Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

The monopole moment of the three-point correlation function of the two-degree Field Galaxy Redshift Survey     

Jun Pan  István Szapudi 《Monthly notices of the Royal Astronomical Society》2005,362(4):1363-1370

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一次西南低涡过程的地面场中尺度分析     

曾俊  卢敬华  潘鄂芬 《成都信息工程学院学报》1990,(Z1)

本文运用带通滤波分析方法,对四川省1981年7月由西南低涡等天气系统引起的大暴雨过程作了地面气象要素场的中尺度诊断分析。结果表明,带通滤波后的场具有明显的中尺度特征,其中一些物理量场的适当配置与6小时后的暴雨中心有较好的对应关系。说明了此带通滤波方法在实际业务预报中具有一定的使用价值。  相似文献   

北部湾北部海上油田发现历程     

钟铿  潘其云 《南方国土资源》1997,(2)

北部湾北部海上油田的开发工作始于５０年代，６０～７０年代作了大量地质工作。改革开放后，油气勘查取得突破性进展。累计发现油气构造６个，含油面积超过４０ｋｍ２，石油地质储量约４亿ｔ，已开发油田２个，揭开我国南方油气资源开发序幕  相似文献   

γ射线暴的研究进展（Ⅳ：特强γ射线暴和软γ重复暴   总被引：2，自引：0，他引：2  

陆建隆  潘善龙  陆埮 《天文学进展》1996,14(4):302-314

最近CGRO上的仪器观测到了两个迄今为止发现的最强的λ暴GB930131和GB940217,其光子最高能量均达GeV量级;GB930131的峰值计数率达2×10~6个光子s~(-1);而GB940217的持续时间竟长达90min。另外沉寂了多年的软重复暴源SGR1900 14和SGR1806-20的再次爆发也由BATSE发现。一系列的观测还发现这些软重复暴均与X射线源对应且与超新星遗迹成协。文中对特强暴和软重暴(SGR)的性质及研究进展作了较为详细的评述。  相似文献   

Conditional cumulants in a weakly non-linear regime     

Jun Pan †  István Szapudi 《Monthly notices of the Royal Astronomical Society》2005,361(1):357-361

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CHARACTERIZATION OF LACTATE DEHYDROGENASE ISOZYME PATTERN AND MORPHOLOGY OF THREE MARINE FISH CELL LINES     

郭华荣  张士璀  李红岩  童裳亮  相建海 《中国海洋湖沼学报》2002,20(3):226-231

Three continuous marine fish cell lines of FG (i. e., Hounder Gill) from flounder (Paralichthys olivaceus) gill, SPH (i. e. , Sea Perch Heart) from sea perch (Lateolabrax japonicus) heart and RSBF (i.e., Red Sea Bream Fin) from red sea bream (Pagrosomus major) fin, were characterized by lactate dehydrogenase (LDH) isozyme and morphological analysis. The LDH isozyme patterns of these three cell lines and their corresponding tissues of origin were investigated and compared. The results showed: (1) No difference was found in the LDH isozyme patterns of FG and flounder gill tissue. However, the LDH isozyme patterns of SPH and RSBF were significantly different from their corresponding tissues of origin; (2) LDH isozyme patterns of FG, SPH and RSBF were markedly different from each other and could serve as genetic markers for species identification and detection of cross contamination. Morphological change analysis of these three cell lines in comparison to their original tissues indicated that FG cells still appeared epithelioid without morphological transformation. However, morphological changes were found in SPH and RSBF compared to their original tissues. Therefore, the cellular morphology was still plastic in the relatively stable culture conditions, and it was possible that change of LDH patterns wasrelated to morphological changes of fish cells in vitro.  相似文献   

Theory of stability, and regulation and control of ecological system in oasis   总被引：1，自引：0，他引：1  

Pan Xiaoling  Chao Jiping 《Global and Planetary Change》2003,37(3-4):287

Starting with analysis on the evolving course of oasis and the characteristics and evolution of transitional zone between oasis and desert, in consideration of ecological elements including plant stomata resistance, area covered by vegetation, and physical elements including albedo of vegetation and bare soil, atmosphere temperature, and humidity, under the condition of the balance among net radiation flux, latent heat flux, and sensible heat flux, the following are calculated: temperatures of vegetation and bare soil in different conditions, as well as the evapotranspiration rate of ecosystem. Analysis on evapotranspiration rate indicates that it depends on both the climate of environment and the physiological and ecological conditions of plants. On certain conditions, the evapotranspiration rate of transitional zone between oasis and desert (i.e. area covered by vegetation less than 20%), in some parameter domains, appears in bifurcation or multiequilibrium state. Meanwhile, in such area, ecosystem is extremely unstable. Any minor change to the balance will cause either increase or reduction of area covered by vegetation in ecosystem, on the basis of discussion on the emergency of these phenomena. This paper is attempting to propose an effective way of destruction and rebuilt ecosystem in transitional zone. The way is to control the evaporation of plant through selecting anti-drought country plant with big stomata resistance, and modify the roughness of the underlying surface in ecosystem by establishing rational interspace structure of plant community, so as to put the degenerative ecosystem into the natural succession track. This primary theory is being verified through observation and analysis on historical data.  相似文献   

射电源0420—014,1334—127和2345—167中的视超光速运动     

沈志强  万同山  洪晓瑜 《中国天文和天体物理学报》1997,(1)

本文叙述南天区 5GHzVLBI普查中新发现的视超光速射电源 ,0 4 2 0— 0 1 4,1 334—1 2 7和 2 345— 1 67,这些结果尚待进一步的观测加以证实  相似文献   

    

Guocheng Pan  D. P. Harris 《Mathematical Geology》1991,23(6):861-886

A new multidimensional scaling (MS) technique, referred to as the Pijk model, is formulated on the basis of associations among triple objects (samples or variables), instead of pairs of objects as used in the usual MS methods, such as factor analysis. The computational scheme provided for this method is the reduction of an original problem to a standard eigenvalue-eigenvector problem. The major goal of the technique is simplification and reduction of data structures and the rescaling of original objects into a new and reduced space, so that patterns and relations of the original objects can be conventiently examined in two-dimensional factor plots. The Pïjk method is illustrated and tested by using a set of geochemical data related to the epithermal gold and silver vein deposits in the Walker Lake quadrangle of Nevada and California. The characteristics of element associations suggested in the Pijk analysis are consistent with field observations. A preliminary comparison between the new method and the ordinary factor analysis also is made on the basis of the same data set. Results are encouraging in that analysis by the Pijk model captures triple-object associations that might be missed by the ordinary factor analysis which considers only pair-variable correlations  相似文献