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Spatial and temporal variations of Na, Mg, Si, K, Ca, SO42-, Cl-, HCO3-, Ag, Al, As, Au, B, Ba, Be, Bi, Br, Ce, Cd, Co, Cr, Cs, Cu, Dy, Er, Eu, F, Fe, Ga, Ge, Gd, Hf, Hg, Ho, I, La, Li, Mn, Mo, Nb, Nd, Ni, P, Pb, Pr, Rb, Sb, Sm, Sn, Sr, Ta, Tb, Te, Th, Ti, Tl, U, V, W, Y, Yb, Zn, and Zr were monitored through 37 sampling stations to determine the main aspects influencing the surface-water quality in the Salí River watershed (Tucumán Province, NW Argentina). The influence of the regional geological setting on water chemistry allows to distinguish three sub-basins. The interaction with sedimentary rocks was found to be dominant in the northern and central-eastern sub-basin as well as in the southern sub-basin, whereas the metamorphic-granitic basement of the Pampean Ranges was noted in the central sub-basin. In addition, anthropogenic activities affect the spatial variation of K, P, Mn, Rb, and Pb as well as dissolved oxygen concentrations and Eh. Temporal water-quality variation is related to the spatial distribution of precipitation and to the seasonal character of the main local industries (sugar cane, alcohol, citrus), increasing P and K concentrations and decreasing dissolved oxygen concentration and Eh in winter. Cl-, Na, SO42-, Al, As, B, Fe, Mn, Se and U concentrations exceed the regulated drinking-water thresholds at several sampling stations.  相似文献   
2.
Summary The Iberian Peninsula is one of the regions in the world with higher occurrence of cut-off low systems (COL). The aim of this paper is to analyse the weather events (rainfall and cloudiness layer) associated to COLs in the Iberian Peninsula with tools not previously used: (a) the use of the new multidecadal COLs database developed by Nieto et al (2005) that permit us to study a 41 years period (1958–1998), (b) the checking of the expected weather events (rainfall and cloudiness layer) associated with COLs in a conceptual model (Winkler et al, 2005) and (c) the extensive use of radiosoundings to analyse convective instability in areas inside and close to the COL. Two points of view are used to make the analysis: (1) a source oriented method, when a particular COL is followed and its associated precipitation and cloudiness is analysed over four quadrants in which Iberia was divided and (2) a receptor oriented method, when the precipitation associated to COLs is analysed in given areas, defined by patterns of precipitation. Results reveal that the precipitation and cloudiness patterns associated to COLs in the conceptual model reproduce quite well the main characteristics found over the Iberian Peninsula. The generalized idea that most of the COLs produce intense convective rainfall is show to be misleading. Convective phenomena are important usually when the centre of the COL is located on the Mediterranean region. Most of the rainfall associated with COLs comes from the baroclinic shield; specially in cases located over the west half of the Iberian Peninsula. It is shown that nearly 30% of COLs do not induce any rainfall; most of them located in the southern half of the Peninsula, and mainly during autumn. Only 30% of COLs produce generalized rainfall over the whole analysed territory, being most of them (about 90%) located over the western half of the Iberian Peninsula.  相似文献   
3.
In a cordieritite marking the contact of a granite massif one of the large porphyroblasts of cordierite was found to contain relatively high amounts of BeO (0.93 wt.%) and Na2O (1.25 wt.%), while others are very poor in these components. Na and Be were introduced following the substitution NaBeAl. Like in other sodian beryllian cordierites the distortion index is low (0.12), and a negative correlation between and Be contents is established using additional data from the literature.Dehydration of NaBe-cordierites through heating consistently leads to increasing , and subsequent hydrothermal rehydration of the Soto sample reestablished low . This behavior is consistent with that implied by the model of Stout (1975) which, however, does not apply to the pure system Mg-cordierite-water. Nevertheless it is not certain that the unusual behavior of NaBe-cordierites is due to hydrogen bonding of H2O molecules within the structural channels of cordierite to oxygens of the framework, although the Type II water molecules occurring exclusively in alkali-bearing cordierites and having their H-H vectors parallel [010] (Goldman et al. 1977) would seem mechanically fitter to have this effect than the Type I water with H-H parallel [001] as proposed by Stout (1975). An alternative explanation of this dehydration/rehydration behavior implies positional shifts of sodium within the channels depending on whether or not water is available.  相似文献   
4.
Although fire‐induced soil water repellency (SWR) and its effects on soil hydrology and geomorphology have been studied in detail, very few studies have considered the effect of rock fragments resting on the soil surface or partly embedded in soil. In this research, we have studied the effect of rock fragments on the strength and spatial distribution of fire‐induced SWR at different fire severities. A fire‐affected area was selected for this experiment and classified into different zones according to fire severity (unburned, low, moderate and high) and rock fragment cover (low, <20% and high, >60%). During 7 days after fire, SWR and infiltration rates were assessed in the soil surface covered by individual rock fragments and in the midpoint between two adjacent rock fragments (with maximum spacing of 20 cm). SWR increased with fire severity. Rock fragments resting on the soil surface increased the heterogeneity of the spatial distribution of fire‐induced SWR. SWR increased significantly with rock fragment cover in bare areas under moderate and high fire severity, but quantitatively important changes were only observed under high fire severity. In areas with a low rock fragment cover, water repellency from soil surfaces covered by rock fragments increased relative to bare soil surfaces, with increasing SWR. In areas with a high rock fragment cover, SWR increased significantly from non‐covered to covered soil surfaces only after low‐severity burning. Rock fragment cover did not affect infiltration rates, although it decreased significantly in soil surfaces after high‐severity burning in areas under low and high rock fragment cover. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
5.
Lago Roca-Lapataia valley (54°50′S, 68°34′W) is a paleofjord that was occupied by a valley-glacier system during the glacial maximum of the late Pleistocene (estimated ca. 18–20 ka BP). Deglaciation began before 10,080 ± 270 BP. The marine fauna in several marine terraces found in the area shows that early-middle Holocene climatic conditions were basically the same as at present. Species found are characteristic of cold and shallow waters, although minor temperature fluctuations cannot be ruled out for this period. A recent radiocarbon date of 7518 ± 58 BP on Chlamys patagonica (NZ # 7730) confirms that Lago Roca was transformed into a fjord ca. 7500–8000 BP. The sea reached its maximum level of 8–10 m a.s.l. around 6000 BP and at 4000–4500 BP was at least above 6 ± 1 m a.s.l. Later, when sea level fell, Lago Roca was occupied by fresh water and was no longer tidal. The relative land-sea positions during this period are a consequence of combined eustatic and neotectonic processes.  相似文献   
6.
The North-Andean subduction zone generates recurrent tsunamigenic earthquakes. The seismicity is usually considered to be segmented because of different specific morphological features of the Nazca Plate driving the subduction motion. Most of the recent powerful earthquakes in the margin were located in its northern part. To the south, the region of the Gulf of Guayaquil, only (undocumented) three events in 1901, 1933 and 1953 were possibly powerful and tsunamigenic. Here we are interested in the tsunami signature due to local seismicity. Two realistic earthquake scenarios (Mw = 7 and Mw = 7.5) taking into account the hypothesized segmentation of the area are proposed. Their return period is supposed to be intra-centenary. Then, a larger magnitude unsegmented Mw = 8 scenario is computed (half-millennium return period). The interior of the Gulf of Guayaquil as well as the Santa Elena Peninsula are sheltered areas including numerous coastal infrastructures and the city of Guayaquil. It is predicted that potential flooding would occur at high tide only for both segmented and unsegmented scenarios in (1) south of Playas with however only a few centimeters of wave height and (2) Chanduy (a few meters). Both are important zones of coastal farms.  相似文献   
7.
NaBe-cordierites (Fe/(Fe+Mn+Mg)=0.49–0.57) with BeO contents up to 1.16 weight % and additional Li2O contents up to 0.21 wt.% occur in cordierite-apatite-uraninite-muscovite-biotite-chlorite-feldspar-quartz nodules within pegmatites penetrating gneissic roof pendants of a lower Palaeozoic granite batholith. Occasional small crystals of beryl are interpreted to coexist stably with unaltered cordierite. Be and Li are incorporated in cordieriteaccording to the substitutions Na[Channel] + Be[4] Al[4] and Na[Ch]+Li[6]R2+[6], respectively. The coexisting phyllosilicates do apparently not contain appreciable amounts of Li. According to powder IR-data, the analyzed water contents of the cordierites are dominantly of type II, and there is also little CO2. Their distortion indices are rather low (0.121–0.145) and so are their optic angles (2V=50-51°). Considering all eleven NaBeLi-cordierites known thus far there is a strong positive correlation between Na and (Be+Li) with a slope close to 1.0. However, there is virtually no correlation between Be and Li, their incorporation into cordierite depending on the local geochemical environment. A strong negative correlation exists between the distortion indices of the NaBeLi-cordierites and their Be contents. Li has a disturbing influence on this relationship, and the versus Na correlation is also statistically worse than versus Be.Deceased December 20, 1984  相似文献   
8.
The Late Miocene (7.9 to 4.5 Ma) Pocho volcanic field in Argentina occurs 700 km east of the Chile trench over the modern shallowly dipping Andean Wadati-Benioff zone near 32° S latitude in Argentina. The field is located in the Sierra de Cordoba which is the easternmost Laramide-style, block-faulted range in the Sierras Pampeanas (Pampean ranges). The arrival of the shallowly dipping slab initiated both volcanism and the uplift of the Sierra de Cordoba. Pocho rocks (52% to 68% SiO2; FeO*/MgO>2.2) comprise an older (7.5±0.5 Ma) high-K and a younger (5.3±0.7 Ma) shoshonitic series. Mineralogic data and fractionation models show that crystallization occurred under hydrous, oxidizing conditions, which were most extreme in the high-K series. An unusual pattern of successively lower REE at higher SiO2 concentrations can be modeled by sphene, apatite and amphibole removal. An arc-like trace element signature attributed to an arc component is strongest in the younger shoshonitic series. An important depleted lower crustal/mantle lithospheric source component in both series is indicated by non-radiogenic Sr and Pb isotopic ratios at Nd= 0 to + 2, low Rb/Sr ratios, and low U and Th concentrations. This depleted signature contrasts with the enriched one in potassic back-arc Central Volcanic Zone (CVZ) lavas over the steeper subduction zone to the north and is attributed to several processes in the shallow subduction zone. First, deep crustal (MASH) processes in the nearly normal thickness crust beneath Pocho incorporated depleted Proterozoic basement components, and not complexly mixed structurally thickened crustal components as in the CVZ. Second, the association of Pocho volcanism with the arrival of the slab allowed little time for modification of the mantle by subduction components. Third, Miocene shallowing of the subduction zone beneath the flat-slab required thinning of both the astenosphere and the subcontinental lithosphere. Thus, an important subcrustal component could be from blocks removed from the base of the lithosphere to the west and recycled into the asthenosphere. Similar magmatic sources would have existed during Laramide shallow subduction in western North America.Deceased  相似文献   
9.
Streamflow is the runoff response integrated in space and time over a complex system involving climatic and catchment physiographic factors. In the Andes, accelerating runoff process understanding is hampered by the inability to quantify heterogeneity of surface and subsurface catchment properties. Here, we present a statistical approach based on regression models and correlation analysis that links hydrological signatures and catchment properties to unveil processes in a set of volcanic mountain catchments (latitude 0°30'N) in Ecuador. The catchments represent form and function diversity in the same hydrological unit. We found that despite of similar atmospheric-water inputs the water yield in the north-east region is about 5× larger than in the south-west region and their flow regimes are asymmetric. The soil-bedrock interface and lithology exert a first-order control on hydrologic partitioning, and this allowed us to hypothesize two hydrological mechanisms. Firstly, in the north-east region, the perennial streamflow is associated with seasonal rainfall patterns, and subsequent drainage processes taking place at the surface and subsurface level. The amount of streamflow is related to landform characteristics, high canopy density and root development of forest as well as water holding capacity of organic soils. From a mechanistic standpoint, the low concentration time, steep slopes and shallow infiltration limited by high-consolidated deposits of sedimentary and volcanics suggest a lateral movement of the flow. Secondly, in the south-west region the streamflow regime is mostly groundwater-dependent and it becomes seasonally enhanced by rainfall. Larger seasonal variations of precipitation and temperature result into enhanced evapotranspiration in the drier months, limiting shallow soil infiltration. Under the soil layers, highly permeable pyroclastic deposits and andesitic lavas promote deep percolation. The results highlight the degree of dissimilarity of hydrological processes in Andean settings, but unravelling their complexity seems plausible using streamflow signatures and causal explanatory models.  相似文献   
10.
Summary An earlier developed multidecadal database of Northern Hemisphere cut-off low systems (COLs), covering a 41 years period (from 1958 to 1998) is used to study COLs interannual variability in the European sector (25°–47.5° N, 50° W–40° E) and the major factors controlling it. The study focus on the influence on COLs interannual variability, of larger scale phenomena such as blocking events and other main circulation modes defined over the Euro-Atlantic region. It is shown that there is a very large interannual variability in the COLs occurrence at the annual and seasonal scales, although without significant trends. The influence of larger scale phenomena is seasonal dependent, with the positive phase of the NAO favoring autumn COL development, while winter COL occurrence is mostly related to blocking events. During summer, the season when more COLs occur, no significant influences were found.  相似文献   
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