significant contribution of carbonyl carbon. There was no significant difference in elemental composition between surface and deep-water DOM in the Weddell Sea. Although there were some molecules with unique marine elemental composition, there was a conspicuous degree of similarity between the terrigenous and algal-derived end members. Approximately one third of the molecular formulas were present in all marine as well as in the mangrove samples. We infer that different forms of microbial degradation ultimately lead to similar structural features that are intrinsically refractory, independent of the source of the organic matter and the environmental conditions where degradation took place.  相似文献   

Do southern Appalachian Mountain summer stream temperatures respond to removal of understory rhododendron thickets?     

Scott Raulerson  C. Rhett Jackson  Nathan D. Melear  Seth E. Younger  Maura Dudley  Katherine J. Elliott 《水文研究》2020,34(14):3045-3060

Dense understory thickets of the native evergreen shrub Rhododendron maximum expanded initially following elimination of American chestnut by the chestnut blight, and later in response to loss of the eastern hemlock due to hemlock woolly adelgid invasion. Rhododendron thickets often blanket streams and their riparian zones, creating cool, low-light microclimates. To determine the effect of such understory thickets on summer stream temperatures, we removed riparian rhododendron understory on 300 m reaches of two southern Appalachian Mountain headwater streams, while leaving two 300 m reference reaches undisturbed. Overhead canopy was left intact in all four streams, but all streams were selected to have a significant component of dead or dying eastern hemlock in the overstory, creating time-varying canopy gaps throughout the reach. We continuously monitored temperatures upstream, within and downstream of treatment and reference reaches. Temperatures were monitored in all four streams in the summer before treatments were imposed (2014), and for two summers following treatment (2015, 2016). Temperatures varied significantly across and within streams prior to treatment and across years for the reference streams. After rhododendron removal, increases in summer stream temperatures were observed at some locations within the treatment reaches, but these increases did not persist downstream and varied by watershed, sensor, and year. Significant increases in daily maxima in treatment reaches ranged from 0.9 to 2.6°C. Overhead canopy provided enough shade to prevent rhododendron removal from increasing summer temperatures to levels deleterious to native cold-water fauna (average summer temperatures remained below 16°C), and local temperature effects were not persistent.  相似文献