Comparative Re-Os systematics of chondrites: Implications regarding early solar system processes     

R.J WalkerM.F Horan  J.W MorganH Becker  J.N GrossmanA.E Rubin 《Geochimica et cosmochimica acta》2002,66(23):4187-4201

A suite of 47 carbonaceous, enstatite, and ordinary chondrites are examined for Re-Os isotopic systematics. There are significant differences in the ¹⁸⁷Re/¹⁸⁸Os and ¹⁸⁷Os/¹⁸⁸Os ratios of carbonaceous chondrites compared with ordinary and enstatite chondrites. The average ¹⁸⁷Re/¹⁸⁸Os for carbonaceous chondrites is 0.392 ± 0.015 (excluding the CK chondrite, Karoonda), compared with 0.422 ± 0.025 and 0.421 ± 0.013 for ordinary and enstatite chondrites (1σ standard deviations). These ratios, recast into elemental Re/Os ratios, are as follows: 0.0814 ± 0.0031, 0.0876 ± 0.0052 and 0.0874 ± 0.0027, respectively. Correspondingly, the ¹⁸⁷Os/¹⁸⁸Os ratios of carbonaceous chondrites average 0.1262 ± 0.0006 (excluding Karoonda), and ordinary and enstatite chondrites average 0.1283 ± 0.0017 and 0.1281 ± 0.0004, respectively (1σ standard deviations). The new results indicate that the Re/Os ratios of meteorites within each group are, in general, quite uniform. The minimal overlap between the isotopic compositions of ordinary and enstatite chondrites vs. carbonaceous chondrites indicates long-term differences in Re/Os for these materials, most likely reflecting chemical fractionation early in solar system history.A majority of the chondrites do not plot within analytical uncertainties of a 4.56-Ga reference isochron. Most of the deviations from the isochron are consistent with minor, relatively recent redistribution of Re and/or Os on a scale of millimeters to centimeters. Some instances of the redistribution may be attributed to terrestrial weathering; others are most likely the result of aqueous alteration or shock events on the parent body within the past 2 Ga.The ¹⁸⁷Os/¹⁸⁸Os ratio of Earth’s primitive upper mantle has been estimated to be 0.1296 ± 8. If this composition was set via addition of a late veneer of planetesimals after core formation, the composition suggests the veneer was dominated by materials that had Re/Os ratios most similar to ordinary and enstatite chondrites.  相似文献   

Early Permian climate change in the Falkland Islands     

Phil Stone  Kate Horan 《Geology Today》2016,32(3):107-114

An Early Permian glacial diamictite forms a distinctive unit within the Falkland Islands sedimentary succession and two aspects of its significance have recently been serendipitously enhanced. Fossil discoveries in exotic limestone clasts bear on palaeogeography, whilst a series of mineral‐exploration borehole cores have allowed a detailed study of the sedimentary record of deglaciation that followed deposition of the diamictite. Statistical analysis of reflectance and XRF core‐scanning data has identified likely Milankovitch periodicities and enabled tentative time‐scale modelling. The ‘icehouse to greenhouse’ transition appears to have spanned approximately 1.2 million years, with waning cycles of re‐advance superimposed on overall glacial retreat. The new results play into a long‐debated geological paradox: although the Falkland Islands are now proximal to the South Atlantic coastline of South America, their geology bears an uncanny resemblance to that of the Cape Fold Belt and Karoo Basin in South Africa. This puzzled the geological pioneers, but became readily explicable when first continental drift and then plate tectonics were invoked to reconstruct the break‐up of the Gondwana supercontinent—although the details remain controversial. One of the key stratigraphical correlation levels throughout the major fragments of southern Gondwana—South Africa, South America, Antarctica and Australia—is the glacigenic deposit left behind by the extensive, Late Carboniferous to Early Permian regional glaciation; in the Falkland Islands it is designated the Fitzroy Tillite Formation.  相似文献   

Contributors to chromium isotope variation of meteorites   总被引：3，自引：0，他引：3  

Liping Qin  Conel M.O’D. Alexander  Mary F. Horan 《Geochimica et cosmochimica acta》2010,74(3):1122-400

We report the results of a comprehensive, high precision survey of the Cr isotopic compositions of primitive chondrites, along with some differentiated meteorites. To ensure complete dissolution of our samples, they were first fused with lithium borate-tetraborate at 1050-1000 °C. Relative to the NIST Cr standard SRM 3112a, carbonaceous chondrites exhibit excesses in ⁵⁴Cr/⁵²Cr from 0.4 to 1.6ε (1ε = 1 part in 10,000), and ordinary chondrites display a common ⁵⁴Cr/⁵²Cr deficit of ∼0.4ε. Analyses of acid-digestion residues of chondrites show that carbonaceous and ordinary chondrites share a common ⁵⁴Cr-enriched carrier, which is characterized by a large excess in ⁵⁴Cr/⁵²Cr (up to 200ε) associated with a very small deficit in ⁵³Cr/⁵²Cr (<2ε). We did not find ⁵⁴Cr anomalies in either bulk enstatite chondrites or in leachates of their acid-digestion residues. This either requires that the enstatite chondrite parent bodies did not incorporate the ⁵⁴Cr anomaly carrier phase during their accretion, or the phase was destroyed by parent body metamorphism. Chromium in the terrestrial rocks and lunar samples analyzed here show no deviation from the NIST SRM 3112a Cr standard. The eucrite and Martian meteorites studied exhibit small deficits in ⁵⁴Cr/⁵²Cr. The ⁵⁴Cr/⁵²Cr variations among different meteorite classes suggest that there was a spatial and/or temporal heterogeneity in the distribution of a ⁵⁴Cr-rich component in the inner Solar System.We confirm the correlated excesses in ⁵⁴Cr/⁵²Cr and ⁵³Cr/⁵²Cr for bulk carbonaceous chondrites, but the new data yield a steeper slope (∼6.6) than that reported in Shukolyukov and Lugmair (2006). The correlated excesses may affect the use of the Mn-Cr chronometer in carbonaceous chondrites. We could not confirm the bulk carbonaceous chondrite Mn-Cr isochron reported by Shukolyukov and Lugmair (2006) and Moynier et al. (2007), mostly because we find much smaller total variations in ε⁵³Cr (∼0.2). All bulk chondrites have small ε⁵³Cr excesses (up to 0.3) relative to the Earth, most likely reflecting the sub-chondritic Mn/Cr ratio of the Earth. The ε⁵³Cr variations in chondrites do seem to grossly correlate with Mn/Cr and yield an initial Solar System ⁵³Mn/⁵⁵Mn value of 5.4(±2.4) × 10⁻⁶, corresponding to an absolute age of 4566.4 (±2.2) Ma.Nuclear interactions with cosmic rays result in coupled excesses in ε⁵⁴Cr and ε⁵³Cr with a ∼4:1 ratio in phases with high Fe/Cr. These are most dramatically demonstrated in the iron meteorite Carbo, showing excesses in ε⁵⁴Cr of up to 140ε. These new results show that the Mn-Cr chronometer should be used with caution in samples/minerals with high Fe/Cr and long cosmic ray exposure ages.  相似文献   

Whipple telescope observations of LS I +61 303: 2004–2006     

A. Smith  R. W. Atkins  S. Bradbury  O. Celik  Y. C. K. Chow  P. Cogan  C. Dowdall  S. J. Fegan  P. Fortin  D. Gall  G. H. Gillanders  J. Grube  K. J. Gutierrez  T. A. Hall  D. Hanna  J. Holder  D. Horan  S. B. Hughes  T. B. Humensky  I. Jung  P. Kaaret  G. Kenny  M. Kertzman  D. B. Kieda  A. Konopelko  H. Krawczynski  F. Krennrich  M. J. Lang  S. Le Bohec  G. Maier  J. Millis  P. Moriarty  R. A. Ong  J. S. Perkins  K. Ragan  G. H. Sembroski  J. A. Toner  L. Valcarcel  V. V. Vassiliev  R. G. Wagner  S. P. Wakely  T. C. Weekes  R. J. White  D. A. Williams 《Astrophysics and Space Science》2007,309(1-4):299-303

In this paper we present the results of the past two years observations on the galactic microquasar LS I +61 303 with the Whipple 10 m gamma-ray telescope. The recent MAGIC detection of the source between 200 GeV and 4 TeV suggests that the source is periodic with very high energy (VHE) gamma-ray emission linked to its orbital cycle. The entire 50-hour data set obtained with Whipple from 2004 to 2006 was analyzed with no reliable detection resulting. The upper limits obtained in the 2005–2006 season covered several of the same epochs as the MAGIC Telescope detections, albeit with lower sensitivity. Upper limits are placed on emission during the orbital phases of 0→0.1 and 0.8→1, phases which are not included in the MAGIC data set.   相似文献   

Chemical and chronologic complexity in the convecting upper mantle: Evidence from the Taitao ophiolite, southern Chile   总被引：1，自引：0，他引：1  

Ruth F. Schulte  Manuel Schilling  Ryo Anma  James Farquhar  Mary F. Horan  Tsuyoshi Komiya  Philip M. Piccoli  Lynnette Pitcher  Richard J. Walker   《Geochimica et cosmochimica acta》2009,73(19):5793-5819

Exposure of the ca. 6 Ma Taitao ophiolite, Chile, located 50 km south of the Chile Triple Junction, allows detailed chemical and isotopic study of rocks that were recently extracted from the depleted mantle source of mid-ocean ridge basalts (DMM). Ultramafic and mafic rocks are examined for isotopic (Os, Sr, Nd, and O), and major and trace element compositions, including the highly siderophile elements (HSE). Taitao peridotites have compositions indicative of variable extents of partial melting and melt extraction. Low δ¹⁸O values for most whole rock samples suggest some open-system, high-temperature water–rock interaction, most likely during serpentinization, but relict olivine grains have δ¹⁸O values consistent with primary mantle values. Most of the peridotites analyzed for Nd–Sr isotopes have compositions consistent with estimates for the modern DMM, although several samples are characterized by ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd indicative of crustal contamination, most likely via interactions with seawater. The peridotites have initial ¹⁸⁷Os/¹⁸⁸Os ratios that range widely from 0.1168 to 0.1288 (γ_Os = −8.0 to +1.1), averaging 0.1239 (γ_Os = −2.4), which is comparable to the average for modern abyssal peridotites. A negative correlation between the Mg^# of relict olivine grains and Os isotopic compositions of whole rock peridotites suggests that the Os isotopic compositions reflect primary mantle Re/Os fractionation produced by variable extents of partial melting at approximately 1.6 Ga. Recent re-melting at or near the spatially associated Chile Ridge further modified these rocks, and Re, and minor Pt and Pd were subsequently added back into some rocks by late-stage melt–rock or fluid–rock interactions.In contrast to the peridotites, approximately half of the mafic rocks examined have whole rock δ¹⁸O values within the range of mantle compositions, and their Nd and Sr isotopic compositions are all generally within the range of modern DMM. These rocks have initial ¹⁸⁷Os/¹⁸⁸Os ratios, calculated for 6 Ma, that range from 0.126 (γ_Os = −1) to as high as 0.561 (γ_Os = +342). The Os isotopic systematics of each of these rocks may reflect derivation from mixed lithologies that include the peridotites, but may also include pyroxenites with considerably more radiogenic Os than the peridotites. This observation supports the view that suprachondritic Os present in MORB derives from mixed mantle source lithologies, accounting for some of the worldwide dichotomy in ¹⁸⁷Os/¹⁸⁸Os between MORB and abyssal peridotites.The collective results of this study suggest that this >500 km³ block of the mantle underwent at least two stages of melting. The first stage occurred at 1.6 Ga, after which the block remained isolated and unmixed within the DMM. A final stage of melting recently occurred at or near the Chile Ridge, resulting in the production of at least some of the mafic rocks. Convective stirring of this mantle domain during a >1 Ga period was remarkably inefficient, at least with regard to Os isotopes.  相似文献   

Pt-Os and Re-Os systematics of the Sudbury Igneous Complex, Ontario     

John W. Morgan  Richard J. WalkerMary F. Horan  Ellyn S. BearyAnthony J. Naldrett 《Geochimica et cosmochimica acta》2002,66(2):273-290

We measured by negative thermal ionization mass spectrometry (NTIMS) Re, Os and ¹⁸⁶Os/¹⁸⁸Os and ¹⁸⁷Os/¹⁸⁸Os in 26 samples of 18 Ni-Cu sulfide ores from the Falconbridge, McCreedy West, and Strathcona mines at Sudbury, Ontario. At McCreedy West and Falconbridge, the isochron Re-Os ages are 1835 ± 70 Ma and 1827 ± 340 Ma, and the initial ¹⁸⁷Os/¹⁸⁸Os ratios 0.514 ± 0.019 and 0.550 ± 0.024, respectively. The ages agree with the canonical value of 1850 ± 1 Ma for the Sudbury Igneous Complex (SIC). For Hangingwall and Deep Zone ores at Strathcona, the age of 1780 ± 7 Ma may reflect resetting by dyke activity. The high initial ¹⁸⁷Os/¹⁸⁸Os of 0.934 ± 0.005 in these ores is distinct from those at McCreedy West and Falconbridge. Strathcona Deep Copper Zone ores have highly radiogenic Os giving a mean model age of 1883 ± 54 Ma that is similar to ages at McCreedy West and Falconbridge, but distinct from other Strathcona sulfides. Initial ¹⁸⁶Os/¹⁸⁸Os in two Strathcona ores with low ¹⁹⁰Pt/¹⁸⁸Os average 0.119 826 ± 0.000 009 (n = 3) and 0.119 827 ± 0.000 004 (n = 3), respectively, with a grand mean of 0.119 827 ± 0.000 003. This ratio may be slightly lower than the chondritic value at that time. Similar ores at Falconbridge and McCreedy West show more scatter, averaging 0.119 855 ± 0.000 008 (n = 6) and 0.119 867 ± 0.000 020 (n = 3), respectively. These values are substantially suprachondritic. The Re-Os isotope systematics of Sudbury ores are clearly of crustal origin and may be derived from a binary mixture of Superior Province and Huronian metasedimentary rocks, with Strathcona, Falconbridge, and McCreedy West ores containing, respectively, 55%, 16%, and 12% of Os from Superior sediments. The suprachondritic ¹⁸⁶Os/¹⁸⁸Os at McCreedy West and Falconbridge may be due to admixture of Archean or Paleozoic mafic rocks with ¹⁹⁰Pt/¹⁸⁸Os ≈ 0.1. No trace of the asteroid that produced the Sudbury Structure has been reported. At the Whistle mine S-poor olivine melanorite inclusions with high Ni and Os and low ¹⁸⁷Os/¹⁸⁸Os may contain the signature of a magmatically fractionated asteroidal core contributing 1 to 2.5 % metal. The S-poor melanorite Ni and Os data are equally well explained by admixture of ≈40% mantle peridotite, however.  相似文献   

Direct measurements of the gradual extreme ultraviolet emission from large solar flares     

D. M. Horan  R. W. Kreplin  K. P. Dere 《Solar physics》1983,85(2):303-312

Broadband sensors aboard the Naval Research Laboratory's SOLRAD 11 satellites measured solar emission in the 0.5 to 3 Å, 1 to 8 Å, 8 to 20 Å, 100 to 500 Å, 500 to 800 Å, and 700 to 1030 Å bands. Data from sixteen large flares show that the EUV emission is dominated by gradual emission which parallels the soft X-ray emission in duration and magnitude. The data are consistent with the separation of EUV and X-ray flare emission into two distinct components. A persistent component is made up of gradual EUV and gradual soft X-ray emissions. A brief component consists of hard X-rays, impulsive soft X-rays, and impulsive EUV emission.  相似文献   

Study of nuclear decays during a solar eclipse: Thule Greenland 2008     

D. Javorsek II  M. C. Brewer  J. B. Buncher  E. Fischbach  J. T. Gruenwald  J. Heim  A. W. Hoft  T. J. Horan  J. L. Kerford  M. Kohler  J. J. Lau  A. Longman  J. J. Mattes  T. Mohsinally  J. R. Newport  M. A. Petrelli  C. A. Stewart  J. H. Jenkins  R. H. Lee  B. Morreale  D. B. Morris  R. Mudry  D. O’Keefe  B. Terry  M. A. Silver  P. A. Sturrock 《Astrophysics and Space Science》2012,338(1):9-13

A new prediction technique based on logarithmic values is proposed to predict the maximum amplitude (R _m) of a solar cycle from the preceding minimum aa geomagnetic index (aa _min). The correlation between lnR _m and lnaa _min (r=0.92) is slightly stronger than that between R _m and aa _min (r=0.90). From this method, cycle 24 is predicted to have a peak size of R _m(24)=81.7(1±13.2%). If the suggested error in aa (3 nT) before 1957 is corrected, the correlation coefficient between R _m and aa _min (r=0.94) will be slightly higher, and the peak of cycle 24 is predicted much lower, R _m(24)=52.5±13.1. Therefore, the prediction of R _m based on the relationship between R _m and aa _min depends greatly on the accurate measurement of aa.  相似文献   

Chemical Separation of Tungsten and Other Trace Elements for TIMS Isotope Ratio Measurements Using Organic Acids     

Bradley J. Peters  Andrea Mundl‐Petermeier  Mary F. Horan  Richard W. Carlson  Richard J. Walker 《Geostandards and Geoanalytical Research》2019,43(2):245-259

One requirement for isotope ratio measurement results with small measurement uncertainties is that the element of interest is effectively separated from the sample matrix. Efficient chemical separation of W from matrix components, especially Ti, can be challenging, particularly for large test portion masses (> 1 g). We present a new W separation procedure that takes advantage of the distinct complexation behaviour of Ti and W with citrate ligand in a moderately low pH, oxidising solution. This preparation procedure can reduce the Ti/W ratio of large (4–10 g) basaltic (i.e., high‐matrix) test portions by a factor of 10⁵, relative to their original compositions, in a two‐step separation procedure. The procedure additionally provides a separate, well‐purified Mo fraction. We show that optimal separation requires precise selection of reagent concentrations and sample load. The procedure was employed to determine the μ¹⁸²W composition of BHVO‐2 as ?6.7 ± 4.2 (2 standard deviation, 2s). The principles derived from this method may prove useful for chemical separation of other elements used for geochemical and cosmochemical applications given an appropriate selection of organic acid. Future successful applications of this method may reveal that the use of organic acids as procedural reagents is a currently under‐utilised tool for efficient chemical separation protocols.  相似文献   

Re — Os isotopic constraints on the origin of volcanic rocks,Gorgona Island,Colombia: Os isotopic evidence for ancient heterogeneities in the mantle     

R. J. Walker  L. M. Echeverria  S. B. Shirey  M. F. Horan 《Contributions to Mineralogy and Petrology》1991,107(2):150-162

The Re — Os isotopic systematics of komatiites and spatially associated basalts from Gorgona Island, Colombia, indicate that they were produced at 155±43 Ma. Subsequent episodes of volcanism produced basalts at 88.1±3.8 Ma and picritic and basaltic lavas at ca. 58 Ma. The age for the ultramafic rocks is important because it coincides with the late-Jurassic, early-Cretaceous disassembly of Pangea, when the North- and South-American plates began to pull apart. Deep-seated mantle upwelling possibly precipitated the break-up of these continental plates and caused a tear in the subducting slab west of Gorgona, providing a rare, late-Phanerozoic conduit for the komatiitic melts.Mantle sources for the komatiites were heterogeneous with respect to Os and Pb isotopic compositions, but had homogeneous Nd isotopic compositions (_Nd+9±1). Initial ¹⁸⁷Os/¹⁸⁶Os normalized to carbonaceous chondrites at 155 Ma (_Os) ranged from 0 to +22, and model-initial values ranged from 8.17 to 8.39. The excess radiogenic Os, compared with an assumed bulk-mantle evolution similar to carbonaceous chondrites, was likely produced in portions of the mantle with long-term elevated Re concentrations. The Os, Pb and Nd isotopic compositions, together with major-element constraints, suggest that the sources of the komatiites were enriched more than 1 Ga ago by low (<20%) and variable amounts of a basalt or komatiite component. This component was added as either subducted oceanic crust or melt derived from greater depths in the mantle. These results suggest that the Re — Os isotope system may be a highly sensitive indicator of the presence of ancient subducted oceanic crust in mantle-source regions.  相似文献