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1 INTRODUCTION Agricultural use of pesticides has been recognized as one of the important non-point pollution sources in the world, and the pesticide application to agricultural lands has led to large amounts of residues discharged into surface water through runoff (Leonard, 1990). There have been growing concerns about the fate and transport of pesticides in agricultural lands, due to the associated adverse impacts on water environment and human health (Agassi et al., 1995; Ng and Clegg…  相似文献   
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Deep, elongated incisions, often referred to as tunnel valleys, are among the most characteristic landforms of formerly glaciated terrains. It is commonly thought that tunnel valleys were formed by meltwater flowing underneath large ice sheets. The sedimentary infill of these features is often highly intricate and therefore difficult to predict. This study intends to improve the comprehension of the sedimentology and to establish a conceptual model of tunnel‐valley infill, which can be used as a predictive tool. To this end, the densely sampled, Pleistocene tunnel valleys in Hamburg (north‐west Germany) were investigated using a dataset of 1057 deep wells containing lithological and geophysical data. The stratigraphic correlations and the resulting three‐dimensional lithological model were used to assess the spatial lithological distributions and sedimentary architecture. The sedimentary succession filling the Hamburg area tunnel valleys can be subdivided into three distinct units, which are distinguished by their inferred depositional proximity to the ice margin. The overall trend of the succession shows a progressive decrease in transport energy and glacial influence through time. The rate of glacial recession appears to have been an important control on the sedimentary architecture of the tunnel‐valley fill. During periods of stagnation, thick ice‐proximal deposits accumulated at the ice margin, while during rapid recession, only a thin veneer of such coarse‐grained sediments was deposited. Ice‐distal and non‐glaciogenic deposits (i.e. lacustrine, marine and terrestrial) fill the remaining part of the incision. The infill architecture suggests formation and subsequent infill of the tunnel valleys at the outer margin of the Elsterian ice sheet during its punctuated northwards recession. The proposed model shows how the history of ice‐sheet recession determines the position of coarse‐grained depocentres, while the post‐glacial history controls the deposition of fines through a progressive infill of remnant depressions.  相似文献   
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The amounts of microbial and root‐respired CO2 in a maize/winter wheat agricultural system in south western Germany were investigated by measurements of the CO2 mixing ratio and the 13C/12C ratio in soil air. CO2 fluxes at the soil surface for the period of investigation (1993–1995) were also determined. Root respired CO2 shows a strong correlation with the plant mass above ground surface of the respective vegetation (R2≥0.88); the maximum CO2 release from roots was in August for the maize (2.0±0.5 mmol m−2 h−1) and in June for winter wheat (1.5±0.5 mmol m−2 h−1). Maximum CO2 production by roots correlate well with the maximum amount of plant root matter. Integrating the CO2 production over the whole growing season and normalizing to the dry root matter yields, the CO2 production per gram dry organic root matter (DORM) of maize was found to be 0.14±0.03 gC (g DORM)−1. At the sites investigated, root‐produced CO2 contributed (16±4)% for maize, and (24±4)% for winter wheat, respectively, to the total annual CO2 production in the soil (450±50 gC m−2 for maize, 210±30 gC m−2 for winter wheat).  相似文献   
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An 'alternate grid' (GridAlt) technique is presented, which allows the different components of a general circulation model's governing equations to be computed on distinct grids chosen for that component or process. In the implementation presented here, the tendencies of state variables from the physical parametrizations are computed on a vertical grid with very fine resolution near the surface, whereas the remaining terms in the equations of motion are computed using an Eta coordinate with coarser vertical resolution.
Results from a suite of aquaplanet experiments show that much of the benefit of increased vertical resolution in the whole model can be realized by enhancing the vertical resolution of the 'physics grid' using GridAlt. The benefit is realized in the fields which are computed directly in the physical parametrizations, and in the vertical structure of the relative humidity and mass streamfunction. Results from a suite of realistically configured simulations demonstrated an impact of GridAlt that was similar to its impact in the simplified simulations, as well as an improved response to El Niño Southern Oscillation forcing. It is concluded that the present implementation of GridAlt offers a practical way to allow GCMs to better capture the near-surface structure of the atmosphere.  相似文献   
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Two Palaeogene fluvial fan systems linked to the south‐Pyrenean margin are recognized in the eastern Ebro Basin: the Cardona–Súria and Solsona–Sanaüja fans. These had radii of 40 and 35 km and were 800 and 600 km2 in area respectively. During the Priabonian to the Middle Rupelian, the fluvial fans built into a hydrologically closed foreland basin, and shallow lacustrine systems persisted in the basin centre. In the studied area, both fans are part of the same upward‐coarsening megasequence (up to 800 m thick), driven by hinterland drainage expansion and foreland propagation of Pyrenean thrusts. Fourteen sedimentary facies have been grouped into seven facies associations corresponding to medial fluvial fan, channelized terminal lobe, non‐channelized terminal lobe, mudflat, deltaic, evaporitic playa‐lake and carbonate‐rich, shallow lacustrine environments. Lateral correlations define two styles of alluvial‐lacustrine transition. During low lake‐level stages, terminal lobes developed, whereas during lake highstands, fluvial‐dominated deltas and interdistributary bays were formed. Terminal lobe deposits are characterized by extensive (100–600 m wide) sheet‐like fine sandstone beds formed by sub‐aqueous, quasi‐steady, hyperpycnal turbidity currents. Sedimentary structures and trace fossils indicate rapid desiccation and sub‐aerial exposure of the lobe deposits. These deposits are arranged in coarsening–fining sequences (metres to tens of metres in thickness) controlled by a combination of tectonics, climatic oscillations and autocyclic sedimentary processes. The presence of anomalously deeply incised distributary channels associated with distal terminal lobe or mudflat deposits indicates rapid lake‐level falls. Deltaic deposits form progradational coarsening‐upward sequences (several metres thick) characterized by channel and friction‐dominated mouth‐bar facies overlying white‐grey offshore lacustrine facies. Deltaic bar deposits are less extensive (50–300 m wide) than the terminal lobes and were also deposited by hyperpycnal currents, although they lack evidence of emergence. Sandy deltaic deposits accumulated locally at the mouths of main feeder distal fan streams and were separated by muddy interdistributary bays; whereas the terminal lobe sheets expand from a series of mid‐fan intersection points and coalesced to form a more continuous sandy fan fringe.  相似文献   
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The Early Jurassic dolomitized carbonates are a hydrocarbon exploration target in Northern Italy. Of these carbonates, the Liassic Albenza Formation platform and the overlying Sedrina Formation shelf were studied to define a pervasive dolomitization model and to shed light on dolomite distribution in the sub‐surface. Field work, as well as analyses of well cores, stable isotopes, trace elements and fluid inclusions, was carried out on the outcropping thrust belt and sub‐surface deformed foreland of the Southern Alps. Petrographic analyses showed a first, pervasive, replacement dolomitization phase (D1) followed by volumetrically less important dolomite cement precipitation phases (D2, D3 and D4). The δ18O values fall between ?8·2‰ and 0·1‰ Vienna‐Pee Dee Belemnite with the more depleted samples belonging to dolomite cement‐rich dolostones; the δ13C ranges from 2·6‰ to 3·7‰ Vienna‐Pee Dee Belemnite. Analysis of trace elements showed different Fe and Mn contents in the sub‐surface and outcropping dolostones, and a higher Fe in the younger dolomite cements. An increase in the precipitation temperature (up to 130 °C from fluid inclusion data) and a decrease in diagenetic fluid salinity (from sea water to brackish) are observed from the first pervasive replacement dolomite to the dolomite cement phases. Field observations indicate that, in the Albenza Formation, dolomitization was limited to palaeohighs or faulted platform margins in the Early Jurassic carbonates. The pervasive replacement phase is interpreted based on a ‘compaction model’; the formation fluids expelled from compacting basinal carbonates could have funnelled along faults into permeable palaeohighs. The high homogenization temperature of the dolomite cements and decreased salinities indicate precipitation at great depth with an influx of meteoric water. These data, along with the thermal history, suggest that the dolomite cements precipitated according to the ‘tectonic squeegee’ dolomitization model. The dolomite precipitation temperature was set against the thermal history of the carbonate platform to interpret the timing of dolomite precipitation. The dolomite precipitation temperatures (90 to 100 °C) were reached in the studied formations first in the thrust fold belt (Early Tertiary, 60 Ma), and then in the foreland succession during the Late Tertiary (10 Ma). This observation suggests that the dolomite precipitation fronts moved southwards over time, recording a ‘diagenetic wave’ linked to the migration of the orogenic system. Observations suggest that the porosity increased during the first phase of replacement dolomitization while the dolomite cementation phases partially occluded the pores. The distribution of porous dolomitized bodies is therefore linked to the ‘compaction dolomitization’ model.  相似文献   
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