Iron oxidation state in the Fe‐rich layer and silica matrix of Libyan Desert Glass: A high‐resolution XANES study     

Gabriele Giuli  Eleonora Paris  Giovanni Pratesi  Christian Koeberl  Curzio Cipriani 《Meteoritics & planetary science》2003,38(8):1181-1186

Abstract— Libyan Desert Glass (LDG) is an enigmatic type of glass that occurs in western Egypt in the Libyan Desert. Fairly convincing evidence exists to show that it formed by impact, although the source crater is currently unknown. Some rare samples present dark‐colored streaks with variable amounts of Fe, and they are supposed to contain a meteoritic component. We have studied the iron local environment in an LDG sample by means of Fe K‐edge highresolution X‐ray absorption near edge structure (XANES) spectroscopy to obtain quantitative data on the Fe oxidation state and coordination number in both the Fe‐poor matrix and Fe‐rich layers. The pre‐edge peak of the high‐resolution XANES spectra of the sample studied displays small but reproducible variations between Fe‐poor matrix and Fe‐rich layers, which is indicative of significant changes in the Fe oxidation state and coordination number. Comparison with previously obtained data for a very low‐Fe sample shows that, while iron is virtually all trivalent and in tetrahedral coordination (^[4]Fe³⁺) in the low‐Fe sample, the sample containing the Fe‐rich layers display a mixture of tetra‐coordinated trivalent iron (^[4]Fe³⁺) and penta‐coordinated divalent iron (^[5]Fe²⁺), with the Fe in the Fe‐rich layer being more reduced than the matrix. From these data, we conclude the following: a) the significant differences in the Fe oxidation state between LDG and tektites, together with the wide intra‐sample variations in the Fe‐oxidation state, confirm that LDG is an impact glass and not a tektite‐like glass; b) the higher Fe content, coupled with the more reduced state of the Fe, in the Fe‐rich layers suggests that some or most of the Fe in these layers may be directly derived from the meteoritic projectile and that it is not of terrestrial origin.  相似文献   

Environmental hydrogeology of the southern sector of the Samborombon Bay wetland,Argentina     

Eleonora Carol  Eduardo Kruse  Jorge Pousa 《Environmental Geology》2008,54(1):95-102

The Samborombon Bay wetland is located on the west margin of the Rio de la Plata estuary, in the Province of Buenos Aires, Argentina. This paper analyses the geological, geomorphologic, soil and vegetation characteristics of the southernmost sector of this wetland and their influence on surface water and groundwater. The study area presents three hydrologic units: coastal dunes, sand sheets and coastal plain. Coastal dunes and sand sheets are recharge zones of high permeability with well-drained, non-saline soils, and a few surface water flows. Changes in the water table are related to rainfall. Groundwater in coastal dunes is Ca–Mg–HCO₃ to Na–HCO₃, and of low salinity (590 mg/l). Groundwater in sand sheets is mainly Na–HCO₃ with a salinity of about 1,020 mg/l. The coastal plain exhibits medium to low permeability sediments, with submerged saline soils poorly drained. Groundwater is Na–Cl with a mean salinity of 16,502 mg/l. A surface hydrological network develops in the coastal plain. Surface water levels near the shoreline are affected by tidal fluctuations; far from the shoreline water accumulates because of poor drainage. Both sectors have Na–Cl water, but the former is more saline. Human intervention and sea level rise may affect the wetland severely.  相似文献   

Présence d'une mangrove à Avicennia au Miocène moyen dans la région de Digne (Alpes-de-Haute-Provence,France) : implications stratigraphiques et paléoclimatiques     

Jean-Jacques Châteauneuf  Hugues Bauer  Isabelle Cojan 《Comptes Rendus Geoscience》2006,338(3):197-205

Avicennia pollen grains have been discovered in marine facies from the Middle Miocene deltaic series of Châteauredon (southeastern France). Based on the local stratigraphy, an age between 15.8 and 16.5 Ma is proposed for these grains. The age and the transgressive context of the Avicennia bearing-levels are in agreement with the maximum extension of the mangrove known in the western Mediterranean during interval N8–NN4 pro parte, in relation with the Langhian highstand. This mangrove occurrence at 42°N latitude during Middle Miocene is a more northern witness of the mangrove sites known in Languedoc and Provence areas. It also implies a lower climatic gradient than today. To cite this article: J.-J. Châteauneuf et al., C. R. Geoscience 338 (2006).  相似文献   

Effet de l'agrégation sur le transport de la kaolinite recouverte d'acide humique à travers un sable de quartz d'origine naturelleAggregation effect on the transport of humic-coated kaolinite colloids through a natural quartz sand     

Rachid Ait Akbour  Jamaâ Douch  Mohamed Hamdani  Philippe Schmitz 《Comptes Rendus Geoscience》2002,334(13):981-985

To evaluate the risk of contaminant transport by mobile colloids, it is necessary to understand how colloids and associated pollutants behave during their migration through uncontaminated soil or groundwater. In this study, we investigated the influence of aggregation induced by Ca²⁺ and trace metals (Pb²⁺, Cu²⁺) concentrations on the transport of humic-coated kaolinite colloids through a natural quartz sand at pH=4. Adsorbed divalent cations reduce the colloids surface charge and thereby induce aggregation and deposition in porous media. To cite this article: R. Ait Akbour et al., C. R. Geoscience 334 (2002) 981–985.  相似文献   

The local structure of Ca-Na pyroxenes. I. XANES study at the Na K-edge     

Annibale Mottana  Takatoshi Murata  Ziyu Wu  Augusto Marcelli  Eleonora Paris 《Physics and Chemistry of Minerals》1997,24(7):500-509

 X-ray absorption Na K-edge spectra have been recorded on synthetic endmember jadeite and on a series of natural Ca-Na pyroxenes compositionally straddling the Jd-Di join. The C2/c members of the series are systematically different from the P2/n members. Differences can be interpreted and explained by comparing the experimental spectra with theoretical spectra. These have been calculated by the multiple-scattering formalism from the atomic positional parameters determined by single-crystal X-ray diffraction structure refinement on the same samples. In the full multiple scattering region of the spectra (1075 to 1090 eV) C-pyroxenes exhibit three features which reflect the 6-2 configuration of the O back-scattering atoms around the Na absorber located at the center of the cluster (site M2 of the jadeite structure). P-pyroxenes show more complicated spectra in which at least four (possibly five) features can be recognized; they reflect the two types of configuration (6-2 and 4-2-2) of O around Na in the two independent M2 and M21 eight-fold coordinated sites of the omphacite structure. A weak, sometimes poorly resolved peak at 1079 eV is diagnostic and discriminates C- from P-pyroxenes. The Garnet Ridge C2/c impure jadeite exhibits a spectrum which is intermediate between those of jadeite and omphacite. The Hedin-Lundqvist potential proves best for these insulating materials and allows multiple-scattering calculations agreeing well with experiments. Received: July 11, 1996/Revised, accepted: October 21, 1996  相似文献   

Turbulent Humidity Fluctuations in the Convective Boundary Layer: Case Studies Using Water Vapour Differential Absorption Lidar Measurements     

Shravan Kumar Muppa  Andreas Behrendt  Florian Späth  Volker Wulfmeyer  Simon Metzendorf  Andrea Riede 《Boundary-Layer Meteorology》2016,158(1):43-66

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Revised method to detect the onset and demise dates of the rainy season in the South American Monsoon areas     

Sâmia R. Garcia  Alan J. P. Calheiros  Mary T. Kayano 《Theoretical and Applied Climatology》2016,126(3-4):481-491

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Carcinogenic risk evaluation for human health risk assessment from soils contaminated with heavy metals     

D. M. Cocârţă  S. Neamţu  A. M. Reşetar Deac 《International Journal of Environmental Science and Technology》2016,13(8):2025-2036

Human activities have progressively increased in recent years. Consequently, significant environment deterioration resulted. Soils have a particularly varied vulnerability to heavy metal pollution, especially in the vicinity of industrial areas. Heavy metal contamination of soil may induce risks and hazards to humans and the ecosystem, while toxic metals in soil can severely inhibit the biodegradation of organic contaminants. This paper is focused on human health risk assessment from extremely contaminated soil with heavy metals, mainly with carcinogenic elements. The study refers to an agricultural area in the vicinity of an old metallurgical processing industrial facility. The contaminants evaluated in the present paper are beryllium (Be), cadmium (Cd), chromium (Cr), nickel (Ni) and lead (Pb). Contamination level is pointed out through laboratory analysis results of soil samples taken from 0–0.2 m, 0.2–0.4 m soil layers and up to 2.1 m soil depth. Some heavy metal concentrations (Cd, Cr and Pb) exceed the intervention thresholds for sensitive areas, as they are stipulated in the national regulation in Romania. The identified average concentration levels of Cd, Cr^VI and Pb in the first layer of the investigated land are 23.83, 7.71 and 704.22 mg/kg_d.w, respectively. The results show that the potential risk of human health is relevant (higher than the acceptable one after World Health Organization) and a possible solution for the remediation should become a major concern for the investigated area.  相似文献   

Variability of mangrove ecosystems along the Brazilian coast   总被引：1，自引：0，他引：1  

Yara Schaeffer-Novelli  Gilberto Cintrón-Molero  Raquel Rothleder Adaime  Tânia Maria de Camargo 《Estuaries and Coasts》1990,13(2):204-218

Brazilian mangroves extend from 4°30′N to 28°30′S, varying greatly in growth form, species distribution patterns, and stand structure, in spite of a limited floristic diversity. We divided the Brazilian coastline into eight units, within which physiographic and climatic conditions are relatively uniform, and described mangrove occurrence, species distribution and structural attributes characteristic of each segment. In general, greates mangrove coverage and greatest forest stature are found in areas with a large surplus of rainfall over potential evapotranspiration and macrotidal regimes. An exception was the segment containing the mouth of the Amazon river, where freshwater systems dominate over brackish or marine associations. We believe that the variability in species associations and the dominance of each in a given environment is predominantly determined by the characteristics of the landforms that can be colonized by each species in a given region. The type, size, and frequency of occurrence of available landforms is a function of the particular mix of fluvial, tidal, and wave energies found in a region. Different species colonize these sites depending on their adaptations and edaphic preferences. Climate affects mangrove colonization and growth. We suggest that Brazilian mangroves play a minor role in modifying the geomorphic setting; the spatial arrangement of the various forest types is a response to the underlying topography and edaphic conditions, and to the constraints imposed by climatic and hydrologic factors. The spatial arrangement of species does not necessarily show successional processes, but may be the result of direct and differential colonization on appropriate substrates.  相似文献   

Complex zoning and resorption in Breunnerite from hall in Tyrol,Austria: Evidence from back-scattered electron microscopy     

Mag. Ch. Spötl 《Mineralogy and Petrology》1989,40(3):225-233

Summary Back-scattered electron imagery (BSE) coupled with energy-dispersive X-ray elemental analysis was applied to petrographic investigations of recrystallized, anchimetamorphic breunnerites (ferroan magnesites). Analyses of polished thin sections allowed the recognition of a complex zoning pattern, invisible by transmitted or reflected light microscopy. Breunnerite precipitation and replacement started with (Mg_0.90Fe_0.07Ca_0.01Mn_0.02) CO₃ and proceeded towards (Mg_0.73Fe_0.22Ca_0.00Mn_0.05)CO₃. This precipitation sequence was interrupted by at least two major events of reverse zoning (i.e. Fe-rich zones followed by Fe-poor ones). Resorption surfaces in Fe-poor zones are common and prove that short-term fluctuations occurred in the paleobrine composition and/or paleotemperature.

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Nachweis komplexer zonierung und resorption im breunnerit mittels Rückstreuelektronenbilder

Zusammenfassung Breunnerit-Proben von der Typlokalität evaporitischer Magnesitlagerstätten (ehemaliger Salzbergbau Hall in Tirol/Österreich) wurden an Hand von Rückstreuelektronen(BSE)-Bildern und energiedispersiven Röntgenanalysen (EDS) untersucht. Während Durch- und Auflichtmikroskopie lediglich eine zweiphasige Kristallisationsgeschichte erkennen ließen, konnte mittels BSE-Bildern eine detaillierte Rekonstruktion der spätdiagenetischen bzw. anchimetamorphen Breunneritbildung durchgeführt werden. Ein genereller Trend zu Fe-reicheren, häufig oszillierend-zonierter Mischkristalle der Reihe Magnesit-Siderit konnte erkannt werden, der jedoch von mindestens zwei invers zonierten Phasen unterbrochen wurde. Resorptionserscheinungen in den Fe-ärmeren Zonen sind verbreitet und belegen kurzfristige Fluktuationen in der Paläofluid-Zusammensetzung und/oder dessen Paläotemperatur.

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With 5 Figures  相似文献