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1.
Tellurium,selenium and cobalt enrichment in Neoproterozoic black shales,Gwna Group,UK: Deep marine trace element enrichment during the Second Great Oxygenation Event 
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下载免费PDF全文 Joseph G. T. Armstrong John Parnell Liam A. Bullock Magali Perez Adrian J. Boyce Jorg Feldmann 《地学学报》2018,30(3):244-253
Black shales of the late Neoproterozoic Gwna Group (570–580 Ma), UK, contain enrichments of tellurium (Te), selenium (Se) and cobalt (Co) relative to average shale compositions. The Te and Co enrichments bear comparison with those of ferromanganese crusts in the modern deep ocean. Gwna Group deposition coincides with the Second Great Oxidation Event, which had a significant effect on trace element fixation globally. Selenium and Te concentrations within these black shales indicate increased continental weathering rates, high biological productivity and corresponding increases in atmospheric O2 concentrations. Cobalt, nickel (Ni) and arsenic (As) enrichments in this succession are secondary mineralisation phases. Demand for many of the trace elements found enriched in the Gwna Group black shales make their mechanisms of accumulation, and variations through the geological record, important to understand, and suggests that new resources may be sought based on black shale protoliths from this period. 相似文献
2.
P.J. Patchett W.M. White H. Feldmann S. Kielinczuk A.W. Hofmann 《Earth and Planetary Science Letters》1984,69(2):365-378
Among long-lived radioactive parent-daughter element pairs, the ratio Lu/Hf is strongly fractionated relative to constant Sm/Nd in the Earth's sedimentary system. This is caused by high resistance to chemical weathering of the mineral zircon (Zr,Hf)SiO4. Zircon-bearing sandy sediments on and near continents have very low Lu/Hf, while deep-sea clays have up to three times the chondritic Lu/Hf ratio. Turbidity currents mechanically carry the low-Lu/Hf sandy material onto the ocean floor. The results are important for the crust-to-mantle recycling discussion, where most recycled materials would be subducted oceanic sediments. Such sediment should be capable of explaining the HfNd mantle isotopic variation by mixing with peridotite, but in fact any average pelagic sediment has Nd/Hf and Lu/Hf too high to allow mixing curves to pass through the Hf/Nd isotopic array. The array could only be reproduced by subduction of turbidite sandstone with pelagic sediment in the approximate ratio 1.2 to 1, and by maintaining a good mixture between the two components. At least today, turbidites are available for subduction only at locations quite different and distant from those where pelagic sediments may be recycled; furthermore, mantle isotopic variation shows that the mantle often cannot mix itself well enough to homogenize these widely-separated sedimentary components to the degree required. The Lu/Hf fractionations place a severe restriction on the ability of recycled sediments to explain mantle isotopic patterns. 相似文献
3.
Three physical quantities define the essentials of the cosmic ray exposure history of a sample of an iron meteorite: (1) the cosmic ray exposure age T, (2) the pre-atmospheric “size” S of the irradiated body, and (3) the location, i.e. the “depth” D, of the samples within the body. To establish these quantities for a given sample three independent quantities must be determined experimentally. In the present work T is ascertained by the 41K/40K method and the 4He and 21Ne concentrations (C4 and C21) are measured by the isotope dilution method. Signer and Nier's evaluation of the rare gas distribution in the meteorite Grant and the measured exposure age for this meteorite provide the relationships allowing to ascertain for any meteorite the quantities S and D from the 21Ne production rate (P21 = C21/T) and the 4He/21Ne ratio.Earlier measurements have provided data on the isotopic composition of potassium in 74 different iron meteorites. New rare gas measurements are reported for some 40 samples. Results on the age, size and depth are obtained for almost 60 samples. These data suggest that Signer and Nier's model is well suited for describing not only the rare gas distribution in a single selected meteorite (Grant) but also the exposure histories of the great majority of all irons. For a few samples, however, secondary breakups of the meteoroid and a two- or multiple-stage irradiation must be invoked. Further measurements are proposed for testing and, possibly, refining the still somewhat uncertain relationships between the abundances of cosmogenic nuclides and the quantities T, S, and D in very large meteorites.Histograms are presented showing the age distributions for irons of different chemical groups and of different size ranges.The feasibility and the relative merits of other methods for the determination of T, S, and D are discussed. 相似文献
4.
Vertical eddy diffusivity estimations in Swan river estuary 总被引：1，自引：0，他引：1
A field experiment is described in which diapycnal diffusivity is estimated by direct and indirect methods in Swan river estuary, Perth, Western Australia. The microstructure profiles were collected in a narrow and straight part of this estuary using a portable flux profiler (PFP). The profiles were segmented into stationary parts and the rate of vertical eddy diffusivity was estimated for the segments within the pycnocline. The direct measurement showed that instantaneous flux could be positive or negative with a low net rate of vertical eddy diffusivity for mass of about 6.5 × 10−8 m2 s−1. All the indirect methods overestimated this rate. However, within the indirect methods, the method of Osborn yielded the poorest estimate while the method of Osborn and Cox gave the closest estimate. 相似文献
5.
This investigation had the purpose of evaluating the reliability of a sequential extraction procedure according to Zeien and Brümmer (1989) which is performed routinely to analyse the distribution of heavy metals to different soil phases. Reliability was tested by two hypotheses. According to the first hypothesis an error propagation increased during a morefold extraction of heavy metals from a single soil sample to such an extend that it does not allow a statistical comparison of different analyses. This assumption was confirmed in an interlaboratory study of five participants applying the sequential extraction scheme on two different soils. The heavy metal amounts extracted by the different partners were of the same magnitude, but from the results no statistical correspondence at the 95% confidence level could be observed. The second hypothesis stated that also weak extraction agents were able to release metals from the more immobile soil fractions, especially if the amount of easily soluble metals was comparatively small. To answer this question the sequential extraction was modified by carrying out selected weak extraction steps several times. As expected the intensified extraction conditions caused a decrease of the element content within the more resistant phases. However, the additional release in the first four extraction steps of Pb, Mn, Fe, and Zn was only in the range of 5 to 10%. Furthermore, it was observed that a single EDTA extraction (step four within the sequential extraction scheme) was capable to extract the same amount of metals as the first four extraction steps of the original scheme at a variation of about 15%. From these results it was concluded that the EDTA step alone already represents a reliable pool of mobilisable metals. Thus it can be maintained that such a simple single EDTA extraction can be used to assess the environmental risk from heavy metal contaminated soils or to predict the potential heavy metal release of soil remediation processes. 相似文献
6.
R. Feldmann C. M. Carollo C. Porciani S. J. Lilly P. Capak Y. Taniguchi O. Le Fèvre A. Renzini N. Scoville M. Ajiki H. Aussel T. Contini H. McCracken B. Mobasher T. Murayama D. Sanders S. Sasaki C. Scarlata M. Scodeggio Y. Shioya J. Silverman M. Takahashi D. Thompson G. Zamorani 《Monthly notices of the Royal Astronomical Society》2006,372(2):565-577
7.
Fortunato André B. Meredith Edmund P. Rodrigues Marta Freire Paula Feldmann Hendrik 《Natural Hazards》2019,98(3):1003-1020
Natural Hazards - Decadal predictions bridge the gap between the short-term weather/seasonal forecasts and the long-term climate projections. They target the reproduction of large-scale weather... 相似文献
8.
对全球寒武系与奥陶系界线层型剖面和点位(GSSP)——西纽芬兰绿岬(Green Point)剖面和我国吉林白山(原浑江)大阳岔小洋桥原全球寒武系与奥陶系界线候选剖面的对比研究表明,绿岬"金钉子"剖面所指定的界线生物标志——波动古大西洋牙形石(Iapetognathus fluctivagus)并不存在于所指定的界线生物层和点位上,而且在分布和分类上是均存在争议的物种,更遗憾的是,所展示的大部分牙形石和笔石标本图片以及碳氧同位素异常数据也并非来自该"金钉子"剖面,因而完全违背了选择金钉子剖面的原则和要求,有必要进行重新的评估。小洋桥寒武系与奥陶系界线剖面交通方便、环境优美,寒武系与奥陶系界线地层系由一套深水且未变质的黑色、黄绿色页岩与灰色薄层瘤状灰岩所构成的韵律沉积组成,并保存了完整的具有广泛代表性牙形石和笔石序列,在详细研究的34 m界线间隔中,自下而上保存了完整的Cambrostodus、Codylodus proavus、C.intermedius、C.lindstromi和C.angulatus等5牙形石生物带,在C.intermedius带上部至C.angulatus带之间,还依次出现3层笔石,归属于重新厘定的Rhabdinopora parabola和Anisograptus matanensis等2个笔石带,此外还有大量三叶虫和介形类化石共生,结合高精度同位素地球化学的研究,笔者等建议,以全球广泛分布的牙形石C.intermedius的首现,取代Iapetognathus fluctivagus,作为寒武系与奥陶系界线划分对比的标志,其层位与原来所指定的界线层几乎一致或接近,界线之上所记录的最大碳同位素异常和首次出现的最早的浮游正笔石——R.parabola(含R.praeparabola),可作为该界线划分的辅助标志。 相似文献
9.
Thomas Heberer Dirk Feldmann Kirsten Reddersen Hans‐Juergen Altmann Thomas Zimmermann 《洁净——土壤、空气、水》2002,30(1):24-33
In military out of area missions of the Bundeswehr, it can be necessary to produce drinking water even from highly polluted surface waters containing a variety of organic, inorganic, and microbiological contaminants. Thus, mobile drinking water purification systems must be able to remove such contaminants as far as possible to meet the requirements of the German and European drinking water regulation/directive. Presently, two novel drinking water purification units applying membrane filtration undergo intensive long‐term trials carried out by the Bundeswehr. If these trials positively proof the functionality of these units and their ability to remove all possible contaminants they shall substitute so far available devices which use large amounts of chemicals and charcoal filtration for water purification.In the course of a research project, the functionality of the new devices and their efficacy to remove high amounts of algae, microbes, and organic and inorganic pollutants are additionally tested in “worst‐case” field studies. In September 2000, the first mobile drinking water purification unit was tested at the Teltowkanal in Berlin, Germany.This canal was chosen because it carries high burdens of municipal sewage effluents. The results from the fatigue test confirmed the ability of the water purification unit to reduce the concentrations of all contaminants meeting the maximum tolerance levels set by the German/European drinking water regulation.The pre‐filtration device was very effective in removing algae and solid particles to protect the membranes from clogging and to enable an almost maintenance‐free operation. Residues of pharmaceuticals and some other organic contaminants have almost totally been removed from the surface water where they were detected at individual concentrations up to the μg/L‐level. 相似文献
10.
Sediment Melts at Sub-arc Depths: an Experimental Study 总被引：14，自引：0，他引：14
The phase and melting relations in subducted pelites have beeninvestigated experimentally at conditions relevant for slabsat sub-arc depths (T = 600–1050°C, P = 2·5–4·5GPa). The fluid-present experiments produced a dominant paragenesisconsisting of garnet–phengite–clinopyroxene–coesite–kyanitethat coexists with a fluid phase at run conditions. Garnet containsdetectable amounts of Na2O (up to 0·5 wt%), P2O5 (upto 0·56 wt%), and TiO2 (up to 0·9 wt%) in allexperiments. Phengite is stable up to 1000°C at 4·5GPa and is characterized by high TiO2 contents of up to 2 wt%.The solidus has been determined at 700°C, 2·5 GPaand is situated between 700 and 750°C at 3·5 GPa.At 800°C, 4·5 GPa glass was present in the experiments,indicating that at such conditions a hydrous melt is stable.In contrast, at 700°C, 3·5 and 4·5 GPa, asolute-rich, non-quenchable aqueous fluid was present. Thisindicates that the solidus is steeply sloping in P–T space.Fluid-present (vapour undersaturated) partial melting of thepelites occurs according to a generalized reaction phengite+ omphacite + coesite + fluid = melt + garnet. The H2O contentof the produced melt decreases with increasing temperature.The K2O content of the melt is buffered by phengite and increaseswith increasing temperature from 2·5 to 10 wt%, whereasNa2O decreases from 7 to 2·3 wt%. Hence, the melt compositionschange from trondhjemitic to granitic with increasing temperature.The K2O/H2O increases strongly as a function of temperatureand nature of the fluid phase. It is 0·0004–0·002in the aqueous fluid, and then increases gradually from about0·1 at 750–800°C to about 1 at 1000°C inthe hydrous melt. This provides evidence that hydrous meltsare needed for efficient extraction of K and other large ionlithophile elements from subducted sediments. Primitive subduction-relatedmagmas typically have K2O/H2O of 0·1–0·4,indicating that hydrous melts rather than aqueous fluids areresponsible for large ion lithophile element transfer in subductionzones and that top-slab temperatures at sub-arc depths are likelyto be 700–900°C. KEY WORDS: experimental petrology; pelite; subduction; UHP metamorphism; fluid; LILE 相似文献