Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

南水北调中线初期引汉工程经济效益初探     

屈焕英 《地理研究》1985,4(3):89-95

南水北调是补充华北地区新水源的有效途径之一。“中线”初期引汉工程是从长江支流汉江调水,渠线跨越汉江、淮河、黄河、海河四大水系,直达北京市。引汉水源是丹江口水库。该库集流面积95200平方公里,多年平均年径流量380亿立米,已建成初期规模。坝顶高程162米,正常蓄水位157米,总库容174.5亿立米。  相似文献   

On the Line Formation in Stellar Magnetized Atmospheres     

Zhong-Quan Qu  Xiao-Yu Zhang  Zhi Xu 《中国天文和天体物理学报》2001,1(2):161-175

1 INTRODUCTIONIn the previous paper (on et al. 1999, hereafter Paper I), we investigated the wavelength-dependence of four colltribution functions (CFs) derived from dmerent formal solutions andreferring to different emergellt quantities in the unpolarized case. Because one cannot generallyassign a single formation region to the whole line band in a real stellar atmosphere, e.g., the solaratmosphere, instead, the line formation region can be defined as the layers deviating farthestfrom t…  相似文献   

Paleoproterozoic Extensional Structure and Its Controlling on Mineralization in the East of Liaoning Province     

Yang Zhongzhu  Chen Shuliang  Li Xiandong  Wang Zhongjiang  Qu Hongxiang  Gang Jiang 《东北亚地学研究》2001,(1)

IntroductionThe area of eastern Liaoning is an importantmetal and nonmetal metallogenetic district in China,and the Liaohe group is one of the most importantstrata that hosts Pb, Zn, Au, B and Mg etcstratabound deposits. Up to now many geo1ogistssuch as Z…  相似文献   

抗差估计的初值选择     

王振杰  欧吉坤  曲国庆 《大地测量与地球动力学》2001,21(3):32-35

对L1 范估计的平差值和LS估计的平差值作为抗差估计的初值进行了比较 ,指出在 ρ函数是严凸函数时 ,二者无明显的区别。因为LS估计简单且易于计算 ,因此建议用LS估计的平差值作为抗差估计的初值。  相似文献   

CHARACTERIZATION OF LACTATE DEHYDROGENASE ISOZYME PATTERN AND MORPHOLOGY OF THREE MARINE FISH CELL LINES     

郭华荣  张士璀  李红岩  童裳亮  相建海 《中国海洋湖沼学报》2002,20(3):226-231

Three continuous marine fish cell lines of FG (i. e., Hounder Gill) from flounder (Paralichthys olivaceus) gill, SPH (i. e. , Sea Perch Heart) from sea perch (Lateolabrax japonicus) heart and RSBF (i.e., Red Sea Bream Fin) from red sea bream (Pagrosomus major) fin, were characterized by lactate dehydrogenase (LDH) isozyme and morphological analysis. The LDH isozyme patterns of these three cell lines and their corresponding tissues of origin were investigated and compared. The results showed: (1) No difference was found in the LDH isozyme patterns of FG and flounder gill tissue. However, the LDH isozyme patterns of SPH and RSBF were significantly different from their corresponding tissues of origin; (2) LDH isozyme patterns of FG, SPH and RSBF were markedly different from each other and could serve as genetic markers for species identification and detection of cross contamination. Morphological change analysis of these three cell lines in comparison to their original tissues indicated that FG cells still appeared epithelioid without morphological transformation. However, morphological changes were found in SPH and RSBF compared to their original tissues. Therefore, the cellular morphology was still plastic in the relatively stable culture conditions, and it was possible that change of LDH patterns wasrelated to morphological changes of fish cells in vitro.  相似文献   

射电源0420—014,1334—127和2345—167中的视超光速运动     

沈志强  万同山  洪晓瑜 《中国天文和天体物理学报》1997,(1)

本文叙述南天区 5GHzVLBI普查中新发现的视超光速射电源 ,0 4 2 0— 0 1 4,1 334—1 2 7和 2 345— 1 67,这些结果尚待进一步的观测加以证实  相似文献   

On the influence of magnetic fields on level populations     

Z. Q. Qu  C. L. Xu  X. Y. Zhang  X. L. Yan  C. L. Jin 《Monthly notices of the Royal Astronomical Society》2006,370(4):1790-1796

The influence of magnetic fields on the energy level populations of atoms is firstly studied by analysing the Stokes profiles of Fe  i 6302.5 forming in the solar magnetized atmosphere, with the aid of a departure factor defined to evaluate the deviation from the normal Boltzmann distribution without a magnetic field. This factor is directly related to the ratio of line-source function to the continuum one. The relationship between the departure and the magnetic field reveals an effect that the magnetic field induces an exponential increase in the level population of the lower level of Fe  i 6302.5 (Landé factor   g = 2.5  ) with the field strength. This indicates that the magnetic field can cause the redistribution of populations of those levels whose Landé factors are non-zero. Therefore, this effect should be included in the calculation of the statistical equilibrium. Secondly, an experiment utilizing the Hg5461 line in the laboratory on the Earth is carried out to reveal that the exponential relation is independent of variations in temperature, and the excitation is completely magneto-induced. Finally, the exponential relation is explained by taking account of the magnetic energy in the Boltzmann distribution.  相似文献   

Direct generation of solar and stellar radio bursts by energetic electron maser     

P. Louarn  D. Le Quéau  A. Roux 《Solar physics》1987,111(1):201-206

A fully relativistic electron maser is proposed for the explanation of certain non-thermal solar and stellar radio bursts. This mechanism (maser synchrotron) is based on a gyroresonant interaction between waves and electrons of high energies and uses the free energy contained in an electronic distribution function that peaks for energies around 1 MeV.By a calculation of the growth rates of the three electromagnetic modes, we show that the X-mode prevails for values of _p/ _cup to 2 or 3. This result is very different from the standard cyclotron maser case where such values of _p/ _clead to quench the X-mode growth. Hence, the synchrotron maser instability appears to be a direct and efficient amplification process for considerably larger physical conditions than the cyclotron maser. In addition, the radiation, emitted over the second gyroharmonic, freely propagates without a strong reabsorbtion at the 2 _clayer. All these points can constitute major advantages of this mechanism in an astrophysical context.Proceedings of the Second CESRA Workshop on Particle Acceleration and Trapping in Solar Flares, held at Aubigny-sur-Nère (France), 23–26 June, 1986.  相似文献   

Tetraploid induced by physical and chemical methods in Jinjiang oyster(Crassostrea rivularis)   总被引：1，自引：0，他引：1  

Rong Shoubai  Shi Shumei  Mo Qirong  Liu Shaeqiong  Liang Ze  Zhao Xiuzhu  Tong Wangdong  Li Shouwu  Li Yimin 《海洋学报(英文版)》1994,13(2):275-283

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