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1.
The bulk composition of organic matter and saturated and aromatic hydrocarbons extracted from 16 samples collected from two Kuperschiefer profiles in the Rudna mine,Southwest Poland has been analyzed to study the role of organic matter during base metal enrichment in the Kupferschiefer shale.The results indicated that the extract yields and saturated hydrocarbon yields decreased with increasing base metal contents.GC and GC/MS analyses indicated that n -alkanes and alkylated aromatic compounds were depleted and may have served as hydrogen donators for thermochemical sulfate reduction.The enrichment of base metal is closely connected with the destruction of hydrocarbons. 相似文献
2.
孙玉壮 《中国地球化学学报》2004,23(2):101-111
Thirty-seven Kupferschiefer samples from southwestern Poland were analyzed by microscopy, Rock-Eval approach and instrumental neutron activation analysis to understand the geochemical and morphological characteristics of kerogen present in the samples. The analytical results indicate that there are two different types of kerogens. One type was only subjected to thermal alteration processes, and the other was further oxidized after deposition of the sediment.In the oxidized samples migrabitumen was transformed into pyrobitumen. Rock-Eval analyses show a significant decrease in HI values in the oxidized samples and an increase in OI values in relation to the samples that were not influenced by oxidation. Variations in S2 versus Corg contents indicate a change in kerogen from Type II to Type III with progressing oxidation. The presence of pyrobitumen and the depletion of hydrogen in the altered kerogen allow one to conclude that the kerogen was used as hydrogen donor for thermochemical sulfate reduction(TSR). 相似文献
3.
琥珀是由古代植物代谢产生的树脂聚合物形成的化石。琥珀中的有机质保存环境稳定、封闭,能很好地记载其形成时期的古植物和古环境等信息。本次研究运用气象色谱质谱联用仪（GC-MS）和元素分析稳定同位素质谱仪（EA-IRMS）等测试方法,研究了沈北煤田煤中琥珀的有机地球化学组成、稳定同位素和化合物单体碳同位素特征。结果表明,琥珀中的饱和烃以二萜化合物为主（占73.45%）,芳香烃以松香烷型化合物为主（56.17%）;高含量的贝壳杉烷、雪松烷、扁枝烷和松香烷型化合物指示琥珀来源于松柏类植物,且以柏科植物为主。沈北琥珀的δ13C值为-22.8‰ ~ -21.2‰,与同时期其他地区琥珀的δ13C值相似;氢同位素变化范围较小（-297.2‰ ~ -276.0‰）,氧同位素值为17.4‰ ~ 31.6‰。琥珀的稳定同位素组成（碳、氢和氧）进一步证明琥珀来源于裸子植物。琥珀的δ13C值主要与其形成时的全球气温变化和大气组成有关。沈北琥珀的氢和氧同位素组成主要受植物种类（松柏类）以及植物生长的局部气温和降水条件有关。琥珀稳定碳同位素有望成为研究古气候和古大气组成的良好载体,琥珀的氢和氧同位素可以反映形成时期的古环境条件,但仍需进一步深入研究。 相似文献
4.
河川是一个复杂的生态系统,河川主支干道即为系统中的主要动脉,各种物质循环、能量流动、物种讯息传输,均依赖河川水系为之.但因人类迁入活动及过度利用水资源,干扰了水的自然循环,土壤与微生物的自然演化,生物的迁徙与演替平衡等.且目前河川治理大多以取水、防洪为优先,忽略了景观生态原则在河川中的作用,致使城市与水环境关系日益疏离,物种的栖息地逐渐被破坏.本研究以台湾北部淡水河流域为例,探讨河川流域中之景观生态功能,并将景观生态原则纳入流域治理的综合目标之一,研拟可持续发展的策略. 相似文献
5.
Further Information of the Associated Li Deposits in the No.6 Coal Seam at Jungar Coalfield,Inner Mongolia,Northern China 总被引：2，自引：0，他引：2
SUN Yuzhuang ZHAO Cunliang LI Yanheng WANG Jinxi ZHANG Jiany JIN Zhe LIN Mingyue Wolfgang KALKREUTH 《《地质学报》英文版》2013,87(4):1097-1108
Total 138 coal samples and 14 parting samples were taken from the No. 6 Seam of the Jungar Coalfield, Inner Mongolia. These samples were analysed by optical microscopy, sequential chemical extraction procedure (SCEP), inductively coupled plasma mass spectrometry (ICP-MS), X-ray powder diffraction (XRD), and scanning electron microscope in conjunction with an energy-dispersive X-ray spectrometer (SEM-EDX) analysis. The results indicate that the Li contents have reached the industrial grade of the coal associated Li deposit, and the total Li reserves have reached 2406600 tons, that is, 5157000 tons Li2O in the No. 6 seam in the Jungar Coalfield. The sequential chemical extraction procedure results suggest that the Li concentration is mainly related to inorganic matter. The minerals in the coals consist of kaolinite, boehmite, chlorite-group mineral, quartz, calcite, pyrite, siderite and amorphous clay material. Some Li could be absorbed by clay minerals in the Li-bearing coal seam. The chlorite phase?could be?most likely the host for a part of Li. The Yinshan Oldland should be the most possible source of Li of the coal. 相似文献
6.
<正>In order to study the accumulation mechanism of"barkinite",eight Late Permian channel benches(approximately 15-cm across and 10-cm deep) were taken from the Jinshan Mine,Anhui Province,China.The samples were analyzed by microscopical and geochemical methods.The microscopical observations indicate that the occurrence modes of"barkinite"in this area are different from those in other areas of China.The ratios of structureless"barkinite"are much higher in the Jinshan Mine,probably due to the flow-water and marine influenced environments.Furthermore, vitrinite macerals also show a strong fluorescence.The vitrinite fluorescence characteristics have not been observed in the Permian"barkinite"coals from northern China.The composition and variation of minerals in the column section also showed that the swamps in the study area were seriously influenced by seawater in the early and late stage during the peat accumulation. 相似文献
7.
Geochemical Characteristics of a Veinlet Kupferschiefer Profile from the Lubin Mine, Southwestern Poland 总被引：3，自引：0，他引：3
Previous studies have shown that the ascending, oxidizing brines play a very important role in Kupferschiefer mineralization. Fractures could be the pathway of the brines. In order to clarify the influences of the brines on bulk organic matter, aromatic hydrocarbons and Kupferschiefer mineralization, one veinlet Kupferschiefer profile from the Lubin mine, southwestern Poland was studied with the microscopic, geochemical and Rock-Eval methods. The microscopic results indicate that organic matter of the veinlet sample consists dominantly of bitumen. Its extract content is higher than in other samples. The dominant aromatic compounds are naphthalene and alkylated naphthalenes (Na-PAH), which have migrated into the veinlet sample from other sediments. The content of phenanthrene and its methylated derivatives (Ph-PAH) is much lower than in other samples. The reason may be due to their heavier mass than Na-PAH. It is more difficult for Ph-PAH to migrate. The Na-PAH was probably removed from the shale by dist 相似文献
8.
Petrologic and geochemical characteristics of Seam 9-3 and Seam 2, Xingtai Coalfield, Northern China
Yuzhuang Sun W. Püttmann W. Kalkreuth B. Horsfield 《International Journal of Coal Geology》2002,49(4)
Six samples of Carboniferous (Mississippian–Pennsylvanian) coal (Seam 9-3) and 11 samples of Permian coal (Seam 2) from the Xingtai Coalfield were studied by petrological and organic geochemical methods. Both seams show different petrological and geochemical compositions. In Seam 9-3 of the Carboniferous age, the predominant maceral is vitrinite (83%) whereas in Seam 2 of Permian age, inertinite predominates (45%). “Barkinite” was found with an average content 1% only in Seam 2. Sixty-four different aromatic compounds were identified by gas chromatography (GC)/mass spectrometry (MS) analysis of solvent extracts (Extr) of both seams. Abundant polyaromatic sulfur hydrocarbons (PASH) were determined in coal samples from Seam 9-3, while they are very low in samples from Seam 2. 1,2,5-Trimethylnaphthalene and 1,2,5,6-tetramethylnaphthalene contents are much higher in Seam 2, while 2-methylfluorene contents are higher in Seam 9-3. Cadalene was found in Seam 2 with a high content of 94 mg/kg coal but was not detected in samples from Seam 9-3. This might indicate a different floral contribution to the sedimentary organic matter. All petrologic and geochemical results indicate that Seam 2 formed in a more oxidized environment compared with Seam 9-3. 相似文献
9.
SUN Yuzhuang Basin Reservoir Research Centre University of Petroleum Shuiku Ro Changping Beijing JIN Yujie China University of Mining Technology Beijing 《《地质学报》英文版》2000,74(1):93-101
Previous studies have shown that the oxidizing brines from the Early Permian Rotliegende sequence have influences on the organic matter of Kupferschiefer. However, inside the Rotliegende sequence there are two other black shales: the Lower and Upper Antracosia shales, which have not been studied as much in detail as in Kupferschiefer. In the present study 12 samples from the Lower and Upper Antracosia shales were analyzed by organic geochemical methods in order to clarify the influences of the oxidizing brines on organic matter. The results indicate that the organic matter of the samples from the Upper Antracosia shale and the bottom of the Lower Antracosia shale was oxidized under the influences of the oxidizing brines. The oxidation resulted in a depletion of saturated hydrocarbons and the alky Is of the aromatic compounds. 相似文献
10.
