Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

平阳矾山明矾石矿床岩石学特征及其成因浅析     

王福生  兰翔  梁祥济 《浙江国土资源》1997,(1)

在野外地质工作的基础上，通过对浙江平阳研山明矾石矿床的岩石学及地球化学特征进行认真的研究，进一步证实了矾山明矾山矿床是酸性火山气热液与中酸性火山碎屑岩内的碱性长石的交代中形成的。为了解释矿床的均一性，成矿的周期性和矿床单向依变分带等重要特征，我们重点研究了矿床中明矾石化和叶蜡石化的热力学性质，得出了K 活度和pH值是控制交代产物的重要因素的新结论，提出了该矿床交代成矿作用的新模型，并据此成功地解释了矿床的一些重要特征。  相似文献   

滇西北和邻区均衡重力异常特征及其壳内构造     

袁果田  项爱民 《大地测量与地球动力学》1992,(2)

本文以爱黎-海斯卡宁均衡补偿假设模式为基础,利用圆模板编制了滇西北及邻区均衡重力异常图。分析了异常的基本特征与壳内构造的关系,并初步探讨了均衡重力异常和强震活动的相关性。  相似文献   

重力插值方法研究     

向文 《大地测量与地球动力学》1997,(2)

为了根据离散观测数据构制连续空间重力变化图像，分析和讨论了３种数值插值方法，计算结果表明多面函数方法插值精度最高。由于逐步回归分析筛选核函数中心点的计算繁琐，文中提出根据分形理论和Ｓｈａｎｎｏｎ取样定理来确定核函数中心点。对滇西试验场进行模拟试算，插值精度可达到４～５（１０－８ｍｓ－２）。  相似文献   

Profiles of spectral lines of an accretion ring around a Kerr black hole     

J. L. Zhang  S. P. Xiang  J. F. Lu 《Astrophysics and Space Science》1985,113(1):181-187

Profiles of spectral lines emitted from an accretion ring around an object with strong gravitational field should be affected by Doppler shift, gravitational redshift, and deflection of light. Taking these effects into account, precise line profile of a Keplerian ring around a Kerr black hole for a distant observer is obtained by solving the kinetic equation of photons.  相似文献   

VPN技术在浙江省气象网络中的应用   总被引：2，自引：0，他引：2  

吴孟春  马奇蔚  周必高  周捷  周翔 《成都信息工程学院学报》2006,21(4):551-554

随着浙江省气象业务的不断发展，网络数据交换日益增多，同时更多基于网络的气象业务的增加，如网络视频会商、自动站数据传输等，使目前浙江省气象系统专线网络运行已达到极限，所以需要建立VPN网以对现有的网络作链路上的备份，而VPN的建立同时还可以实现移动办公，领导能在远程调用内网的资料进行远程决策服务和汇报工作。主要介绍VPN技术并叙述VPN技术在浙江省气象系统网络中的具体应用。  相似文献   

MERLIN Images of Five Compact Symmetric Object Candidates at 1.6 GHz     

Hai－YanZhang  XiangLiu 《中国天文和天体物理学报》2001,1(2):129-132

1 INTRODUCTIONCompact Symmetric Objects (CSOs) are powerful and compact sources (overall size <1 bpc) with lobe emission on both sides of the central engine. The small size of these sourcesis almost certainly to be attributed to the youth of the sources themselves (ages < 104 yr) andnot due to a dense coallning medium (Readhead 1996). The unification scenario assumes thatCSOs evolve into compact steep spectrum (CSS) sotirces and then into Fanaroff-Riley type 11objects (Fanti 1995). …  相似文献   

广西河池地区矿产资源勘查成果展销会情况介绍     

项开文 《南方国土资源》1996,(3)

１９９５年７月１１日—１２日，广西地矿厅和河池地区行署首次联合举办矿产资源勘查成果展销会，会址设在河池市，与会代表１３０余人。展销会提交大会展销的矿产资源勘查成果３８项，引资勘查项目３８项。经买卖双方三天的洽谈，涉及到的项目２５项，会议期间签订矿产资源勘查成果合同协议４项，愈千万元，取得较好的社会经济效益。为地勘资金多渠道来源开辟了新路子，对促进地勘单位地质找矿工作及勘查成果有偿使用发挥了重要作用  相似文献   

CHARACTERIZATION OF LACTATE DEHYDROGENASE ISOZYME PATTERN AND MORPHOLOGY OF THREE MARINE FISH CELL LINES     

郭华荣  张士璀  李红岩  童裳亮  相建海 《中国海洋湖沼学报》2002,20(3):226-231

Three continuous marine fish cell lines of FG (i. e., Hounder Gill) from flounder (Paralichthys olivaceus) gill, SPH (i. e. , Sea Perch Heart) from sea perch (Lateolabrax japonicus) heart and RSBF (i.e., Red Sea Bream Fin) from red sea bream (Pagrosomus major) fin, were characterized by lactate dehydrogenase (LDH) isozyme and morphological analysis. The LDH isozyme patterns of these three cell lines and their corresponding tissues of origin were investigated and compared. The results showed: (1) No difference was found in the LDH isozyme patterns of FG and flounder gill tissue. However, the LDH isozyme patterns of SPH and RSBF were significantly different from their corresponding tissues of origin; (2) LDH isozyme patterns of FG, SPH and RSBF were markedly different from each other and could serve as genetic markers for species identification and detection of cross contamination. Morphological change analysis of these three cell lines in comparison to their original tissues indicated that FG cells still appeared epithelioid without morphological transformation. However, morphological changes were found in SPH and RSBF compared to their original tissues. Therefore, the cellular morphology was still plastic in the relatively stable culture conditions, and it was possible that change of LDH patterns wasrelated to morphological changes of fish cells in vitro.  相似文献   

Density perturbations in a Universe consisting of fluid plus collisionless neutrino gas     

Xiang Shouping 《Astrophysics and Space Science》1985,112(1):83-91

In a two-component Universe which consists of fluid (visible matter) plus collisinless massive neutrino gas (dark matter), the remarkable difference between the developed inhomogeneities in two components could be formed after the decoupling time. Whether the initial perturbation was in which of the two components, the inhomogeneities developed in visible matter are larger than that in neutrinos, especially on smaller scales. The necessary condition for such a situation to arise is only that the density of neutrinos in the Universe is dominant. That means the non-dominant visible component in the Universe is strongly clustered especially on smaller scales, while the distribution of the dominant dark matter (neutrinos) is fairly uniform.  相似文献