The use of Auger spectroscopy for the in situ elemental characterization of sub‐micrometer presolar grains     

Frank J. STADERMANN  Christine FLOSS  Maitrayee BOSE  A. Scott LEA 《Meteoritics & planetary science》2009,44(7):1033-1049

Abstract— Presolar grains are small samples of stardust that can be found at low abundances in some of the most unaltered types of extraterrestrial materials. While earlier laboratory studies of stardust mainly focused on grain types that can be extracted from bulk meteorites by acid dissolution techniques, such as silicon carbide and graphite, recent analyses of presolar silicates rely on isotope imaging searches for locating these grains in situ. Since presolar silicates are generally less than a micrometer in diameter and represent at best only a few hundred ppm of their host materials (e.g., primitive meteorites or interplanetary dust particles), locating and studying these particles can be analytically challenging. Recently, we began using scanning Auger spectroscopy for the in situ elemental characterization of presolar silicate grains as a complement to NanoSIMS isotopic studies for obtaining spatially matched compositional data. Auger spectroscopy is a well‐established analytical technique for elemental characterizations in the material sciences, but has not been widely used in geological applications. We discuss the application of this technique to sub‐micrometer sized silicate grains and address practical issues such as sample preparation, measurement settings, spatial resolution, data processing, and elemental quantification.  相似文献   

Potassic Magmatism in Western Sichuan and Yunnan Provinces, SE Tibet, China: Petrological and Geochemical Constraints on Petrogenesis   总被引：31，自引：1，他引：30  

GUO  ZHENGFU; HERTOGEN  JAN; LIU  JIAQI; PASTEELS  PAUL; BOVEN  ARIEL; PUNZALAN  LEA; HE  HUAIYU; LUO  XIANGJUN; ZHANG  WENHUA 《Journal of Petrology》2005,46(1):33-78

Potassic volcanism in the western Sichuan and Yunnan Provinces,SE Tibet, forms part of an extensive magmatic province in theeastern Indo-Asian collision zone during the Paleogene (40–24Ma). The dominant rock types are phlogopite-, clinopyroxene-and olivine-phyric calc-alkaline (shoshonitic) lamprophyres.They are relatively depleted in Na₂O, Fe₂O₃, and Al₂O₃ comparedwith the late Permian–early Triassic Emeishan continentalflood basalts in the western part of the Yangtze craton, andhave very high and variable abundances of incompatible traceelements. Primitive mantle-normalized incompatible element patternshave marked negative Nb, Ta and Ti anomalies similar to thoseof K-rich subduction-related magmas, although the geodynamicsetting is clearly post-collisional. Spatially, some incompatibletrace element abundances, together with inferred depths of meltsegregation based on the Mg-15 normalized compositions of thesamples, display progressive zonation trends from SW to NE withincreasing distance from the western boundary of the Yangtzecraton. Systematic variations in major and trace element abundancesand Sr–Nd–Pb isotope compositions appear to havepetrogenetic significance. The systematic increases in incompatibletrace element abundances from the western margin to the interiorof the Yangtze craton can be explained by progressively decreasingextents of partial melting, whereas steady changes in some incompatibletrace element ratios can be attributed to changes in the amountof subduction-derived fluid added to the lithospheric mantleof the Yangtze craton. The mantle source region of the lamprophyresis considered to be a relatively refractory phlogopite-bearingspinel peridotite, heterogeneously enriched by fluids derivedfrom earlier phases of late Proterozoic and Palaeozoic subductionbeneath the western part of the Yangtze craton. Calculationsbased on a non-modal batch melting model show that the degreeof partial melting ranges from 0·6% to 15% and the proportionof subduction-derived fluid added from0·1% to 0·7%(higher-Ba fluid) or from 5% to 25% (lower-Ba fluid) from theinterior to the western margin of the Yangtze craton. Some pre-existinglithospheric faults might have been reactivated in the areaneighbouring the Ailao Shan–Red River (ASRR) strike-slipbelt, accompanying collision-induced extrusion of the Indo-Chinablock and left-lateral strike-slip along the ASRR shear zone.This, in turn, could have triggered decompression melting ofthe previously enriched mantle lithosphere, resulting in calc-alkalinelamprophyric magmatism in the western part of the Yangtze craton. KEY WORDS: Tibet; potassic magmatism; lithospheric mantle; metasomatism  相似文献   

Sensitivity analysis of the climate of a chaotic system     

DANIEL J. LEA  MYLES R. ALLEN  THOMAS W. N. HAINE 《地球，A辑:动力气象学与海洋学》2000,52(5):523-532

This paper addresses some fundamental methodological issues concerning the sensitivity analysis of chaotic geophysical systems. We show, using the Lorenz system as an example, that a naïve approach to variational ("adjoint") sensitivity analysis is of limited utility. Applied to trajectories which are long relative to the predictability time scales of the system, cumulative error growth means that adjoint results diverge exponentially from the "macroscopic climate sensitivity"(that is, the sensitivity of time‐averaged properties of the system to finite‐amplitude perturbations). This problem occurs even for time‐averaged quantities and given infinite computing resources. Alternatively, applied to very short trajectories, the adjoint provides an incorrect estimate of the sensitivity, even if averaged over large numbers of initial conditions, because a finite time scale is required for the model climate to respond fully to certain perturbations. In the Lorenz (1963) system, an intermediate time scale is found on which an ensemble of adjoint gradients can give a reasonably accurate (O(10%)) estimate of the macroscopic climate sensitivity. While this ensemble‐adjoint approach is unlikely to be reliable for more complex systems, it may provide useful guidance in identifying important parameter‐combinations to be explored further through direct finite‐amplitude perturbations.  相似文献   

Stardust in Antarctic micrometeorites     

Toru YADA  Christine FLOSS  Frank J. STADERMANN  Ernst ZINNER  Tomoki NAKAMURA  Takaaki NOGUCHI  A. Scott LEA 《Meteoritics & planetary science》2008,43(8):1287-1298

Abstract— We report the discovery of presolar silicate, oxide (hibonite), and (possibly) SiC grains in four Antarctic micrometeorites (AMMs). The oxygen isotopic compositions of the eighteen presolar silicate (and one oxide) grains found are similar those observed previously in primitive meteorites and interplanetary dust particles, and indicate origins in oxygen‐rich red giant or asymptotic giant branch stars, or in supernovae. Four grains with anomalous C isotopic compositions were also detected. ¹²C/¹³C as well as Si ratios are similar to those of mainstream SiC grains; the N isotopic composition of one grain is also consistent with a mainstream SiC classification. Presolar silicate grains were found in three of the seven AMMs studied, and are heterogeneously distributed within these micrometeorites. Fourteen of the 18 presolar silicate grains and 3 of the 4 C‐anomalous grains were found within one AMM, T98G8. Presolar silicate‐bearing micrometeorites contain crystalline silicates that give sharp X‐ray diffractions and do not contain magnesiowüstite, which forms mainly through the decomposition of phyllosilicates and carbonates. The occurrence of this mineral in AMMs without presolar silicates suggests that secondary parent body processes probably determine the presence or absence of presolar silicates in Antarctic micrometeorites.  相似文献   

RECENT SPEED‐UP OF AN ALPINE ROCK GLACIER: AN UPDATED CHRONOLOGY OF THE KINEMATICS OF OUTER HOCHEBENKAR ROCK GLACIER BASED ON GEODETIC MEASUREMENTS          下载免费PDF全文

LEA HARTL  ANDREA FISCHER  MARTIN STOCKER‐WALDHUBER  JAKOB ABERMANN 《Geografiska Annaler: Series A, Physical Geography》2016,98(2):129-141

Surface velocities have been regularly monitored at the rock glacier in Outer Hochebenkar, Ötztal Alps, Austria since the early 1950s. This study provides an update to previously published surface velocity time series, showing mean profile velocities of four cross profiles since the beginning of the measurements (1951,1954, 1997; depending on the profile), as well as single block displacements from 1998 to 2015. Profiles P1, P2 and P3 have moved between 42 and 90 m, at mean velocities between 0.70 and 1.48 m yr^–1, since they were first established in the early 1950s (1951/54). Profile P0, established in 1997, has since moved 13 m or 0.75 m yr^–1. An acceleration can be observed at all profiles since the late 1990s, with a particularly sharp velocity increase since 2010. All profiles reached a new maximum velocity in 2015, with 1.98 m yr^–1 at the slowest profile (P0) and 6.37 m yr^–1 at the fastest profile (P1). Year‐to‐year variations in profile velocities cannot be clearly attributed to inter‐annual variations of climatic parameters like mean annual air temperature, summer temperature, positive degree days, or precipitation. However, higher correlation is found between velocities and cumulative anomalies of air temperature (mean annual air temperature and positive degree days) and summer precipitation, suggesting that these parameters play a key role for the movement of the rock glacier. The lower profiles (P0, P1) show more pronounced year‐to‐year variations than the upper profiles (P2, P3). It is considered likely that processes other than climatic forcing (e.g. sliding, topography) contribute to the different velocity patterns at the four profiles.  相似文献   

'The gloomy forebodings of this dread disease', climate, famine and sleeping sickness in East Africa     

GEORGINA H ENDFIELD  DAVID B RYVES†  KEELY MILLS†  LEA BERRANG-FORD‡ 《The Geographical journal》2009,175(3):181-195

Identifying the nature of the association between climate, environmental, socio-economic and political context and disease remains a major challenge, yet a better comprehension of the linkages is imperative if predictive models to guide public health responses are to be devised. Our understanding of the relationships could be improved through investigations of historical epidemics. In this paper we draw on a range of published and unpublished documents to explore the complex relationship between climate, environmental change and epidemic disease (re)emergence in East Africa, and Uganda in particular. This is a region which has experienced climate variability at a range of temporal and spatial scales, but which also has a long history of episodic epidemic disease. We focus on the late nineteenth and early twentieth centuries – a time of social, economic and political reordering in East Africa associated with European colonial intervention, but also a period which witnessed a variety of climatic, ecological and disease events. It will be argued that these developments coalesced, creating a set of spatially distinctive social and environmental conditions which fostered the emergence and prolongation of one of the most deadly episodes of disease in East African history, the sleeping sickness epidemic of c.1900–20.  相似文献