Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

MATLAB在运用系统建模处理南海气象数据过程中应用     

董言治  周晓东  娄树理  陈永刚  沈同圣 《成都信息工程学院学报》2004,19(1):76-81

介绍了MATLAB语言特点和系统建模方法的基本理论.根据南海气象数据的实际建模处理过程,给出了建模的详细步骤及其MATLAB实现过程以及MATLABTM的主要实现程序.试验讨论和结果表明利用MATLAB语言可以方便地对南海气象数据用系统建模方法进行建模和处理,MATLAB在运用系统建模法处理南海气象数据方面具有明显的优越性.  相似文献   

Tanlu Fault Zone and Gold Ore Metallogenesis     

SHEN Yuanchao  ZENG Qingdong  LIU Tiebing 《东北亚地学研究》2002,(1)

Tanlu Fault Zone (TFZ) is a large NE trending deep fracture system in East China and is about 2500 km long. It extends from the south of Lujiang to Tancheng, and passes through the Bohai Sea and continues to the north, where it branches into Yilan ?Shulan Fault and Dunhua ?Mishan Fault. TFZ is a long lasting huge deep - rooted lithospherical fault system with different characteristics in different parts and at different periods of its evolution. TFZ also controls the distribution and occur-rences of many superlarge, large, middle and small sized gold ore deposits, e. g. Jiapigou, Haigou, Xiaoxihancha and Ciwei-gou gold deposits in Northeast China; Linglong, Jiaojia, Sanshandao, Taishang, Xincheng, Rushan, and Pengjiakuang gold deposits in Jiaodong Peninsula of Shandong Province; and Guilaizhuang and Yinan in Western Shandong Province.  相似文献   

CHARACTERIZATION OF LACTATE DEHYDROGENASE ISOZYME PATTERN AND MORPHOLOGY OF THREE MARINE FISH CELL LINES     

郭华荣  张士璀  李红岩  童裳亮  相建海 《中国海洋湖沼学报》2002,20(3):226-231

Three continuous marine fish cell lines of FG (i. e., Hounder Gill) from flounder (Paralichthys olivaceus) gill, SPH (i. e. , Sea Perch Heart) from sea perch (Lateolabrax japonicus) heart and RSBF (i.e., Red Sea Bream Fin) from red sea bream (Pagrosomus major) fin, were characterized by lactate dehydrogenase (LDH) isozyme and morphological analysis. The LDH isozyme patterns of these three cell lines and their corresponding tissues of origin were investigated and compared. The results showed: (1) No difference was found in the LDH isozyme patterns of FG and flounder gill tissue. However, the LDH isozyme patterns of SPH and RSBF were significantly different from their corresponding tissues of origin; (2) LDH isozyme patterns of FG, SPH and RSBF were markedly different from each other and could serve as genetic markers for species identification and detection of cross contamination. Morphological change analysis of these three cell lines in comparison to their original tissues indicated that FG cells still appeared epithelioid without morphological transformation. However, morphological changes were found in SPH and RSBF compared to their original tissues. Therefore, the cellular morphology was still plastic in the relatively stable culture conditions, and it was possible that change of LDH patterns wasrelated to morphological changes of fish cells in vitro.  相似文献   

射电源0420—014,1334—127和2345—167中的视超光速运动     

沈志强  万同山  洪晓瑜 《中国天文和天体物理学报》1997,(1)

本文叙述南天区 5GHzVLBI普查中新发现的视超光速射电源 ,0 4 2 0— 0 1 4,1 334—1 2 7和 2 345— 1 67,这些结果尚待进一步的观测加以证实  相似文献   

湖北徐家山锑矿床流体包裹体特征及其意义     

沈能平  彭建堂  袁顺达  张东亮  胡瑞忠  王国强 《矿床地质》2008,27(5):570-578

文章利用激光拉曼光谱和显微测温学方法,对湖北徐家山锑矿床成矿期的石英、重晶石和方解石中的流体包裹体进行了研究。研究表明,这些矿物中的流体包裹体主要有纯液体包裹体和液体包裹体(气相 液相)2类,其液体包裹体的气相成分为H2O±CO2±N2;石英、重晶石和方解石的均一温度分别为134~258℃、154~259℃和145~230℃,主要集中于150~200℃;流体的盐度w(NaCleq)和密度分别集中于3%~6%和0.90~0.96g/cm3。流体包裹体资料揭示出该矿床为典型的中低温热液锑矿床,其成矿流体为中低温、低盐度、中等密度热液。结合H、O、Sr、Pb同位素等研究结果,进一步推断该成矿热液主要是经深部循环演化的大气降水。  相似文献   

豫西前河构造蚀变岩型金矿成矿过程中的流体-岩石反应     

曹烨  李胜荣  申俊峰  要梅娟  李庆康  毛付龙 《矿床地质》2008,27(6):714-726

前河金矿区位于华北地台南缘,赋存在中元古界熊耳群安山岩和英安岩中,矿体受断裂破碎带控制。含矿热液在迁移过程中与围岩发生了广泛的流体-岩石反应而引起热液蚀变。本区石英中有4种类型的流体包裹体,均一温度范围为145～331℃,其中含CO2包裹体的完全均一温度主要分布在中-高温区。成矿流体的密度和压力变化范围分别是0.68～0.94g/cm3和(367.01～896.55)×105Pa。金大量沉淀成矿时的流体特征为:温度213～260℃、密度0.80～0.89g/cm3和压力(502.86～710.57)×105Pa。流体相为SO42->Na >Cl->K 型,CO2/H2O比值及N2、H2S、Ar、C2H6等挥发分的含量明显增高,f(CO2)、f(H2S)、f(CH4)和Eh值增大;f(O2)、f(H2O)和pH值减小。在青磐岩化安山岩的基础上发生的流体-岩石反应是造成本矿床金沉淀成矿的最主要原因。  相似文献   

诸广岩体南部基性岩脉的地球化学特征及成因     

徐文雄  王树忠  黄国龙  李伟林  沈渭洲  凌洪飞 《华东地质学院学报》2008,31(2)

诸广岩体南部的晚白垩世辉绿玢岩位于西部九峰岩体中部,呈近SN向展布.它具有较高的Al2O3(15.76%～18.70%),K2O(1.97%～3.17%),Na2O(4.20%～4.98%)含量和较低的TiO2(2.76%～2.84%),SiO2(46.75%～50.41%)含量.所有样品Na2O>K2O(Na2O/K2O=1.37～2.13)、大离子亲石元素(Ba,Rb,K,Th)富集明显、Cr和Ni的含量明显低于原始玄武岩浆的参考值;样品中稀土总量较高(158.4×10-6～191.6×10-6),轻稀土富集(LREE/HREE=6.45～6.56),基本无Eu异常(δEu=0.93～0.96).且具有低的εNd(t)值(-0.9～-2.2)、较高的(87Sr/86Sr)I值(0.71276～0.71312)和典型的Dupal异常铅特征.在Nd-Sr和Nd-Pb图解上,辉绿玢岩具有DMM和EMⅡ端员混合特征.这种富集特征不是由地幔岩浆上升过程中与地壳物质之间的同化混染作用造成.而是归因于俯冲带流体对上覆地幔楔的交代改造.因此,诸广岩体南部的辉绿玢岩是在晚白垩世时期地壳伸展和岩石圈减薄的构造环境下,由具有DMM和EMⅡ地幔端员混合特征的富集地幔源区部分熔融形成的.  相似文献   

四川省华蓥市赵子秀山变形体的成因机制研究   总被引：1，自引：0，他引：1  

伍保祥  沈军辉  沈中超  崔杰  王兰生 《水文地质工程地质》2008,35(3):23-27

赵子秀山变形体位于华蓥市西北部,变形体一旦失稳将直接对华蓥市造成威胁。本文从斜坡地质结构、变形破裂特征、地貌演化及人类工程活动(采煤)入手,结合数值模拟的方法研究变形体的变形机制。研究表明变形体的形成是下部含煤层的中倾角反向层状结构斜坡在河谷下切过程中发生倾倒-拉裂变形所致,同时,后期的采煤活动对拉裂变形的发展有较大影响。  相似文献   

地下水功能评价指标选取依据与原则的讨论   总被引：3，自引：0，他引：3  

王金哲  张光辉  申建梅  聂振龙  严明疆  YAN Ming-jiang 《水文地质工程地质》2008,35(2):76-81

地下水功能评价是实现地下水可持续利用和有效保护生态及地质环境的重要基础,而评价的关键是指标的选取。本文在遵循主导性、可度量、可操作、覆盖面广和灵活性原则的基础上,考虑地下水功能的影响因素、表征特征,从地下水系统的驱动、状态和响应因子中筛选出地下水功能评价的指标,从而为地下水功能评价建立了一套行之有效的指标集。  相似文献