Sulfuric Acid Production on Europa: The Radiolysis of Sulfur in Water Ice     

R.W. CarlsonM.S. Anderson  R.E. JohnsonM.B. Schulman  A.H. Yavrouian 《Icarus》2002,157(2):456-463

Europa's surface is chemically altered by radiolysis from energetic charged particle bombardment. It has been suggested that hydrated sulfuric acid (H₂SO₄·nH₂O) is a major surface species and is part of a radiolytic sulfur cycle, where a dynamic equilibrium exists between continuous production and destruction of sulfur polymers S_x, sulfur dioxide SO₂, hydrogen sulfide H₂S, and H₂SO₄·nH₂O. We measured the rate of sulfate anion production for cyclo-octal sulfur grains in frozen water at temperatures, energies, and dose rates appropriate for Europa using energetic electrons. The measured rate is G_Mixture(SO₄²⁻)=f_Sulfur (r₀/r)^βG₁ molecules (100 eV)⁻¹, where f_Sulfur is the sulfur weight fraction, r is the grain radius, r₀=50 μm, β≈1.9, and G₁=0.4±0.1. Equilibrium column densities N are derived for Europa's surface and follow the ordering N(H₂SO₄) » N(S)>N(SO₂)>N(H₂S). The lifetime of a sulfur atom on Europa's surface for radiolysis to H₂SO₄ is τ(−S)=120(r/r₀)^β years. Rapid radiolytic processing hides the identity of the original source of the sulfurous material, but Iogenic plasma ion implantation and an acidic or salty ocean are candidate sources. Sulfate salts, if present, would be decomposed in <3800 years and be rapidly assimilated into the sulfur cycle.  相似文献   

An example of fingerprint detection of greenhouse climate change     

DJ Karoly  JA Cohen  GA Meehl  JFB Mitchell  AH Oort  RJ Stouffer  RT Wetherald 《Climate Dynamics》1994,10(1-2):97-105

As an example of the technique of fingerprint detection of greenhouse climate change, a multivariate signal or fingerprint of the enhanced greenhouse effect is defined using the zonal mean atmospheric temperature change as a function of height and latitude between equilibrium climate model simulations with control and doubled CO₂ concentrations. This signal is compared with observed atmospheric temperature variations over the period 1963 to 1988 from radiosonde-based global analyses. There is a significant increase of this greenhouse signal in the observational data over this period.These results must be treated with caution. Upper air data are available for a short period only, possibly too short to be able to resolve any real greenhouse climate change. The greenhouse fingerprint used in this study may not be unique to the enhanced greenhouse effect and may be due to other forcing mechanisms. However, it is shown that the patterns of atmospheric temperature change associated with uniform global increases of sea surface temperature, with El NinoSouthern Oscillation events and with decreases of stratospheric ozone concentrations individually are different from the greenhouse fingerprint used here.  相似文献   

Integrated Futures for Europe’s Mountain Regions: Reconciling Biodiversity Conservation and Human Livelihoods   总被引：1，自引：1，他引：0  

Jonathan Mitchley  Martin F.Price  Joseph Tzanopoulos 《山地科学学报》2006,(4)

Introduction Europe's mountains cover nearly half of the continent's area (Price et al. 2004) and land cover varies significantly (European Commission 2004). In most massifs, except for Sicily, southern Greece, and the British Isles, forest cover is dominant. In northern Europe, grassland is proportionately more important, and much of the mountains of the British Isles is covered by moorland. In central and southern Europe, arable land is of far greater importance than grassland, with Med…  相似文献