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FOREST C.GARNER MARTIN A.STAPANIAN KIRK E.FITZGERALD Lockheed Engineering Sciences Co. E.Flamingo R Las Vegas NV U.S.A. 《地理学报(英文版)》1991,(3)
Multivariate outliers in environmental data sets are often caused by atypical measurement error in a singlevariable.From a quality assurance perspective it is important to identify these variables efficiently so thatcorrective actions may be performed.We demonstrate a procedure for using two multivariate tests toidentify which variable‘caused’each outlier.The procedure is tested with simulated data sets that havethe same correlation structure as selected water chemistry variables from a survey of lakes in the WesternUnited States.The success rates are evaluated for three of the variables for sample sizes of 50 and 100,significance levels of 0.01 and 0.05 and various amounts of mean shift.The procedure works best forhighly correlated variables. 相似文献
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A 1.2 m snow pit was recovered on July 29th, 2009 from the Bogda Glacier, eastern Tianshan (天山). The sample site temperature of -9.6 ℃ indicates that the unique glaciochemical re-cord was well preserved and suitable for the reconstruction of air pollution levels in this previously un-explored region. Samples were analyzed for major ions (Na+, K+, Ca2+, Mg2+, NH4+, Cl-, SO42-, NO3-, HCOO-, and CH3COO-). NO3- and SO42- were characterized by significant high levels of pollution con-centration. Most air masses ... 相似文献
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V.L. Tauson D.N. Babkin V.V. Akimov S.V. Lipko N.V. Smagunov I.Yu. Parkhomenko 《Russian Geology and Geophysics》2013,54(5):526-543
The three-mode distribution of trace-element (TE) concentrations is observed in accordance with three main forms of TE occurrence in mineral: structural, surficial, and phase (native TE phases). Minerals of hydrothermally synthesized pyrite–pyrrhotite–magnetite–greenockite assemblage in the presence of Au and Mn are studied. Discrimination of modes is made, using the method of statistical sample of analytical data for single crystals (SSADSC), which is based on the postulate that individual crystals can contain predominantly one of possible forms. This is supported by study of Cd modes of occurrence by element thermorelease atomic-absorption spectrometry. X-ray photoelectron spectroscopy and atomic-force microscopy were used to examine the surficial TE forms. It has been confirmed that the dependence of the TE content on the crystal size in the sample is mainly due to surficial nonautonomous phases absorbing TEs. The effect of correspondence of chemical-component forms on the surfaces of coexisting minerals is also corroborated. This phenomenon is not related to the mutual contamination of phases but is due to the induction of the corresponding states of chemical forms in coexisting nonautonomous phases. It is possible to obtain true coefficients of interface distribution, characterizing structural TE impurities. These coefficients differ strongly from apparent distribution coefficients calculated from the bulk contents of impurities, except for Mn in pyrrhotite and magnetite, where its structural mode is predominant. The results obtained show that TEs can be used as quantitative geochemical indicators, which help to obtain correct information about the parameters of mineral formation and TE contents in the fluid phase. 相似文献
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V. L. Tauson D. N. Babkin T. M. Pastushkova N. V. Smagunov S. V. Lipko I. Yu. Voronova V. I. Men’shikov N. V. Bryanskii K. Yu. Arsent’ev 《Geochemistry International》2016,54(2):149-166
Distribution coefficients D of Au and Pd between magnetite (manganmagnetite) and ammonium chloride hydrothermal solution and the structural Dstr and surface-related Dsur terms of these coefficients were determined at 450 and 500°С and a pressure of 1 kbar using internal sampling techniques. Quantitative data on the speciation of precious metals are obtained using the technique of statistical selections of analytical data on single crystals SSADSC and compared with LA-ICP-MS data. Both Pd and Au are elements compatible with magnetite and its manganoan variety: Dstr is ≈3 for Pd and ≈1 for Au, although Au seems to weakly enrich fluid at 500°C: Dstr ≈ 0.5–0.8. The trends of postmagmatic Pd and Au fractionation can thus strongly depend on the presence of spinel-group minerals, first of all, magnetite and its solid solutions. The dualistic nature of the distribution coefficients provides sound grounds to believe that both elements are highly compatible, with regard not only for the structural but also for the surface-related modes of their occurrence (Dsur ≈ 17 and ≈50–70 for Au and Pd, respectively). The maximum concentrations of structural modes of the elements are 5.3 ppm for Au and 5.1 ppm for Pd and were found in the solid solution whose jacobsite mole fractions were 0.82 and 0.49, respectively. The principal distribution patterns of the elements in crystals are confirmed by LA-ICP-MS data. Data on this system testify that the distribution coefficients of minor and trace elements are geochemically dualistic because of the abnormal absorption properties of nanometer-sized nonautonomous phases on the surface of ore minerals, and this dualism plays an important geochemical role. 相似文献
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V.L. Tauson S.V. Lipko N.V. Smagunov R.G. Kravtsova K.Yu. Arsent’ev 《Russian Geology and Geophysics》2018,59(12):1718-1732
The interfacial crystal layer of poorly soluble mineral grown under hydrothermal conditions is modified chemically into a surficial nonautonomous phase (SNAP) and, in this capacity, takes part in growth process, doing several important functions. This paper considers some of them related to geochemistry and mineralogy. The new interpretation is given to the following phenomena: (1) selection of components during crystal growth in multiphase associations; (2) stability of multiphase parageneses having a common chemical component; (3) dual character of the distribution coefficients due to different properties of the crystal volume and SNAP; (4) formation of nano- and microinclusions of unusual composition different from the basic mineral phase; (5) spatial ordering of nano- and microparticles during their directed aggregation at the growing crystal face; (6) accumulation of valuable components (primarily noble metals), incompatible in most of mineral matrixes, in the surficial layer; and (7) effect of “hidden” metal content, associated with the presence of noble metals in the SNAP or of nano- and microinclusions formed during the SNAP evolution. 相似文献
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E.A.YFANTIS Computer Science Department University of Neva Las Vegas NV U.S.A.G.T.FLATMAN U.S.Environmental Protection Agency E.Harmon Las Vegas NV U.S.A. 《地理学报(英文版)》1991,(3)
In many environmental applications,such as exposure assessment and risk modelling,the desiredestimate is a random variable computed as the product of three independently distributed randomvariables.These variables may not necessarily have the same mean and variance.The method for findingthe 100(1-α)% confidence interval for the mean of the product random variable has been proposed bysome practitioners as the product of the 100(1-α)% confidence interval of the three means.In this paperwe show that the distribution of the product of three independent normal random variables is not normal.We find the mean and variance of the product distribution.Further,we show that although the meanof the product is equal to the product of the means,the product of the three confidence intervals is nota good approximation of the confidence intervals for the mean of the product variable.The confidenceinterval of the mean of the product variable may be estimated by computer simulation.An algorithmfor estimating the confidence interval for the mean of the product random variable is given.The programimplementing this algorithm is given as an appendix. 相似文献
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V. L. Tauson S. V. Lipko K. Yu. Arsent’ev Yu. L. Mikhlin D. N. Babkin N. V. Smagunov T. M. Pastushkova I. Yu. Voronova O. Yu. Belozerova 《Geochemistry International》2017,55(9):753-774
The FeS2–Ag–Pt–As system was studied using hydrothermal thermogradient synthesis (with internal sampling) of pyrite crystals at a temperature of 500°C and pressure of 1 kbar in ammonium chloridebased solutions. The modes of occurrence of precious metals (PM) were determined using atomic absorption spectrometry (AAS) in its version of statistical selections of analytical data on single crystals (SSADSC), electron microprobe analysis (EMPA), scanning electron microscopy with energy-dispersive spectrometry (SEM-EDS), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS). The concentration of Pt in its structural mode in pyrite is as high as 10–11 ppm and is practically not correlated with the As concentration. The dualistic distribution coefficient of Pt between pyrite and hydrothermal solution is 21 ± 7 for the structural mode and 210 ± 80 for the surface-related mode of this element. No inclusions of either any Pt-bearing minerals or Pt itself was detected. Platinum is an element highly compatible with hydrothermal pyrite and is different in this sense from gold, and pyrite is underestimated as a potential concentrator of platinumgroup elements (PGE). The distribution of Ag in pyrite is highly heterogeneous. The likely reason for this is that the Ag solid solution cannot be quenched, and hence, the Ag concentrations broadly vary and are very unsystematically distributed in natural pyrite crystals. Assuming this hypothesis, the limit for Ag accommodation in FeS2 can be estimated using SSADSC at 0.09 ± 0.06 wt % under the experimental parameters, and the distribution coefficient of the structural Ag mode is thereby evaluated at 1400 ± 700. When crystallizing together with FeS2 proustite (Ag3AsS3) near its melting point, forms mixtures with dervillite (Ag2AsS2), in which Ag deficit is counterbalanced by excess divalent As. The limit of As incorporation into pyrite under these conditions is ≤0.1 wt %. SEM-EDS and XPS data indicate that the surface phases are of three types. In the course of crystal growth, practically two-dimensional nonautonomous phases (NP) are aggregated into submicroscopic and micrometer-sized crystalline bodies (mesocrystals) that largely inherit their unusual minor-element composition from NP and are enriched in Ag, Pt, As, and other minor elements. NP and mesocrystals are enriched in Al, which was transferred into them from the Al-bearing Ti alloy of the reaction containers. Silver occur in the volume of the crystals and on their surface as monovalent silver sulfide. Arsenic was detected mostly in the form of di- and trivalent arsenic sulfides. Pentavalent arsenic oxide was identified only on the surface of the crystals and can be easily eliminated by ion milling. 相似文献
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