The bivalve Lembulus bicuspidatus may enhance denitrification in shelf sediment at the Angola–Benguela Frontal Zone     

A Neumann  A Flohr 《African Journal of Marine Science》2018,40(1):91-96

We collected living individuals of the bivalve Lembulus bicuspidatus, which shows an unusual preference for the oxygen-deficient habitat found at the Angola–Benguela Frontal Zone of the southeastern Atlantic. With a series of incubation experiments with ¹⁵N-labelled nitrate as a tracer in combination with membrane-inlet mass spectrometry, we studied the potential contribution of L. bicuspidatus to nitrate reduction in the upper sediment layer. Our preliminary results suggest that L. bicuspidatus enhances nitrate reduction if the oxygen concentration is sufficiently low. The Lembulus-mediated nitrate reduction rate is then similar to the rate of microbial nitrate reduction in the surrounding sediment.  相似文献   

Probing the (in)compatibilities of social theory and policy relevance in Piers Blaikie’s political ecology     

Roderick P. Neumann 《Geoforum》2008,39(2):728-735

One of Piers Blaikie’s most important contributions to the development of political ecology is his critique of land and resource conservation policy in the global South. In this paper I trace the development of Blaikie’s ideas about the policy relevance of political ecology, focusing particularly on the challenges posed by the introduction of poststructural social theory into the field. I begin by revisiting Blaikie’s earlier critiques of environment and development policy. This will provide the departure point to explore how his thinking on the relationship of theory and policy and of academic and development practices has evolved in subsequent writings. I have invented two personas, “early Blaikie” and “late Blaikie”, to facilitate this task. Second, I want to probe some of the challenges that late Blaikie presents for doing political ecology research, to some extent by pitting early Blaikie against late Blaikie and letting them hash it out. Third, I turn to my own and others’ research and consultation experiences as a way to examine the possibilities for reconciling theoretically driven critiques with policy relevant research.  相似文献   

Trace element diagenesis in pyrite-rich sediments of the Achterwasser lagoon, SW Baltic Sea     

Florian Scholz  Thomas Neumann 《Marine Chemistry》2007,107(4):516-532

The early diagenesis of trace elements (V, Cr, Co, Cu, Zn, As, Cd, Ba, U) in anoxic sediments of the Achterwasser, a shallow lagoon in the non-tidal Oder estuary in the Baltic Sea, was investigated in the context of pyrite formation. The dissolved major redox parameters show a two-tier distribution with transient signals in the occasionally re-suspended fluid mud layer (FM) and a permanently established diagenetic sequence in the sediment below. Intense microbial respiration leads to rapid depletion of O₂ within the uppermost mm of the FM. The reduction zones of Mn, Fe and sulfate overlap in the FM and in the permanently anoxic sediment section which appears to be a typical feature of estuarine sediments, under low-sulfate conditions. Degrees of pyritization (DOP) range from 50% in the FM to remarkably high values > 90% at 50 cm depth. Pyrite formation at the sediment surface is attributed to the reaction of Fe-monosulfides with intermediate sulfur species via the polysulfide pathway. By contrast, intense pyritization in the permanently anoxic sediment below is attributed to mineral growth via adsorption of aqueous Fe-sulfide complexes onto pyrite crystals which had originally formed in the surface layer.The studied trace elements show differential behavior patterns which are closely coupled to the diagenetic processes described above: (i) Zn, Cu and Cd are liberated from organic matter in the thin oxic layer of the sediment and diffuse both upwards across the sediment/water boundary and downwards to be trapped as monosulfides, (ii) V, Cr, Co and As are released during reductive dissolution of Mn- and Fe-oxyhydroxides, (iii) U removal from pore water occurs concomitantly to Fe reduction in the FM and is attributed to reduction of U(VI) to U(IV), (iv) the Ba distribution is controlled by reductive dissolution of authigenic barite in the sulfate reduction zone coupled with upward diffusion and re-precipitation. The incorporation of trace elements into pyrite is most intense for Co, Mn and As, intermediate for Cu and Cr and little to negligible for U, Zn, Cd, V and Ba. The observed trend is largely in agreement with previous studies and may be explained with differing rates for ligand exchange. Slow and fast ligand exchange and thus precipitation kinetics are also displayed by downcore increasing (Mn, Cr, Co and As) or constantly low (Zn, Cu, Cd) pore water concentrations. The downward increasing degrees of trace metal pyritization (DTMP) for Co, Cu, Zn and As are, in analogy to pyrite growth, assigned to adsorption of sulfide complexes or As oxyanions onto preexisting pyrite minerals.  相似文献   

Origin of iodine in volcanic fluids: I results from the Central American Volcanic Arc     

Glen T Snyder  Udo Fehn 《Geochimica et cosmochimica acta》2002,66(21):3827-3838

The largest reservoir of crustal iodine is found in marine sediments, where it is closely associated with organic material. This presence, together with the existence of a long-lived, cosmogenic radioisotope ¹²⁹I (t_1/2 = 15.7 Ma), make this isotopic system well suited for the study of sediment recycling in subduction zones. Reported here are the results of ¹²⁹I/I ratios in volcanic fluids, collected during a comprehensive study of fluids and gases in the Central American Volcanic Arc. ¹²⁹I/I ratios, together with I, Br, and Cl concentrations, were determined in 79 samples from four geothermal centers and a number of crater lakes, fumaroles, hot springs, and surface waters in Costa Rica, Nicaragua, and El Salvador. Geothermal and volcanic fluids were found to have iodine concentrations substantially higher than values in seawater or meteoric waters. ¹²⁹I/I ratios in most of the geothermal fluids are below the preanthropogenic input ratio of 1500 × 10⁻¹⁵, demonstrating that recent anthropogenic additions are largely absent from the volcanic systems. The majority of the ¹²⁹I/I ratios are between 500 and 800 × 10⁻¹⁵. These ratios indicate minimum iodine ages between 25 and 15 Ma, in good agreement with the age of subducted sediments in this region. In all four geothermal systems, however, a few samples were found with iodine ages older than 40 Ma—that is, considerably below the expected age range for subducted sediments from the Cocos Plate. These samples probably reflect the presence of iodine derived from sediments in older accreted oceanic terraines. The iodine ages indicate that the magmatic end member for the volcanic fluids originates in the deeper parts of the subducted sediment column, with small additions from older iodine mobilized from the overlying crust. The high concentrations of iodine in geothermal fluids, combined with the observed iodine ages, demonstrate that remobilization in the main volcanic zone (and probably also in the forearc area) is an important part in the overall marine cycle of iodine and similar elements.  相似文献   

Provenance analysis and tectonic setting of the Ordovician clastic deposits in the southern Puna Basin, NW Argentina   总被引：9，自引：0，他引：9  

Udo Zimmermann  Heinrich Bahlburg† 《Sedimentology》2003,50(6):1079-1104

Provenance studies on Early to Middle Ordovician clastic formations of the southern Puna basin in north-western Argentina indicate that the sedimentary detritus is generally composed of reworked crustal material. Tremadoc quartz-rich turbidites (Tolar Chico Formation, mean composition Q_t89 F7 L4) are followed by volcaniclastic rocks and greywackes (Tolillar Formation, mean Q_t33 F42 L25). These are in turn overlain by volcaniclastic deposits (mean Q_t24 F30 L46) of the Diablo Formation (late Arenig–early Llanvirn) that are intercalated by lava flows. All units were deformed in the Oclóyic Orogeny during the Middle and Late Ordovician. Sandstones of the Tolar Chico Formation are characterized by Th/Sc ratios > 1, La/Sc ratios ≈ 10, whereas associated fine-grained wackes show slightly lower values for both ratios. LREE (light rare earth elements) enrichment of the arenites is ≈ 50× chondrite, Eu/Eu* values are between 0·72 and 0·92, and flat HREE (heavy rare earth elements) patterns indicate a derivation from mostly felsic rocks of typical upper crustal composition. The ε_{Nd(t = sed)} values scatter around −11 to −9. The calculated Nd-T_DM residence ages vary between 1·8 and 2·0 Ga indicating contribution by a Palaeoproterozoic crustal component. The Th/Sc and La/Sc ratios of the Tolillar Formation are lower than those of the Tolar Chico Formation. Normalized REE (rare earth elements) patterns display a similar shape to PAAS (post-Archaean average Australian shale) but with higher abundances of HREEs. Eu/Eu* values range between 0·44 and 1·17, where the higher values reflect the abundance of plagioclase and feldspar-bearing volcanic lithoclasts. Average ε_{Nd(t = sed)} values are less negative at −5·1, and Nd-T_DM are lower at 1·6 Ga. This is consistent with characteristics of regional rocks of upper continental crust composition, which most probably represent the sources of the studied detritus. The rocks of the Diablo Formation have the lowest Th/Sc and La/Sc ratios, lower LREE abundances than the average continental crust and are slightly enriched in HREEs. Eu/Eu* values are between 0·63 and 1·17. The Nd isotopes (ε_{Nd(t = sed)} = −3 to −1; T_DM = 1·2 Ga) indicate that one source component was less fractionated than both the underlying Early Ordovician and the overlying Middle Ordovician units. Synsedimentary vulcanites in the Diablo Formation show the same isotopic composition. Our data indicate that the sedimentary detritus is generally composed of reworked crustal material, but that the Diablo Formation appears to contain ≈ 80% of a less fractionated component, derived from a contemporaneous continental volcanic arc. There are no data indicating an exotic detrital source or the accretion of an exotic block at this part of the Gondwana margin during the Ordovician.  相似文献   

Metal island growth and dynamics on molybdenite surfaces     

Udo Becker  Kevin M. Rosso  Michele Warren 《Geochimica et cosmochimica acta》2003,67(5):923-934

In order to understand the adsorption mechanism of metal atoms to semiconducting surfaces, we have studied, as a model system, the vapor phase adsorption of Ag, Au, and Cu on the (001) surface of molybdenite (MoS₂) and the subsequent surface diffusion of these adsorbates. Our scanning tunneling microscopy (STM) images show that, depending on the type of metal atom that is adsorbed, islands of a characteristic size (2 nm for Ag, 8 to 10 nm for Cu, two distinct sizes of 2 nm and 8 to 10 nm for Au), shape (well rounded in the lateral extension) and thickness (one monolayer for Ag, 1 to 1.5 nm for Cu) are formed during the initial stages of deposition. Whole islands are observed to surface diffuse without loss of size or shape. Despite the relatively large size of the copper islands on molybdenite, these islands surface diffuse extensively, suggesting that the Cu-S interaction is weak. Surface diffusion is only hindered once individual islands start to coalesce. As copper islands accumulate, the size and shape of the original islands can still be recognized, supporting the conclusion that these characteristics are constant and that monolayer growth occurs by the aggregation of islands across the surface.The strength and the nature of the Ag-S(MoS₂) bond were further investigated by using molecular orbital calculations, ultraviolet photoelectron spectroscopy (UPS) and scanning tunneling spectroscopy (STS). By applying quantum mechanical approaches using a two-dimensional periodic molybdenite slab and hexagonal MoS₂ clusters of different sizes with metal atoms adsorbed to them, it is possible to calculate the electron transfer between the mineral surface and the metal atom as well as the adsorption energy as a function of surface coverage. In addition, we used the results from the quantum mechanical runs to derive empirical potentials that model the characteristics of the forces within the crystal, within the adsorbed islands, and the metal and mineral surface. The combination of quantum mechanical calculations and empirical force field calculations explain the electronic structure and the highest stability of Ag islands that have seven atoms in diameter, which exactly agrees with the size of experimentally observed islands. UPS results also suggest that a specific new state is formed (approximately 4.5 eV into the valence band) which may describe the Ag-S bond because it does not occur in pure silver or molybdenite.This study shows how the combination of microscopic (STM), spectroscopic (STS, UPS), compositional (X-ray photoelectron spectroscopy, XPS) and molecular modeling (quantum mechanical and empirical) techniques is a useful approach to understand the nature of the metal to sulfide bond. Further insights may be gained concerning the natural association of certain metals with sulfides.  相似文献   

Observation of gravity waves in a boreal forest     

X. Lee  H.H. Neumann  G. Hartog  R.E. Mickle  J.D. Fuentes  T.A. Black  P.C. Yang  P.D. Blanken 《Boundary-Layer Meteorology》1997,84(3):383-398

In this paper we report the results of the analysis of two 60-min wave events that occurred in a boreal aspen forest during the 1994 BOREAS (Boreal Ecosystems-Atmosphere Study) field experiment. High frequency wind and temperature data were provided by three 3-D sonic anemometer/thermometers and fourteen fine-wire thermocouples positioned within and above the forest. Wave phase speeds, estimated from information revealed by spectral analysis and linear plane wave equations, are 2.2 and 1.3 m s^-1 for the two events. The wavelengths are 130 m and 65 m respectively and are much larger than the vertical wave displacements. There is strong evidence from the present analysis and from the literature supporting our postulate that these waves are generated by shear instability. We propose that wind shear near the top of the stand is often large enough to reduce the gradient Richardson number below the critical value of 0.25 and thus is able to trigger the instability. When external conditions are favorable, the instability will grow into waves.  相似文献   

High-resolution fluvial records of Holocene environmental changes in the Sahel: the Yamé River at Ounjougou (Mali,West Africa)     

L. Lespez  Y. Le Drezen  A. Garnier  M. Rasse  B. Eichhorn  S. Ozainne  A. Ballouche  K. Neumann  E. Huysecom 《Quaternary Science Reviews》2011,30(5-6):737-756

The Yamé river, in the Bandiagara Plateau, Dogon Country, Mali, is characterised by extensive alluvial sedimentary records, particularly in the 1 km long Ounjougou reach where Holocene floodplain pockets are inset in the Pleistocene formations. These alluvial records have been investigated via geomorphologic fieldwork and sedimentologic and micromorphologic analyses and are supported by 79 radiocarbon dates. The alluvial deposits of the valley floor correspond to a vertical accretion of 3–10 m. The reconstruction of fluvial style changes provides evidence of four main aggradation periods. From 11,500 to 8760 cal. BP, the alluvial architecture and grain-size parameters indicate a wandering river. This period included phases of pulsed high-energy floods and avulsion related to a northward shift of the summer monsoon to around 14°N after 11,500 cal. BP. From 7800 to 5300 cal. BP, a swampy floodplain environment with standing water pools within a Sudanian savanna/woodland mosaic corresponds to the culmination of the Holocene humid period. From 3800 cal. BP onwards, rhythmic sedimentation attests to an increase in the duration and/or intensity of the dry season, giving a precise date for the local termination of the Holocene Optimum period. During the last two millennia and for the first time during the Holocene, the alluvial formations are progressively restricted whereas the colluvial deposits increase, indicating strong soil erosion and redeposition within the watershed related to an increase in human impact. Four major periods are characterised by incision (I1: ante 11,500, I2: 8760–7800; I3: 6790–6500 cal. BP; I4; 2400–1700 cal. BP) pointing to dramatic changes in fluvial style. They result from high-energy flood flows during dry spells and confirm the capacity of the floodplain pocket in the upstream reach of the Sahelian belt to record rapid Holocene climatic change.  相似文献   

Natural fracking and the genesis of five-element veins     

Gregor Markl  Mathias Burisch  Udo Neumann 《Mineralium Deposita》2016,51(6):703-712

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Statistical analyses of Global U-Pb Database 2017     

Stephen J.Puetz  Carlos E.Ganade  Udo Zimmermann  Glenn Borchardt 《地学前缘(英文版)》2018,9(1):121-145

The method of obtaining zircon samples affects estimation of the global U-Pb age distribution.Researchers typically collect zircons via convenience sampling and cluster sampling.When using these techniques,weight adjustments proportional to the areas of the sampled regions improve upon unweighted estimates.Here,grid-area and modern sediment methods are used to weight the samples from a new database of 418,967 U-Pb ages.Preliminary tests involve two age models.Model-1 uses the most precise U-Pb ages as the best ages.Model-2 uses the~(206)Pb/~(238)U age as the best age if it is less than a1000 Ma cutoff,otherwise it uses the~(207)Pb/~(206)Pb age as the best age.A correlation analysis between the Model-1 and Model-2 ages indicates nearly identical distributions for both models.However,after applying acceptance criteria to include only the most precise analyses with minimal discordance,a histogram of the rejected samples shows excessive rejection of the Model-2 analyses around the1000 Ma cutoff point.Because of the excessive rejection rate for Model-2,we select Model-1 as the preferred model.After eliminating all rejected samples,the remaining analyses use only Model-1 ages for five rock-type subsets of the database:igneous,meta-igneous,sedimentary,meta-sedimentary,and modern sediments.Next,time-series plots,cross-correlation analyses,and spectral analyses determine the degree of alignment among the time-series and their periodicity.For all rock types,the U-Pb age distributions are similar for ages older than 500 Ma,but align poorly for ages younger than 500 Ma.The similarities(500 Ma)and differences(500 Ma)highlight how reductionism from a detailed database enhances understanding of time-dependent sequences,such as erosion,detrital transport mechanisms,lithification,and metamorphism.Time-series analyses and spectral analyses of the age distributions predominantly indicate a synchronous period-tripling sequence of~91-Myr,~273-Myr,and~819-Myr among the various rock types.  相似文献