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The Ebro catchment, the largest river basin in Spain, includes various heavily industrialized areas. Among these is the Flix site, where a chemical plant has been operating since the beginning of the 20th century. This extended operational period, together with the construction of a dam next to the factory around 1960, resulted in the accumulation of large amounts of heavily polluted sediments in the adjacent riverbed, many of which are contaminated by mercury. Pollutants from Flix are carried downstream by the Ebro River to its delta. In order to assess the transfer of mercury to the complex river estuary ecosystem, we studied the ecology of the tern community living there as these birds segregate into a range of habitats. For this purpose, first we used stable isotope analysis (SIA) (δ34S, δ13C, δ15N) of eggs to determine the trophic ecology and habitat partitioning of several tern species (Common, Sandwich, Little, Gull-Billed and Whiskered Tern) breeding sympatrically, in order to link their foraging ecology with habitat types. Next we measured mercury concentrations in eggs to monitor the input of this metal into the diverse habitats. With the exception of the Little Tern, the other terns used a restricted habitat range in the Ebro Delta, as shown by C and S isotopes; the Gull-Billed and Whiskered Tern foraged in freshwater habitats, while the Common and Sandwich Tern used marine habitats. This restricted feeding behavior of the Gull-Billed and Common Tern contrasts with previous reports in other breeding sites. The Little Tern, which showed a wide range of isotopic values, was found to be an opportunistic forager but fed mainly in saltpans, a feeding habitat not reported previously for this species in this area. We found that mercury concentrations are related to foraging habitat and diet, and are unexpectedly higher in species feeding on demersal prey in marine habitats and also higher in birds feeding in saltpans than in those feeding in freshwater habitats. The mercury concentrations found in the Little and Common Tern eggs sampled in “Punta de la Banya” may be sufficiently high to endanger breeding success.  相似文献   
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Natural Hazards - There are personal and institutional decisions that can increase the seismic resilience of the buildings in a city. However, some of these decisions are possible if we have basic...  相似文献   
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Late Paleocene to Middle Eocene strata in the easternmost part of the Southern Pyrenees, up to 4 km thick, provide information on tectono-sedimentary evolution of faults transversal to the Pyrenean chain. To know how changes in tectonic plate processes control the structural evolution of transverse faults and the synchronous thickness and lithological distribution of sedimentary strata in a foreland basin, field observations, interpretation of 2D seismic lines tied to lithostratigraphic data of exploration wells and gravity modelling constrains were carried out. This resulted in the following two tectono-sedimentary phases in a foreland basin: first phase, dominated by transverse extensional faulting, synchronous with deposition of marine carbonates (ca. 57 to 51 Ma); and second phase, characterized by transverse contractional faulting, coeval to accumulation of marine and transitional siliciclastics (51 to 44 Ma). During the first phase, Iberia and Adria were moving to the east and west respectively. Therefore, lithospheric flexure in the easternmost part of the Iberian plate was developed due to that Sardinia was over-thrusting Iberia. Consequently, activation of E-dipping normal faults was generated giving rise to thick-deep and thin-shallow carbonate platform deposits across the hanging walls and footwalls of the transverse structures. During the second phase, a shearing interaction between Iberia and Sardinia prevailed re-activating the transverse faults as contractional structures generating thin-shelf and thick-submarine fan deposits across the hanging walls and footwalls of the transverse structures. In the transition between the first and second phases, evaporitic conditions dominated in the basin suggesting a tectonic control on basin marine restriction. The results of our study demonstrate how thickness and lithology distribution, controlled by transverse faulting in a compressional regimen, are influenced by phases related to processes affecting motions and interactions between tectonic plates and continental blocks.  相似文献   
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During late Early to Late Cretaceous, the Peruvian coastal margin underwent fast and oblique subduction and was characterized by important arc plutonism (the Peruvian Coastal Batholith) and formation of volcanosedimentary basins known as the Western Peruvian Trough (WPT). We present high-precision U–Pb ages and initial Hf isotopic compositions of zircon from conformable volcanic and crosscutting intrusive rocks within submarine volcanosedimentary strata of the WPT hosting the Perubar massive sulfide deposit. Zircons extracted from both the volcanic and intrusive rocks yield concordant U–Pb ages ranging from 67.89±0.18 Ma to 69.71±0.18 Ma, indicating that basin subsidence, submarine volcanism and plutonic activity occurred in close spatial and temporal relationship within the Andean magmatic arc during the Late Cretaceous. Field observations, satellite image interpretation, and plate reconstructions, suggest that dextral wrenching movements along crustal lineaments were related to oblique subduction. Wrench tectonics is therefore considered to be the trigger for the formation of the WPT as a series of pull-apart basins and for the emplacement of the Coastal Batholith. The zircon initial Hf values of the dated magmatic rocks fall between 5.5 and 7.4, and indicate only very subordinate influence of a sedimentary or continental component. The absence of inherited cores in the zircons suggest a complete lack of old basement below the WPT, in agreement with previous U–Pb and Sr isotopic data for batholithic rocks emplaced in the WPT area. This is supported by the presence of a most likely continuous block of dense (~3.0 g/cm3) material observed beneath the WPT area on gravimetric crustal cross sections. We suggest that this gravimetric anomaly may correspond to a piece of lithospheric mantle and/or oceanic crust inherited from a possible Late Permian–Triassic rifting. Such young and mafic crust was the most probable source for arc magmatism in the WPT area.  相似文献   
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Based on a series of experiments conducted by two regional climate models (RCA4 and LMDZ) with and without soil moisture-atmosphere coupling, we investigate the role of soil moisture on the occurrence of surface air temperature extremes and its persistence in Southeastern South America. Our analysis reveals that both factors, soil moisture-atmosphere coupling and relatively drier soil conditions, enhance the temperature extremes. In addition, the existence of soil-atmosphere coupling and the associated soil moisture variability is crucial for the development of the extremes in SESA. The key role of soil-atmosphere coupling is also reflected in the intrinsic persistence of hot days, which is greater in simulations with interactive soil moisture than in those with prescribed soil conditions. In the absence of soil-atmosphere coupling, the imprint of the anomalous dry (and also wet) soil conditions on the intensity and persistence of hot days is weaker.

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This paper describes the ground-penetrating radar (GPR) survey performed inside the Cathedral of Valencia, Spain. It is part of historical studies performed in the Cathedral in order to add information to old maps and documents in the Cathedral Archives and also to analyze the extent and importance of potentially destructive moisture areas that were appearing on the floor. The construction of the Cathedral of Valencia occurred in three stages, all of which are well-documented in the Cathedral Archives with detailed drawings, maps, and charts. The radar data were successful in locating crypts, ossuaries, sepulchers, and graves, and the location of ancient walls that existed before the final Cathedral expansion. Three cultural layers corresponding to the three periods of construction were also identified corresponding to the Roman, Arabian and Middle Age Epochs. Measurements of relative sub-floor moisture were obtained by comparing dielectric permittivity changes and radar velocity differences between materials in humid and non-humid areas.  相似文献   
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This article presents a methodology for an estimate of the benefit cost ratio of the seismic risk reduction in buildings portfolio at broadscale, for a world region, allowing comparing the results obtained for the countries belonging to that region. This methodology encompasses (1) the generation of a set of random seismic events and the evaluation of the spectral accelerations at the buildings location; (2) the estimation of the buildings built area, the economic value, as well as the classification in structural typologies; (3) the development of vulnerability curves for each typology; (4) the estimation of the annual average loss of the buildings portfolio in the current conditions as well as in the case of a hypothetical structural intervention. The benefit cost ratio is estimated as the difference between the estimates of the present value of these two annual average losses, divided by the retrofitting costs. This methodology has been applied to the portfolio of public schools of 14 countries of Latin America and the Caribbean, for evaluating the feasibility of the seismic risk reduction at a national scale.  相似文献   
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Mercury levels of Audouin's gull are amongst the highest for Mediterranean seabirds, and have been mainly attributed to its piscivorous habits in these naturally Hg rich waters. Moreover, two additional factors could enhance its mercury intake: the consumption of discarded fish (which attain higher concentrations) and/or feeding in areas receiving Hg anthropogenic inputs. In order to differentiate the relevance of both sources we analysed Hg and stable isotopes of chick feathers from different breeding locations in western Mediterranean: one in its northern part (Ebro Delta) and two southern (Chafarinas Isl. and Alborán Isl.). The results from stable isotopes indicate that consumption of discards is higher at Alborán Isl., followed by the Ebro Delta and Chafarinas Isl. Thus, the higher mercury levels found in the Ebro Delta cannot be explained uniquely by the contribution of discarded fish to diet, but local pollution caused by the river Ebro waters accounts for Hg differences observed.  相似文献   
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