The Bear Brook Watershed in Maine: Multi-decadal whole-watershed experimental acidification     

Kaizad F. Patel  Ivan J. Fernandez  Sarah J. Nelson  Stephen A. Norton  Cheryl J. Spencer 《水文研究》2021,35(5):e14147

The Bear Brook Watershed in Maine (BBWM) is a long-term research site established to study the response of forest ecosystem function to environmental disturbances of chronic acidic deposition and ecosystem nitrogen enrichment. Starting in 1989, the West Bear (treated) watershed received bimonthly applications of ammonium sulfate [(NH₄)₂SO₄] fertilizer from above the canopy, whereas East Bear (reference) received ambient deposition. The treatments were stopped in 2016, marking the beginning of the recovery phase. Research at the site has focused on soils, streams, and vegetation. Here, we describe data collected over three decades at the BBWM—input and stream output nutrient fluxes, quantitative soil pits and soil chemistry, and soil temperature and moisture.  相似文献   

Crinoid localities of the Devonian of the British Isles     

Stephen K. Donovan  Fiona E. Fearnhead 《Geology Today》2020,36(3):113-119

Who collects the Devonian crinoids of south-west England? Since the nineteenth century, almost nobody. Few palaeontologists pursue these fossils, undoubtedly handsome in life, but indifferently preserved. Herein, we make a survey of four of the most important crinoid sites, all of which have the potential to produce new specimens.  相似文献   

Evaluating soil water routing approaches in watershed-scale,ecohydrologic modelling     

Garett Pignotti  Indrajeet Chaubey  Keith Cherkauer  Mark Williams  Melba Crawford 《水文研究》2021,35(3):e14034

Soil water dynamics are central in linking and regulating natural cycles in ecohydrology, however, mathematical representation of soil water processes in models is challenging given the complexity of these interactions. To assess the impacts of soil water simulation approaches on various model outputs, the Soil and Water Assessment Tool was modified to accommodate an alternative soil water percolation method and tested at two geographically and climatically distinct, instrumented watersheds in the United States. Soil water was evaluated at the site scale via measured observations, and hydrologic and biophysical outputs were analysed at the watershed scale. Results demonstrated an improved Kling–Gupta Efficiency of up to 0.3 and a reduction in percent bias from 5 to 25% at the site scale, when soil water percolation was changed from a threshold, bucket-based approach to an alternative approach based on variable hydraulic conductivity. The primary difference between the approaches was attributed to the ability to simulate soil water content above field capacity for successive days; however, regardless of the approach, a lack of site-specific characterization of soil properties by the soils database at the site scale was found to severely limit the analysis. Differences in approach led to a regime shift in percolation from a few, high magnitude events to frequent, low magnitude events. At the watershed scale, the variable hydraulic conductivity-based approach reduced average annual percolation by 20–50 mm, directly impacting the water balance and subsequently biophysical predictions. For instance, annual denitrification increased by 14–24 kg/ha for the new approach. Overall, the study demonstrates the need for continued efforts to enhance soil water model representation for improving biophysical process simulations.  相似文献   

Meteoric fluid‐rock interaction in Variscan shear zones     

Camille Dussaux  Aude Gbelin  Philippe Boulvais  Vronique Gardien  Stephen Grimes  Andreas Mulch 《地学学报》2019,31(4):366-372

Variscan shear zones in the Armorican Massif represent sites of strong fluid‐rock interaction. The hydrogen isotope composition of muscovite (δD_Ms) from syntectonic leucogranite allows to determine the source of fluids that infiltrated the footwall of three detachment zones and the South Armorican Shear Zone. Using temperatures of hydrogen isotope exchange estimated from microstructural data, we calculate the hydrogen isotope ratios of water (δD_water) present within the shear zones during high‐temperature deformation. A ~40‰ difference in δD_water values from deep to shallow crustal level reveals a mixing relationship between deep crustal fluids with higher δD values that range from ?34 to ?33‰, and meteoric fluids with δD values as low as ?74‰ in the upper part of detachment footwalls.  相似文献   

Changes in hillslope hydrology in a perched,shallow soil system due to clearcutting and residual biomass removal     

Colin P. R. McCarter  Stephen D. Sebestyen  Susan L. Eggert  Randall K. Kolka  Carl P. J. Mitchell 《水文研究》2020,34(26):5354-5369

Sustainable fuels legislation and volatility in energy prices have put additional pressures on the forestry sector to intensify the harvesting of biomass for “advanced biofuel” production. To better understand how residual biomass removal after harvest affects forest hydrology in relatively low slope terrain, a Before-After-Control-Impact (BACI) study was conducted in the USDA Forest Service's Marcell Experimental Forest, Minnesota, USA. Hydrological measurements were made from 2010–2013 on a forested hillslope that was divided into three treatment blocks, where one block was harvested and residual biomass removed (Biomass Removed), the second was harvested and residual biomass left (Biomass Left), and the last block was left as an Unharvested Control. The pre-harvest period (2 years) was 2010–11 and post-harvest (2 years) was 2012–13. Water table elevation at the upslope and downslope position, subsurface runoff, and soil moisture were measured between May–November. Mixed effect statistical models were used to compare both the before-after and “control” treatment ratios (ratios between harvested hillslopes and the Unharvested Control hillslope). Subsurface runoff significantly increased (p < .05) at both harvested hillslopes but to a greater degree on the Biomass Left hillslope. Greater subsurface runoff volumes at both harvested hillslopes were driven by substantial increases during fall, with additional significant increases during summer on the Biomass Left hillslope. The hydrological connectivity, inferred from event runoff ratios, increased due to harvesting at both hillslopes but only significantly on the Biomass Left hillslope. The winter harvest minimized soil disturbance, resulting in no change to the effective hydraulic conductivity distribution with depth. Thus, the observed hydrological changes were driven by increased effective precipitation and decreased evapotranspiration, increasing the duration that both harvested hillslopes were hydrologically active. The harvesting of residual biomass appears to lessen hydrological connectivity relative to leaving residual biomass on the hillslope, potentially decreasing downstream hydrological impacts of similar forestry operations.  相似文献   

Laboratory kinetics of C₂H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan     

James E. Murphy  Stephen R. Leone 《Icarus》2003,163(1):175-181

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   

Electron microscopy study of the iron meteorite Santa Catharina     

J. Zhang  D. B. Williams  J. I. Goldstein  R. S. Clarke 《Meteoritics & planetary science》1990,25(3):167-175

Abstract— Characterization of the microstructural features of the metal of the Santa Catharina meteorite was performed using a variety of electron optical techniques. Sample USNM#6293 is chemically homogeneous on the micron scale and has a Ni content of 28.2 wt.%. Its microstructure is similar to that of the Twin City ataxite and contains clear taenite II, i.e., fcc taenite with domains of tetrataenite, < 10 nm in size. Sample USNM#3043 is a more typical Santa Catharina specimen with dark and light regions as observed with the light optical microscope. The dark regions are inhomogeneous and contain 45–50 wt.% Ni and 7–12 wt.% O. The light regions are homogeneous and contain 35 wt.% Ni and no detectable oxygen. The microstructure is that of cloudy zone, i.e., islands of tetrataenite, ～20 nm in size, in a honeycomb matrix. The honeycomb phase contains Ni rich oxide in the dark regions and contains metal, fcc taenite, in the light regions. The original metal structure of USNM#3043 is cloudy zone which formed during cooling into the low temperature miscibility gap of the Fe-Ni phase diagram. The dark regions were developed from the metal by selective corrosion of the honeycomb structure, transforming it into Ni containing oxides, possibly non-stoichiometric Fe₂NiO₄ while retaining the tetrataenite islands. Using the results of this study, many of the existing discrepancies concerning the microstructure of Santa Catharina can be explained.  相似文献   

SYSTAT 5.0     

Stephen Roberts 《地学学报》1992,4(5):608-611

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Biological and granulometric controls on sedimentary organic matter of an intertidal mudflat     

Lawrence M. Mayer  Peter T. Rahaim  William Guerin  Stephen A. Macko  Les Watling  Franz E. Anderson 《Estuarine, Coastal and Shelf Science》1985,20(4):491-503

A variety of measures of organic matter concentration and quality were made on samples collected from the top few mm of intertidal mudflat sediment over the course of a year, in order to assess the relative importance of biological and sedimentological influences on sedimentary organic matter. Winter and summer were times of relatively fine-grained sediment accumulation, caused by biological deposition or stabilization processes and resulting in higher organic matter concentrations. Stable carbon isotope and Br:C ratios indicated a planktonic source of bulk organic matter. Ratios of organic carbon to specific surface area of the sediments were consistent with an organic monolayer coverage of sediment grains. Correction for changing grain size during the year showed no change in the organic concentration per unit surface area, in spite of organic matter inputs by in situ primary production, buildup of heterotroph biomass and mucus coatings, and biodeposition of organic-rich seston. There were also no indications of changes in bulk organic quality, measured as hydrolyzable carbohydrates and amino acids, in response to these biological processes. It is concluded that biological processes on a seasonal time scale affect the bulk organic matter of these sediments via a modulation of grain size rather than creation or decay of organic matter.  相似文献   

Fire and ice: unravelling the climatic and volcanic history of James Ross Island, Antarctic Peninsula     

John Smellie  Anna Nelson  Mark Williams 《Geology Today》2006,22(6):220-226

Back in the mid-nineteenth century British explorer James Clark Ross took his ships, HMS Terror and HMS Erebus , farther south than anyone else had been. He now lends his name to James Ross Island, a part-volcanic edifice that rises out of the sea off the north-east tip of the Antarctic Peninsula. The island records a geological history dating back to the Cretaceous, though its great peaks are volcanic. The most recent rocks of the island record a monumental struggle between fire and ice, the volcanoes, and the ice sheets that cover them. The glacigenic sediments that are interspersed with the volcanic rocks contain rich fossil assemblages which suggest that at times, the climate was warmer, with the ice retreating. Their study may help us to delimit the patterns of climate change in the Antarctic Peninsula region as Earth's global climate warms.  相似文献