Elimination of Interferences in the Determination of Palladium,Platinum and Rhodium Mass Fractions in Moss Samples using ICP‐MS/MS          下载免费PDF全文

Terhi Suoranta  Syed N. H. Bokhari  Thomas Meisel  Matti Niemelä  Paavo Perämäki 《Geostandards and Geoanalytical Research》2016,40(4):559-569

Moss samples (Pleurozium schreberi) exposed to traffic‐related emission of Pd, Pt and Rh were analysed in this study. Successful elimination of interferences was achieved in the determination of Pd, Pt and Rh mass fractions in these samples using inductively coupled plasma‐tandem mass spectrometry (ICP‐MS/MS). Based on the results, a reliable determination of Pd, Pt and Rh mass fractions in microwave‐digested moss samples was obtained using ammonia (10% NH₃ in He) in the collision/reaction cell when ¹⁰³Rh was measured either on‐mass (103→103) or with mass‐shift (103→171) and mass‐shifts for ¹⁰⁸Pd (108→159) and ¹⁹⁵Pt (195→229) were used. The ICP‐MS/MS procedure was validated using BCR‐723 (road dust) as a reference material. In addition, a good agreement between the ICP‐MS/MS results and the results obtained with cloud point extraction and quadrupole ICP‐MS was observed for the moss samples.  相似文献   

Resource use conflicts in Mabini and Tingloy,the Philippines     

Terhi Majanen 《Marine Policy》2007

This paper presents the results of an analysis of resource use conflicts in areas near marine protected areas in Mabini–Tingloy, the Philippines. The author found large differences between groups of stakeholders in terms of perceived benefits and costs of conservation and tourism, and these inequalities have led to conflicts between various stakeholder groups. Marked by unequal power relationships, the conflicts place subsistence fishers as the weakest stakeholders. Fishers also have the lowest rates of knowledge of and participation in conservation activities. The study concludes that in order for conservation programs to be effectively transitioned onto the social and legal fabric of Mabini–Tingloy, resource use conflicts need immediate attention.  相似文献   

Regional effects of climate change on reindeer: a case study of the Muotkatunturi region in Finnish Lapland   总被引：2，自引：0，他引：2  

Susan E. Lee  Malcolm C. Press  John A. Lee  Tim Ingold  Terhi Kurttila 《Polar research》2000,19(1):99-105

Few studies have investigated current climate changes for high latitude regions, and the impact of such changes on reindeer and indigenous people. Previous work by other authors has identified snow and ice conditions in winter as being critical in determining the availability of forage for reindeer. Deep snow makes it difficult to access food. Lack of food weakens the herd and can reduce the allocation of nutrients to the development of the foetus in the female deer. Climate data for Lapland, northern Finland, and Karasjok, northern Norway, are examined, together with reindeer calf numbers for the period 1977 to 1994 for the Muotkatunturi region (68°N 25°30'E). Between 1883 and 1993, precipitation increased but temperatures showed no clear warming or cooling trend. However, since the late 1980s, temperatures have increased. A regression analysis on the climate and reindeer data found that the warmer the winter prior to the rut, the fewer the live calves recorded the following year (r = 0.529, p < 0.05). Also, the wetter the winter prior to the rut, the fewer the calves recorded (r = 0.427, p < 0.10). In contrast, the warmer the autumn prior to their birth, the greater the number of calves recorded (r = 0.474, p < 0.10). These results suggest that as climate changes and winters become warmer and wetter with increased snowfall, calf numbers will decline. These findings have important implications for the Saami people who are heavily dependent on the reindeer for their livelihood.  相似文献