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1.
Results of drilling, logging, and testing of three exploration core holes, combined with results of geologic and hydrogeochemical investigations, have been used to present a reservoir model of the Platanares geothermal system, Honduras. Geothermal fluids circulate at depths ≥ 1.5 km in a region of active tectonism devoid of Quaternary volcanism. Large, artesian water entries of 160 to 165°C geothermal fluid in two core holes at 625 to 644 m and 460 to 635 m depth have maximum flow rates of roughly 355 and 560 l/min, respectively, which are equivalent to power outputs of about 3.1 and 5.1 MW(thermal). Dilute, alkali-chloride reservoir fluids (TDS ≤ 1200 mg/kg) are produced from fractured Miocene andesite and Cretaceous to Eocene redbeds that are hydrothermally altered. Fracture permeabillity in producing horizons is locally greater than 1500 and bulk porosity is ≤ 6%. A simple, fracture-dominated, volume-impedance model assuming turbulent flow indicates that the calculated reservoir storage capacity of each flowing hole is approximately 9.7 × 106 l/(kg cm−2), Tritium data indicate a mean residence time of 450 yr for water in the reservoir. Multiplying the natural fluid discharge rate by the mean residence time gives an estimated water volume of the Platanares system of ≥ 0.78 km3. Downward continuation of a 139°C/km “conductive” gradient at a depth of 400 m in a third core hole implies that the depth to a 225°C source reservoir (predicted from chemical geothermometers) is at least 1.5 km. Uranium-thorium disequilibrium ages on calcite veins at the surface and in the core holes indicate that the present Platanares hydrothermal system has been active for the last 0.25 m.y.  相似文献   
2.
An empirical method of estimating the last temperature of water-rock interaction has been devised. It is based upon molar Na, K and Ca concentrations in natural waters from temperature environments ranging from 4 to 340°C. The data for most geothermal waters cluster near a straight line when plotted as the function log (NaK) + β log [ √ (Ca)Na] vs reciprocal of absolute temperature, where β is either 13 or 43 depending upon whether the water equilibrated above or below 100°C. For most waters tested, the method gives better results than the NaK methods suggested by other workers. The ratio NaK should not be used to estimate temperature if √ (MCa)MNa is greater than 1. The NaK values of such waters generally yield calculated temperatures much higher than the actual temperature at which water interacted with the rock.A comparison of the composition of boiling hot-spring water with that obtained from a nearby well (170°C) in Yellowstone Park shows that continued water-rock reactions may occur during ascent of water even though that ascent is so rapid that little or no heat is lost to the country rock, i.e. the water cools adiabatically. As a result of such continued reaction, waters which dissolve additional Ca as they ascend from the aquifer to the surface will yield estimated aquifer temperatures that are too low. On the other hand, waters initially having enough Ca to deposit calcium carbonate during ascent may yield estimated aquifer temperatures that are too high if aqueous Na and K are prevented from further reaction with country rock owing to armoring by calcite or silica minerals.The Na-K-Ca geothermometer is of particular interest to those prospecting for geothermal energy. The method also may be of use in interpreting compositions of fluid inclusions.  相似文献   
3.
Temperatures of aquifers feeding thermal springs and wells in Long Valley, California, estimated using silica and Na-K-Ca geothermometers and warm spring mixing models, range from 160/dg to about 220°C. This information was used to construct a diagram showing enthalpy-chloride relations for the various thermal waters in the Long Valley region. The enthalpy-chloride information suggests that a 282 ± 10°C aquifer with water containing about 375 mg chloride per kilogram of water is present somewhere deep in the system. That deep water would be related to 220°C Casa Diablo water by mixing with cold water, and to Hot Creek water by first boiling with steam loss and then mixing with cold water. Oxygen and deuterium isotopic data are consistent with that interpretation. An aquifer at 282°C with 375 mg/kg chloride implies a convective heat flow in Long Valley of 6.6 × 107 cal/s.  相似文献   
4.
As an example of the technique of fingerprint detection of greenhouse climate change, a multivariate signal or fingerprint of the enhanced greenhouse effect is defined using the zonal mean atmospheric temperature change as a function of height and latitude between equilibrium climate model simulations with control and doubled CO2 concentrations. This signal is compared with observed atmospheric temperature variations over the period 1963 to 1988 from radiosonde-based global analyses. There is a significant increase of this greenhouse signal in the observational data over this period.These results must be treated with caution. Upper air data are available for a short period only, possibly too short to be able to resolve any real greenhouse climate change. The greenhouse fingerprint used in this study may not be unique to the enhanced greenhouse effect and may be due to other forcing mechanisms. However, it is shown that the patterns of atmospheric temperature change associated with uniform global increases of sea surface temperature, with El NinoSouthern Oscillation events and with decreases of stratospheric ozone concentrations individually are different from the greenhouse fingerprint used here.  相似文献   
5.
The Sierra La Primavera, a late Pleistocene rhyolitic caldera complex in Jalisco, México, contains fumaroles and large-discharge 65°C hot springs that are associated with faults related to caldera collapse and to later magma insurgence. The nearly-neutral, sodium bicarbonate, hot springs occur at low elevations at the margins of the complex, whereas the water-rich fumaroles are high and central.The Comisión Federal de Electricidad de México (CFE) has recently drilled two deep holes at the center of the Sierra (PR-1 and Pr-2) and one deep hole at the western margin. Temperatures as high as 285°C were encountered at 1160 m in PR-1, which produced fluids with 820 to 865 mg/kg chloride after flashing to one atmosphere. Nearby, PR-2 encountered temperatures to 307°C at 2000 m and yielded fluids with chloride contents fluctuating between 1100 and 1560 mg/kg after flashing. Neither of the high-temperature wells produced steam in commercial quantities. The well at the western margin of the Sierra produced fluids similar to those from the hot springs. The temperature reached a maximum of 100°C near the surface and decreased to 80°C at 2000 m.Various geothermometers (quartz conductive, Na/K, Na-K-Ca, δ18O(SO4-H2O) and D/H (steam-water) all yield temperatures of 170 ± 20°C when applied to the hot spring waters, suggesting that these spring waters flow from a large shallow reservoir at this temperature. Because the hot springs are much less saline than the fluids recovered in PR-1 and PR-2, the mixed fluid in the shallow reservoir can contain no more than 10–20% deep fluid. This requires that most of the heat is transferred by steam. There is probably a thin vapor-dominated zone in the central part of the Sierra, through which steam and gases are transferred to the overlying shallow reservoir. Fluids from this reservoir cool from 170°C to 65°C by conduction during the 5–7 km of lateral flow to the hot springs.  相似文献   
6.
Steam samples from six wells (Colombaia, Pineta, Larderello 57, Larderello 155, Gabbro 6, and Gabbro 1) in a south to north section across the Larderello geothermal field have been analyzed for inorganic and hydrocarbon gases and for oxygen-18 and deuterium of steam. The wells generally decrease in depth and increase in age toward the south. The steam samples are generally characterized by
  1. Total gas contents increasing south to north from 0.003 to 0.05 mole fraction;
  2. Constant CO2 (95±2 percent); near constant H2S (1.6±0.8), N2 (1.2±0.8), H2 (2±1), CH4 (1.2±1), and no O2 in the dry gas;
  3. Presence of numerous, straight chain and branched C2 to C6 hydrocarbons plus benzene in amounts independent of CH4 contents with highest concentrations in the deeper wells;
  4. Oxygen-18 contents of steam increasing south to north from ?5.0‰ to ?0.4‰ with little change in deuterium (?42±2‰).
These observations are interpreted as showing:
  1. Decreasing gas contents with amount of production because the proportion of steam boiled from liquid water increases with production;
  2. Synthesis of CH4 from H2 and CO2 with CO2 and H2 produced by thermal metamorphism and rock-water reactions;
  3. Extraction of C2 to C6 hydrocarbons from rock organic matter;
  4. Either oxygen isotope exchange followed by distillation of steam from the north toward the south (2 plates at ~220°C) or mixture of deeper more-exchange waters from the north with shallow, less-exchanged recharging waters from the south.
  相似文献   
7.
Introduction Europe's mountains cover nearly half of the continent's area (Price et al. 2004) and land cover varies significantly (European Commission 2004). In most massifs, except for Sicily, southern Greece, and the British Isles, forest cover is dominant. In northern Europe, grassland is proportionately more important, and much of the mountains of the British Isles is covered by moorland. In central and southern Europe, arable land is of far greater importance than grassland, with Med…  相似文献   
8.
Studies of the effect of dissolved salts on the oxygen isotope activity ratio of water have been extended to 275°C. Dehydrated salts were added to water of known isotope composition and the solutions were equilibrated with CO2 which was sampled for analysis. For comparison similar studies were made using pure water. Results on water nearly coincide with earlier calculations. Salt effects diminish with increasing temperature only for solutions of MgCl2 and LiCl. Other salt solutions show complex behavior due to the temperature-dependent formation of ion pairs of changing character. Equilibrium fractionations (103 ln α) between 1 molal solutions and pure water at 25, 100, and 275°C are: NaCl 0.0, ?1.5, +1.0; KCl 0.0, ?1.0, +2.0; LiCl ?1.0, ?0.6, ?0.5; CaCl2 ?0.4, ?1.8, +0.8; MgCl2 ?1.1, ?0.7, ?0.3; MgSO4 ?1.1, +0.1, ?; NaF (0.8 m) 0.0, ?1.5, ?0.3; and NH4Cl (0.55 m) 0.0, ?1.2, ?1.3. These effects are significant in the isotope study of hot saline fluids responsible for ore deposition and of fluids found in certain geothermal systems. Minor modification of published isotope geothermometers may be required.  相似文献   
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