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Solid-phase microextraction (SPME) is a simple, sensitive and less destructive method for the determination of dimethylsulfide (DMS) in seawater. Combined with detection by gas chromatography-mass spectrometry (GC-MS), the method had sufficient sensitivity (minimum detectable concentration of DMS was 0.05 nM), and practical levels of reproducibility (relative standard deviation ≤7%) and linearity (r 2 > 0.995) over a wide concentration range (0.5 to 910 nM). The protocol developed was applied to a Sagami Bay water sample to determine concentrations of DMS and DMSP, and in situ DMSP-lyase activity.  相似文献   
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The effect of ocean acidification, caused by the increase in pCO2 in seawater, on phytoplankton population and on related organic nitrogen production was experimentally examined by use of a natural coastal microbial population. pCO2 and pH were controlled by aeration with air in which pCO2 was at the current level (control), for which ambient air was used, and with air in which pCO2 was ??800?? and ??1200?? ppm, in 500-L culture vessels. The experiment was continued for 15?days after addition of the inorganic nutrients such as nitrate, phosphate, and silicate. During most of the experimental period, a minor increase in phytoplankton biomass was noted, probably because of low irradiance, an increase in phytoplankton biomass was observed at the end of the experiment. Flow cytometric and microscopic observations revealed that this increase was because of Chrysochromulina sp. (Haptophyceae). The growth of Chrysochromulina sp. was most obvious in the control vessel, and tended to be obscured by increasing pCO2 (decrease in pH), indicating the possibility that ocean acidification inhibits the growth of specific phytoplankton groups, for example Chrysochromulina sp. Production of particulate organic nitrogen (PON), determined by the 15N tracer method, also diminished under acidified conditions compared with that at the current level.  相似文献   
3.
Liu  Chunxue  Kubo  Taiki  Lu  Lei  Koike  Katsuaki  Zhu  Wenjie 《Natural Resources Research》2019,28(1):99-108
Natural Resources Research - Fracture is an important factor controlling mineralization and ore distribution in metallic deposits. Fracture also affects mechanical stability of drifts. A plausible...  相似文献   
4.
This paper focuses on the formation mechanism of fractures induced by excavation of a gallery in soft sedimentary rocks in the Horonobe area of Japan.Detailed fracture mapping of the gallery indicates that the fractures consist of both pre-existing shear fractures and excavation damaged zone(EDZ) fractures. EDZ fractures correspond to weak planes associated with bedding planes or transgranular cracks.The EDZ fractures terminate against pre-existing shear fractures.Therefore,even for excavations in soft sedimentary rocks,formation of the EDZ fractures are controlled by pre-existing fractures and earlier weak planes.  相似文献   
5.
Widespread definition of a groundwater system in three dimensions is necessary for the management and maintenance of groundwater resources. A magnetotelluric (MT) survey can be an effective geophysical prospecting method for imaging regional geological structures by measuring both shallow and deep resistivity. To demonstrate the capability of an MT survey to characterize a groundwater system, the Kumamoto area of central Kyushu in southwestern Japan was selected as a case study site because of its rich groundwater resources. Three-dimensional (3D) MT resistivity structure to a depth of 5?km was modeled by 1D inversion analysis of raw MT data and 3D interpolation of the resultant resistivity column data by the optimization principle method. Consequently, both deep and shallow aquifers were detected. A high-resistivity zone appears at depths between 500 and 2,000?m between the Futagawa?CHinagu faults and the Usuki?CYatsushiro tectonic line, which supports the existence of an aquiclude under the aquifer. The most important characteristic inferred from the 3D resistivity model is that the deep groundwater system below a depth of 1,000?m has two main flow paths. One path is likely to be through porous rocks because the low resistivity zone is regarded as tuff with sand and gravel, and the other flow path is interpreted to be through fractured zones along the Hinagu faults. Hence, the path and direction of the groundwater flows are probably controlled by geologic structures and the configuration of the active faults. These findings support the effectiveness of the MT method for investigating groundwater systems.  相似文献   
6.
The summer climate around the Tokyo metropolitan area has been analysed on an urban scale, and the regional characteristics of the thermal energy balance of a bayside business district in the centre of Tokyo (Otemachi) have been compared with an inland residential district (Nerima), using a mesoscale meteorological model incorporating an urban canopy model. From the results of the analysis, the mechanism of diurnal change in air temperature and absolute humidity in these areas is quantitatively demonstrated, with a focus on the thermal energy balance. Moreover, effective countermeasures against urban heat-islands are considered from the viewpoint of each region’s thermal energy balance characteristics. In addition to thermal energy outflux by turbulent diffusion, advection by sea-breezes from Tokyo Bay discharges sensible heat in Otemachi. This mitigates temperature increases during the day. On the other hand, because all sea-breezes must first cross the centre of Tokyo, it has less of a cooling effect in Nerima. As a result, the air temperature during the day in Nerima is higher than that in Otemachi.  相似文献   
7.
The Holocene stalagmite FG01 collected at the Fukugaguchi Cave in Itoigawa, central Japan provides a unique high‐resolution record of the East Asian winter monsoon. Because of the climate conditions on the Japan Sea side of the Japanese islands, the volume of precipitation during the winter is strongly reflected in the stalagmite δ18O signal. Examination of the carbon isotopes and the Mg/Ca ratio of FG01 provided additional information on the Holocene climate in Itoigawa, which is characterized by two different modes separated at 6.4 ka. Dripwater composition and the correlation between the δ13C and Mg/Ca data of FG01 indicate the importance of prior calcite precipitation (PCP), a process that selectively eliminated 12C and calcium ions from infiltrating water from CO2 degassing and calcite precipitation. In an earlier period (10.0–6.4 ka), an increase in soil pCO2 associated with warming and wetting climate trends was a critical factor that enhanced PCP, and resulted in an increasing trend in the Mg/Ca and δ13C data and a negative correlation between the δ13C and δ18O profiles. A distinct peak in the δ13C age profile at 6.8 ka could be a response to an increase of approximately 10% in C4 plants in the recharge area. At 6.4 ka, the climate mode changed to another, and correlation between δ18O and δ13C became positive. In addition, a millennial‐scale variation in δ18O and pulsed changes in δ13C and Mg/Ca became distinct. Assuming that δ18O and PCP were controlled by moisture in the later period, the volume of precipitation was high during 6.0–5.2, 4.4–4.0, and 3.0–2.0 ka. In contrast, the driest interval in Itoigawa was during 0.2–0.4 ka, and broadly corresponds to the Little Ice Age.  相似文献   
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