Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Optical flashes and very early afterglows in wind environments     

X. F. Wu  Z. G. Dai  Y. F. Huang  T. Lu 《Monthly notices of the Royal Astronomical Society》2003,342(4):1131-1138

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Coronal change at the south-west limb observed by Yohkoh on 9 November 1991, and the subsequent interplanetary shock at Pioneer Venus Orbiter     

Shinichi Watari  Z. Smith  H. A. Garcia  T. Detman  M. Dryer 《Solar physics》1996,167(1-2):357-369

A spectacular change in the lower corona on the south-west limb has been found in solar images taken by the Yohkoh soft X-ray telescope. The event is characterized by a large topological change in magnetic field and a large intensity decrease observed after the X1. 1/1B flare on 9 November, 1991. A coronal mass ejection (CME) was observed by the Mark III K-coronameter (MK3) at the HAO/Mauna Loa Observatory. Both the MK3 (white-light) and soft X-ray observations showed that one leg of this CME was located above the flare site. An interplanetary shock associated with this event was observed by Pioneer Venus Orbiter, and, possibly, by IMP-8.Also Cooperative Institute for Research in the Environmental Sciences (CIRES), University of Colorado, Boulder, CO 80309, U.S.A.  相似文献   

Book reviews     

Howard  R. F.  van den Oord  G. H. J.  Švestka  Z. 《Solar physics》1996,169(1):225-227

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Population synthesis for symbiotic stars with white dwarf accretors     

Guoliang Lü  L. Yungelson  Z. Han 《Monthly notices of the Royal Astronomical Society》2006,372(3):1389-1406

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Single star scidar: atmospheric parameters profiling using the simulated annealing algorithm     

A. Habib  J. Vernin  Z. Benkhaldoun  H. Lanteri 《Monthly notices of the Royal Astronomical Society》2006,368(3):1456-1462

In this paper, we present a new method to estimate, for each turbulent layer labelled i , the horizontal wind speed   v ( h _i )  , the standard deviation of the horizontal wind speed fluctuations  σ _v ( h_i )  and the integrated value of   C ² _n   over the thickness  Δ h_i   of the turbulent layer   C ² _n ( h_i )Δ h_i   , where   h_i   is the altitude of the turbulent layer. These parameters are extracted from single star scintillation spatiotemporal cross-correlation functions of atmospheric speckles obtained within the generalized mode. This method is based on the simulated annealing algorithm to find the optimal solution required to solve the problem. Astrophysics parameters for adaptive optics are also calculated using   C ² _n ( h_i )  and   v ( h_i )  values. The results of other techniques support this new method.  相似文献   

A local clay-varve chronology and proglacial sedimentary environment in glacial Lake Peipsi, eastern Estonia     

TIIT HANG 《Boreas: An International Journal of Quaternary Research》2003,32(2):416-426

Ten cores consisting of varved clay from the northern part of Lake Peipsi in eastern Estonia have been correlated using varve thickness variations and specific marker varves into a 375-year floating varve chronology. Continuous sedimentation during gradual ice recession is concluded from a clear transition from proximal to distal varves. Cyclic variations in varve thickness are caused mainly by thickness changes of clayey winter layers. This is interpreted to indicate increased influx of finer material due to faster melting of the glacier. The cyclic pattern of thickness change is explained by alternating periods of increased and decreased melting of the ice. Simultaneous accumulation of varved clay in glacial Lake Peipsi and in the Luga and Neva basins of Russia is concluded from the good visual correlation between the mean varve thickness diagrams for the three chronologies. Because the varve chronologies from northwestern Russia have been tentatively correlated to the Swedish varve chronology, the timing of the clay accumulation in glacial Lake Peipsi is placed between c . 13 500 and 13 100 varve years BP.  相似文献   

Calibration of the kinematic method of studying solar wind disturbances on the basis of a one-dimensional MHD solution and a simulation study of the heliosphere disturbances between 22 november and 6 december 1977     

Wei Sun  S.-I. Akasofu  Z.K. Smith  M. Dryer 《Planetary and Space Science》1985,33(8):933-943

An empirical kinematic method developed by Hakamada and Akasofu (1982) is calibrated on the basis of a one-dimensional MHD solution. The calibrated results are used to simulate the stream-stream interaction and the background corotating structure in a simple situation and also during 22 November–6 December 1977. The solar wind disturbances caused by solar activities during this period are then introduced into the above background stream in simulating the heliospheric disturbance event which was observed by an aligned set of spacecraft at distances between 0.6 and 1.6 a.u. The observations and the simulated results are satisfactory, and a little more refinement in the simulation could reconstruct reasonably well the data by filling the data gaps in the solar wind speed, the density and the IMF magnitude.  相似文献   

Transient‐state groundwater flow in various geometries with wells at arbitrary positions: analytical methods     

M. W. Roth  C. M Wilson  M. Z. Iqbal 《水文研究》2003,17(17):3519-3530

We have developed a method for analytically solving the porous medium flow equation in many different geometries for horizontal (two‐dimensional), homogeneous and isotropic aquifers containing impermeable boundaries and any number of pumping or injection wells located at arbitrary positions within the system. Solutions and results are presented for rectangular and circular aquifers but the method presented here is easily extendible to many geometries. Results are also presented for systems where constant head boundary conditions can be emulated internal to the aquifer boundary. Recommendations for extensions of the present work are briefly discussed. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

A major sulphur isotope event at c. 510 Ma: a possible anoxia–extinction–volcanism connection during the Early–Middle Cambrian transition?     

M.L. Hough  G.A. Shields  L.Z. Evins  H. Strauss  R.A. Henderson  S. Mackenzie 《地学学报》2006,18(4):257-263

A new approach to constraining seawater δ³⁴S and sulphate concentration using francolite‐bound sulphate reveals an abrupt increase in δ³⁴S to +50‰ around the Early–Middle Cambrian boundary. Such high δ³⁴S values are best explained by increased rates of pyrite burial due to ocean anoxia coupled with an increased sensitivity of the ocean sulphate reservoir to perturbations due to low sulphate concentrations of 500–700 μgL^?1. We argue that the spread of anoxic waters at this time was partly the result of greenhouse warming related to the eruption of the Kalkarindji Large Igneous Province of northern Australia and that it triggered the collapse of early metazoan reef ecosystems during the latest Early Cambrian. Mass extinctions of the last 260 Myr have all coincided with enhanced volcanic activity, while several are also associated with positive shifts in seawater δ³⁴S. Extending this correlation back in time further implicates volcanically induced climate change as a major determining factor in biosphere evolution. Terra Nova, 18, 257–263, 2006  相似文献