Geotechnical and Geological Engineering - Hydraulic fracturing is a key technology for increasing the permeability of coal seams and improving the extraction effect of coalbed methane. Exploring... 相似文献
Modelling the sorption properties of coals for carbon dioxide under supercritical conditions is necessary for accurate prediction of the sequestering ability of coals in seams. We present recent data for sorption curves of three dry Argonne Premium coals, for carbon dioxide, methane and nitrogen at two different temperatures at pressures up to 15 MPa. The sorption capacity of coals tends to decrease with increasing temperature. An investigation into literature values for sorption of nitrogen and methane by charcoal also show sorption capacities that decrease dramatically with increasing temperature. This is inconsistent with expectations from Langmuir models of coal sorption, which predict a sorption capacity that is independent of temperature. We have successfully fitted the isotherms using a modified Dubinin–Radushkevich equation that uses gas density rather than pressure. A simple pore-filling model that assumes there is a maximum pore width that can be filled in supercritical conditions and that this maximum pore width decreases with increasing temperature, can explain this temperature dependence of sorption capacity. It can also explain why different supercritical gases give apparently different surface sorption capacities on the same material. The calculated heat of sorption for these gases on these coals is similar to those found for these gases on activated carbon. 相似文献
Many global emission reduction strategies have been proposed, but few have been assessed quantitatively from the view of equality, efficiency and effectiveness. Integrated assessment models (IAM) is one of the effective ways to make climate policy modeling. So in this paper we developed the MRICES (Multi-regional integrated model of climate and economy with GDP spillovers) model, which is an IAM but extends to include GDP spillover mechanism, to make assessment on several strategies for global emission reduction, including the egalitarianism strategy, the UNDP strategy and the Copenhagen Accord. Using 1990 as a baseline for historical emission levels, the egalitarian strategy argues that developed countries should implement urgent emission reductions, whereas developing countries are allowed relatively higher future emission quotas. The UNDP strategy addresses the issue of substantial changes in global temperature but acknowledges that developing countries are not able to afford more costs for mitigation measures, which is inequitable from the perspective of a country’s right to develop. We also simulated the Copenhagen Accord to determine the consequences by the year 2100 if each country continues their current emission mitigation actions, and results indicated that the increase in global temperature will be 2.8 ℃by 2100; consequently, much stronger emission reduction efforts must be implemented after 2020. Based on analysis on mitigation strategies, it is recognized that the common but differentiated responsibility principle must be insisted when making global mitigation strategy. To comply with this principle, the emission reduction baseline of developed and developing countries should be discriminated, so 1990 and 2005 can be taken as the base year for developed and developing countries respectively. 相似文献
Gas emission from the working face in a gas-bearing coal seam impairs safe production. Especially in the coal face, influenced by mining, pressure-relief gas in adjacent seams flows into the working face through the goaf. Moreover, caved overlying strata in different regions show differences in pore and seepage characteristics. Thus, the caving of overlying strata in the goaf of a working face was explored by carrying out physical similarity simulation. Then, based on the characteristics of the geometric shapes of caved overlying strata after mining, a trapezoidal three-dimensional model for gas extraction was established. According to the calculation result, the parameters of field high-level boreholes were optimized. Then, the controllability of gas concentration at the working face after gas extraction was assessed by applying statistical process control. The result showed that after the observed surface of the physical similarity model was lightened, it was more favorable for conducting the test. Moreover, the maximum gas concentration in the goaf was negatively correlated with the diameter of high-level boreholes and the negative pressure for gas extraction. A statistical process control chart revealed that the gas concentrations at the working face were safe after gas extraction based on high-level boreholes, which also validated the feasibility and effectiveness of the model.