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The meteoric input of36Cl due to cosmogenic or nuclear-weapon-produced36Cl cannot contribute significantly to the36Cl present in the saline groundwaters (up to 700 mg l−1 Cl−) from the Stripa granite. The extent of in-situ production of36Cl has been estimated on the basis of the neutron fluxes within the granite and its surrounding leptite. The36Cl present in the groundwaters is attributed to either admixture of labelled Cl− from the leptite with Cl− from the granite or to the total derivation of groundwater chlorinity within the leptite followed by radiochemical ingrowth of36Cl during subsequent groundwater residence within the granite. The chloride derived from the leptite may be either matrix chloride or chloride from an external source which has had a long residence time within the leptite. The implications of36Cl in-situ production for the estimation of groundwater residence times and for the geochemical evolution of groundwater chlorinity are discussed. 相似文献
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Véronique Lavastre Corinne Le Gal La Salle Jean-Luc Michelot Sophie Giannesini Lucilla Benedetti Joël Lancelot Bernard Lavielle Marc Massault Bertrand Thomas Eric Gilabert Didier Bourlès Norbert Clauer Pierre Agrinier 《Applied Geochemistry》2010
Groundwaters from the Tithonian/Kimmeridgian, Oxfordian and Upper Dogger aquifers, within the eastern part of the Paris basin (France), were characterised using 3H, 14C and 36Cl, and noble gases tracers, to evaluate their residence times and determine their recharge period. This information is an important prerequisite to evaluating the confinement properties of the Callovo-Oxfordian clay formation sandwiched between the Oxfordian aquifer and the Dogger aquifer, currently being investigated by the French nuclear waste management agency (Andra) for radioactive waste disposal. Data presented in this paper are used to test 4 hypotheses. 相似文献
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G. Iezzi F. Cámara R. Oberti G. Della Ventura G. Pedrazzi J-L Robert 《Physics and Chemistry of Minerals》2004,31(6):375-385
This work reports the synthesis of ferri-clinoholmquistite, nominally Li2(Mg3Fe3+2)Si8O22(OH)2, at varying fO2 conditions. Amphibole compositions were characterized by X-ray (powder and single-crystal) diffraction, microchemical (EMPA) and spectroscopic (FTIR, Mössbauer and Raman) techniques. Under reducing conditions ( NNO+1, where NNO = Nickel–Nickel oxide buffer), the amphibole yield is very high (>90%), but its composition, and in particular the FeO/Fe2O3 ratio, departs significantly from the nominal one. Under oxidizing conditions ( NNO+1.5), the amphibole yield is much lower (<60%, with Li-pyroxene abundant), but its composition is close to the ideal stoichiometry. The exchange vector of relevance for the studied system is M2(Mg,Fe2+) M4(Mg,Fe2+) M2Fe3+–1 M4Li–1, which is still rather unexplored in natural systems. Amphibole crystals of suitable size for structure refinement were obtained only at 800 °C, 0.4 GPa and NNO conditions (sample 152), and have C2/m symmetry. The X-ray powder patterns for all other samples were indexed in the same symmetry; the amphibole closest to ideal composition has a = 9.428(1) Å, b = 17.878(3) Å, c = 5.282(1) Å, = 102.06(2)°, V = 870.8(3) Å3. Mössbauer spectra show that Fe3+ is strongly ordered at M2 in all samples, whereas Fe2+ is disordered over the B and C sites. FTIR analysis shows that the amount of CFe2+ increases for increasingly reducing conditions. FTIR data also provide strong evidence for slight but significant amounts of Li at the A sites. 相似文献
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Claystones are one of the types of geological formations that are considered for the isolation of radioactive wastes. The study of water transfer through these rocks comes up against a lot of difficulties. Among them is the problem of extracting representative samples of interstitial water from indurated claystones with very low water contents (usually less than 10% vol.). The vacuum distillation technique considered here for samples from the Tournemire site (Toarcian argillite formation), is one of the few usable techniques to extract water from this type of rock in order to perform stable isotope investigations on porewater. Tests have shown that the isotope water content is not only influenced by the yield of extraction and the temperature of distillation (as already known), but also by the rain size and the contact time between the crushed sample and the atmosphere. This affects particularly18O data.The first isotopic results on the Tournemire claystones suggest a meteoric origin for its interstitial water. Data show a depletion in heavy isotopes with respect to present day meteoric water, that could suggest a recharge under climatic conditions cooler than at present. A clear link appears between the isotope contents of water and the structural context: interstitial waters of rock samples taken in the fractured zone of the massif seem to have been affected by a secondary process (evaporation or water-rock exchange) leading to the enrichment in heavy isotopes. 相似文献
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A. G. Szulc Y. Najman† H. D. Sinclair M. Pringle‡ M. Bickle§ H. Chapman§ E. Garzanti¶ S. Andò¶ P. Huyghe&#; J-L. Mugnier&#; T. Ojha P. DeCelles† 《Basin Research》2006,18(4):375-391
40Ar–39Ar dating of detrital white micas, petrography and heavy mineral analysis and whole‐rock geochemistry has been applied to three time‐equivalent sections through the Siwalik Group molasse in SW Nepal [Tinau Khola section (12–6 Ma), Surai Khola section (12–1 Ma) and Karnali section (16–5 Ma)]. 40Ar–39Ar ages from 1415 single detrital white micas show a peak of ages between 20 and 15 Ma for all the three sections, corresponding to the period of most extensive exhumation of the Greater Himalaya. Lag times of less than 5 Myr persist until 10 Ma, indicating Greater Himalayan exhumation rates of up to 2.6 mm year?1, using one‐dimensional thermal modelling. There are few micas younger than 12 Ma, no lag times of less than 6 Myr after 10 Ma and whole‐rock geochemistry and petrography show a significant provenance change at 12 Ma indicating erosion from the Lesser Himalaya at this time. These changes suggest a switch in the dynamics of the orogen that took place during the 12–10 Ma period whereby most strain began to be accommodated by structures within the Lesser Himalaya as opposed to the Greater Himalaya. Consistent data from all three Siwalik sections suggest a lateral continuity in tectonic evolution for the central Himalayas. 相似文献
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Samira Krimissa Jean-Luc Michelot Lhoussaine Bouchaou Jacques Mudry Youssef Hsissou 《Comptes Rendus Geoscience》2004,336(15):1363-1369
The origin of chloride ions in groundwater from the Chtouka-Massa plain (Morocco) was studied by using chemical and isotopic analyses of water, and petrographic and chemical analyses of rocks. It appears that the schist formation, which forms the basement of the studied aquifer, is the main source of the high Cl? concentrations in groundwater. In these schists, chloride is, for a part, probably contained in biotites, and is released into groundwater through the weathering of these minerals. However, the exceptionally high chloride contents of these schists are difficult to explain if one does not assume that they also contain evaporitic-type minerals. To cite this article: S. Krimissa et al., C. R. Geoscience 336 (2004). 相似文献
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The isomeric compositions of the eicosenoic and docosenoic fatty acids of four freshwater fish oils (from sheepshead Aplodinotus grunniens, tullibee Coregonus artedii, maria Lota lota and alewife Alosa pseudoharengus, respectively) were examined by open-tubular gas—liquid chromatography. The 22:1ω11 isomer, usually the dominant isomer in marine-fish oils, was unimportant relative to 22:1ω9. The unsaponifiables lacked fatty alcohols and pristane and were mostly cholesterol. The probability that the 22:1ω1 in marine fish oils is strictly of an exogenous origin (primarily originating as the fatty alcohol in copepod wax esters) is reviewed and it is proposed that docosenoic acids have no obligatory role in the lipid biochemistry of either marine or freshwater fish. 相似文献