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白云凹陷第三系储层中发育大量的铁白云石,受研究区热流背景的影响,铁白云石主要见于高地温梯度地区埋深1000～3000m、地层温度60～130℃的浅—中部地层中及CO_2热流体活动区域。铁白云石的δ~(13)C值(-2.83‰～-1.83‰)具有无机成因的特征,与研究区气藏中幔源岩浆成因CO_2的δ~(13)C值较为一致,铁白云石的δ~(18)O值(-9.45‰～-5.37‰)和~(87)Sr/~(86)Sr值(0.7101～0.7161)也反映了其沉淀受到深部热流体活动的影响。以两口典型CO_2气井为例,储层中流体包裹体均一温度及蒙脱石向伊利石的演化特征证明储层经历了热流体侵入;CO_2热流体活动区域不仅是铁白云石集中分布地带,并出现片钠铝石+铁白云石+菱铁矿等示踪CO_2运移、聚集的自生矿物组合。地层中铁白云石、高岭石含量与气藏中CO_2的含量呈正相关关系,绿泥石含量与CO_2、铁白云石含量呈反消长关系。高地温梯度地区丰富的CO_2热流体活动是该地区储层中铁白云石沉淀与含量高的重要原因,无机岩浆成因CO_2是铁白云石沉淀的主要碳源,CO_2热流体充注造成绿泥石等黏土矿物异常转化,为铁白云石沉淀提供了所需的Fe~(2+)、Mg~(2+)离子。 相似文献
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Hydrogeology Journal - The relative roles of the sediment grain size/permeability, conduit flow rate and conduit geometry/angle on the hyporheic exchange between a karst conduit and its underlying... 相似文献
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Natural Resources Research - Coal seam water injection is a critical measure for the prevention of coal-and-gas outbursts. However, the gas–solid–liquid coupling effect in front of the... 相似文献
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针对在湿地动态变化监测中,经典的土地利用转移矩阵无法实现湿地类型变化信息的定位可视化表达的问题,提出了一种新的时空变化信息的可视化分析方法。利用由空间单元和时序单元集成的时空复合单元建立转移图谱单元分类体系,较好地记录每一个图谱单元湿地类型的起始和终止状态,实现了湿地时空变化信息的定位表达;基于遥感制图和地学图谱的湿地空间演变规律特征图谱,采用图表和图谱的形式展示湿地类型变化的数量及空间位置变化信息,实现了湿地时空变化的可视化表达。基于银川平原湿地的实验结果表明:该方法能够清晰、直观地显示1999—2013年期间银川平原湿地的时空变化,能够为该地区合理利用湿地资源提供科学的理论依据。 相似文献
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Geochemistry of pyrite and chalcopyrite from an active black smoker in 49.6°E Southwest Indian Ridge
Bo Yuan Yaomin Yang Hongjun Yu Yuexia Zhao Qingfeng Ding Jichao Yang Xin Tang 《Marine Geophysical Researches》2018,39(3):441-461
Active hydrothermal chimneys, as the product of submarine hydrothermal activity, can be used to determine the fluid evolution and formation process of potential volcanic-hosted massive sulfide deposits. A hard-won specimen from an active hydrothermal chimney was collected in the 49.6°E ultraslow-spreading Southwest Indian Ridge (SWIR) field through a television-guided grab. A geochemical study of prominent sulfide (e.g., pyrite and chalcopyrite) included in this sample was performed using laser ablation inductively coupled plasma mass spectroscopy. The early sulfides produced at low temperature are of disseminated fine-grained anhedral morphology, whereas the late ones with massive, coarse euhedral features precipitated in a high-temperature setting. The systematic variations in the contents of minor and trace elements are apparently related to the crystallization sequence, as well as to texture. Micro-disseminated anhedral sulfides rich in Pb, As, Ni, Ba, Mn, Mo, U, and V were formed during the initial chimney wall growth, whereas those rich in Sn, Se, and Co with massive, coarse euhedral morphology were formed within the late metallogenic stage. The hydrothermal fluid composition has experienced a great change during the chimney growth. Such a conclusion is consistent with that indicated by using principal component analysis, which is a powerful statistical analysis method widely used to project multidimensional datasets (e.g., element contents in different mineral phases) into a few directions. This distribution pattern points to crystallographic controls on minor and trace element uptake during chimney growth, occurring with concomitant variations in the fluid composition evolutionary history. In this pyrite-chalcopyrite-bearing active hydrothermal chimney at the SWIR, the metal concentration and precipitation of sulfides largely occurred at the seafloor as a result of mixing between the upwelling hot hydrothermal fluid and cold seawater. Over the course of mixing, significant variations in metal solubility were caused by changes in temperature, pH, and redox conditions in the parental fluid phase. 相似文献