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1.
Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff 下载免费PDF全文
We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AICC] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component. 相似文献
2.
网络时代的到来,对传统企业的组织结构、运作模式、管理方法均提出了严峻的挑战。传统的企业组织结构是适应大工业生产而形成的等级组织结构形式,它有很大的局限性;电子商务企业的组织结构是适应网络社会而形成扁平化、双向多对多、以信息为基础的新型组织结构形式。电子商务企业以其组织结构扁平化和中空化,决策分散化,运作虚拟化,灵活高效为特点,它将成为传统企业在电子商务发展阶段变革的方向和目标。 相似文献
3.
采用PCR技术对2种亚洲龙鱼的mtDNAD_Loop全序列进行扩增和测序,序列结构分析和序列同源性比对结果表明,2种亚洲龙鱼的mtDNAD_Loop在靠近5’端有3个终止相关序列TAS(Ⅰ、Ⅱ、Ⅲ),靠近D_Loop的3’端有4个保守区域CSB1、CSB2、CSB3、CSB-D。在终止相关序列和保守区域之间是连续重复区域。经DNASP4.0软件分析,全序列中检测出多态位点数(S)为26,其中有17个转换,核苷酸多样性(Pi)为0.013,平均核苷酸差异数(K)为17.333。 相似文献
4.
An improved approach is given for deriving the physical parameters of a molecular cloud by its NH3 rotation-inversion hyperfine spectra. The optical depth τ0(1, 1) of NH3 (1,1) is obtained by considering the blending effect of the magnetic hyperfine spectral lines, the (1-1) excitation temperature Tex (1, 1) is calculated by a two level model, the effect of different collision rate and the thermalization of the (1, 1) inversion lines are discussed, the rotation temperature TR ( 2, 1) between the NH3 levels (2, 2) and (1, 1) and the column density N( 1, 1) of the NH3 (1, 1) inversion level are derived, the results of the total column density from different assumptions for the abundance ratio of ortho-NH3 and para-NH3 are also discussed.
This approach is used for the molecular cloud NGC 2023 by using the relevant observed data and its optical depth and other physical parameters are obtained. 相似文献
5.
Three continuous marine fish cell lines of FG (i. e., Hounder Gill) from flounder (Paralichthys olivaceus) gill, SPH (i. e. , Sea Perch Heart) from sea perch (Lateolabrax japonicus) heart and RSBF (i.e., Red Sea Bream Fin) from red sea bream (Pagrosomus major) fin, were characterized by lactate dehydrogenase (LDH) isozyme and morphological analysis. The LDH isozyme patterns of these three cell lines and their corresponding tissues of origin were investigated and compared. The results showed: (1) No difference was found in the LDH isozyme patterns of FG and flounder gill tissue. However, the LDH isozyme patterns of SPH and RSBF were significantly different from their corresponding tissues of origin; (2) LDH isozyme patterns of FG, SPH and RSBF were markedly different from each other and could serve as genetic markers for species identification and detection of cross contamination. Morphological change analysis of these three cell lines in comparison to their original tissues indicated that FG cells still appeared epithelioid without morphological transformation. However, morphological changes were found in SPH and RSBF compared to their original tissues. Therefore, the cellular morphology was still plastic in the relatively stable culture conditions, and it was possible that change of LDH patterns wasrelated to morphological changes of fish cells in vitro. 相似文献
6.
本文叙述南天区 5GHzVLBI普查中新发现的视超光速射电源 ,0 4 2 0— 0 1 4,1 334—1 2 7和 2 345— 1 67,这些结果尚待进一步的观测加以证实 相似文献
7.
长江三峡工程地壳形变监测网络 总被引:19,自引:10,他引:9
长江三峡工程地壳形变监测网络,采用了当今高精度GPS、INSAR空间大地测量技术,并与精密水准测量,精密重力测量,精密激光测距和峒体连续形变监测等技术相结合,构成一个空间上点、线、面结合,时间上长、中、短兼顾的高精度,高时空分辨率的地壳形变监测网络。该网络既可获取三峡库区特别是库首区区域形变场和区域应变场的动态变化,监测库区主要断层活动,为水库诱发地震预测及研究服务,又可用于气象、滑坡地质灾害监测等,该监测网络于1997年底开始建设,2001年6月建成,到目前为止,已获得大量宝贵的观测资料,必将产生显著的经济效益和社会效益。 相似文献
8.
9.
Tetraploid induced by physical and chemical methods in Jinjiang oyster(Crassostrea rivularis) 总被引:1,自引:0,他引:1
Rong Shoubai Shi Shumei Mo Qirong Liu Shaeqiong Liang Ze Zhao Xiuzhu Tong Wangdong Li Shouwu Li Yimin 《海洋学报(英文版)》1994,13(2):275-283
TetraploidinducedbyphysicalandchemicalmethodsinJinjiangoyster(Crassostrearivularis)¥RongShoubai,ShiShumei,McQirong,LiuShaeqio... 相似文献
10.
1 .IntroductionNondestructiveinspection (NDI)isveryimportantforensuringthereliabilityofoffshorestructuresintheirservicelives (Lauraetal.,1 996 ) .Itiswellknownthatdetectionofflawsinvolvesconsider ablestatisticaluncertainties.Asaresult,theprobabilityofdetection (POD)forallflawsofagivensizehasbeenusedintheliteraturetodefinethecapabilityofaparticularNDItechniqueinagivenen vironment.SincethedataofPODusuallyscatterlargely ,itisdifficulttodeterminewhichmodelfitstheavailabledatabest.Thismodelun… 相似文献