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1.
Single crystals of akermanite (Ca1–x
Sr
x
)2Co-Si2O7 solid solution were grown in nitrogen by the floating zone method using a lamp-image furnace. The grown crystals were 6 mm in diameter by 50 mm in length. Microprobe analyses indicate uniform strontium content x except in the initially crystallized part. Synthetic crystals with x from 0.0 to 0.3 give, at room temperature, satellite reflections and circular diffuse scatterings in the electron diffraction pattern, which are related to an incommensurate phase and microdomains, respectively. With increasing Sr content the wavelength of a modulation increases and the intensity of satellites decreases, but the intensity of circular diffuse scattering increases up to x=0.15 and then decreases until eventually the satellites and the circular diffuse scatterings disappear at x = 0.3. The circular diffuse scattering is explained by the cluster model for the transition state, proposed by De Ridder et al. (1976). 相似文献
2.
K. Kusaka K. Hagiya M. Ohmasa Y. Okano M. Mukai K. Iishi N. Haga 《Physics and Chemistry of Minerals》2001,28(3):150-166
The structures of Ca2CoSi2O7, Ca2MgSi2O7, and Ca2(Mg0.55Fe0.45)Si2O7 have been determined in the temperature range between 297 and 773 K with arbitrary intervals. The structures of the incommensurate
phase of the three compounds are characterized by the presence of the six-, seven-, and eight-coordinated Ca–O polyhedra and
of the bundles along the c-axes consisting of four arrays of the six-coordinated Ca–O polyhedra and an array of T1O4 (T1: Co, Mg, or Mg–Fe) tetrahedra in the structures. The number of bundles in each material decreases at elevated temperatures.
The incommensurate phase undergoes a phase transition into the normal phase at 493 K in Ca2CoSi2O7, at 360 K in Ca2MgSi2O7, and at 510 K in Ca2(Mg0.55Fe0.45)Si2O7. The features of the structures of the normal phase are almost the same as those found in the basic structures (the averaged
structures of the incommensurate structures), and this fact implies that the characteristics of the structures, such as the
six-coordinated Ca–O polyhedra or fragments of the bundles, should be partially preserved at higher temperatures both in the
incommensurate structures and also in the structures of the normal phase. Analyses of anisotropic displacement parameters
clarified that disorder of the modulation waves is developed in the structures at higher temperatures. The evolution of a
disorder in the structures was ascertained by observation of the circular diffuse streaks in the vicinity of the transition
temperature between the incommensurate and normal phases.
Received: 3 July 2000 / Accepted: 26 October 2000 相似文献
3.
Arata Sugimura Tokihiko Matsuda Kiyotaka Chinzei Kazuaki Nakamura 《Bulletin of Volcanology》1963,26(1):125-140
The late Cenozoic orogeny in Japan is briefly reviewed. Amounts of volcanic materials in the three periods of the orogeny are estimated at: early Neogene 150 × 103 km3 (mafic 40 %, salic 60 %), middle and late Neogene 20 × 103 km3 (mafic 70 %, salic 30 %), Quaternary 5 × 103 km3 (mafic 80 %, salic 20 %). The largest volume per unit time is in the early Neogene, and the smallest in the middle and late Neogene. Volume per unit area becomes larger towards the southeastern margin or «front» of the volcanic belt. Thermal energy transported by volcanic materials is compared with the terrestrial heat flow in the belt. 相似文献
4.
Yoshiyuki Kaneko Shigenori Maruyama Ade Kadarusman Tsutomu Ota Masahiro Ishikawa Tatsuki Tsujimori Akira Ishikawa Kazuaki Okamoto 《Gondwana Research》2007,11(1-2):218
The Timor–Tanimbar islands of eastern Indonesia form a non-volcanic arc in front of a 7 km deep fore-arc basin that separates it from a volcanic inner arc. The Timor–Tanimbar Islands expose one of the youngest high P/T metamorphic belts in the world, providing us with an excellent opportunity to study the inception of orogenic processes, undisturbed by later tectonic events.Structural and petrological studies of the high P/T metamorphic belt show that both deformation and metamorphic grade increase towards the centre of the 1 km thick crystalline belt. Kinematic indicators exhibit top-to-the-north sense of shear along the subhorizontal upper boundaries and top-to-the-south sense in the bottom boundaries of the high P/T metamorphic belt. Overall configuration suggests that the high P/T metamorphic rocks extruded as a thin sheet into a space between overlying ophiolites and underlying continental shelf sediments. Petrological study further illustrates that the central crystalline unit underwent a Barrovian-type overprint of the original high P/T metamorphic assemblages during wedge extrusion, and the metamorphic grade ranged from pumpellyite-actinolite to upper amphibolite facies.Quaternary uplift, marked by elevation of recent reefs, was estimated to be about 1260 m in Timor in the west and decreases toward Tanimbar in the east. In contrast, radiometric ages for the high P/T metamorphic rocks suggest that the exhumation of the high P/T metamorphic belt started in western Timor in Late Miocene time and migrated toward the east. Thus, the tectonic evolution of this region is diachronous and youngs to the east. We conclude that the deep-seated high P/T metamorphic belt extrudes into shallow crustal levels as a first step, followed by doming at a later stage. The so-called ‘mountain building’ process is restricted to the second stage. We attribute this Quaternary rapid uplift to rebound of the subducting Australian continental crust beneath Timor after it achieved positive buoyancy, due to break-off of the oceanic slab fringing the continental crust. In contrast, Tanimbar in the east has not yet been affected by later doming. A wide spectrum of processes, starting from extrusion of the high P/T metamorphic rocks and ending with the later doming due to slab break-off, can be observed in the Timor–Tanimbar region. 相似文献
5.
Kazuaki Okamoto 《Island Arc》1998,7(1-2):283-294
The orientation of straight inclusion trails within albite porphyroblasts from basic schists has been measured around a north-closure fold, in the Besshi district of the Sambagawa Belt, central Shikoku, Japan. The porphyroblasts are aligned with their longest dimension parallel to both the subhorizontal, east–west-directed mineral lineation and to the fold axis. There is a systematic variation in inclusion-trail geometry between the upper (northern) and lower (southern) fold limbs. The shear sense deduced from quartz c-axis fabrics is top-to-the-west in the upper limb and top-to-the-east in the lower limb. Based on observed variations in porphyroblast inclusion trails, the structural history can be modelled as follows: (i) shear flow caused east–west stretching and folding of the metamorphic zonation; (ii) east–west ductile shear resulted in opposing senses of shear in the upper and lower limbs as the eclogite body situated in the core of the fold was extruded to the east. 相似文献
6.
Polarised Raman and infrared spectra of (ir) andalusite (Al2SiO5) single crystals have been measured and interpreted on the basis of a rigid-ion model calculation. The Al-O bond strength is found to be about 70% ionic in character whereas the mainly covalently bound SiO4 tetrahedra show ca. 40% ionicity. The interatomic short range forces are strongest between silicon and oxygen and rather weak around the fivefold coordinated aluminium. Thermal soft modes appear above 200°C and are correlated with a weakening of the Al-O bonds. 相似文献
7.
Kazuaki Iishi 《Physics and Chemistry of Minerals》1978,3(1):1-10
The short-range force constants and the contribution of the potential energy to the elastic constants have been calculated from explicit expressions for the elastic constants and for the optical frequencies. The large elastic constants of corundum are attributable to the contribution of the large short-range stretching forces. The frequencies of the phonon spectrum and the contribution of the potential energy to the frequencies have also been calculated based on a rigid-ion and polarizable-ion model. The effective charge of an oxygen ion is found to be ?0.955e. The electronic polarizability of an aluminium and oxygen ion is found to be 0.05 and 1.36 Å3, respectively. 相似文献
8.
Kazuaki Okamoto Hironao Shinjoe Ikuo Katayama Kentaro Terada Yuji Sano Simon Johnson 《地学学报》2004,16(2):81-89
In order to decipher the origin of eclogite in the high‐P/T Sanbagawa metamorphic belt, SHRIMP U–Pb ages of zircons from quartz‐bearing eclogite and associated quartz‐rich rock (metasandstone) were determined. One zircon core of the quartz‐rich rock yields an extremely old provenance age of 1899 ± 79 Ma, suggesting that the core is of detrital origin. Eight other core ages are in the 148–134 Ma range, and are older than the estimated age for trench sedimentation as indicated by the youngest radiolarian fossil age of 139–135 Ma from the Sanbagawa schists. Ages of metamorphic zircon rims (132–112 Ma) from the quartz‐rich rock are consistent with metamorphic zircon ages from the quartz‐bearing eclogite, indicating that eclogite facies metamorphism peaked at 120–110 Ma. These new data are consistent with both the Iratsu eclogite body and surrounding highest‐grade Sanbagawa schists undergoing coeval subduction‐zone metamorphism, and subsequent re‐equilibration under epidote amphibolite facies conditions during exhumation. 相似文献
9.
10.
A Late Cretaceous mammalian dentary from the Ashizawa Formation (Futaba Group), Fukushima,northeastern Japan 下载免费PDF全文
A mammalian dentary discovered in the Coniacian Ashizawa Formation (Fukushima, northeastern Japan) is described. The specimen is a fragment of the horizontal ramus of a left edentulous dentary with five alveoli, the distal four of which are plugged with broken roots. Based on the morphologies of the dentary and the roots, it is considered to be of a therian mammal. This constitutes the first discovery of a Mesozoic mammal in northeastern Japan and highlights the potential for future mammal discoveries in the Cretaceous System in northeastern Japan, which will be significant for disclosure of the mammalian faunal evolution in East Asia during the Late Cretaceous. 相似文献