Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Dynamic modelling of retrogressive landslides with emphasis on the role of clay sensitivity          下载免费PDF全文

Xue Zhang  Scott W. Sloan  Eugenio Oñate 《国际地质力学数值与分析法杂志》2018,42(15):1806-1822

This paper presents a detailed numerical study of the retrogressive failure of landslides in sensitive clays. The dynamic modelling of the landslides is carried out using a novel continuum approach, the particle finite element method, complemented with an elastoviscoplastic constitutive model. The multiwedge failure mode in the collapse is captured successfully, and the multiple retrogressive failures that have been widely observed in landslides in sensitive clays are reproduced with the failure mechanism, the kinematics, and the deposition being discussed in detail. Special attention has been paid to the role of the clay sensitivity on each retrogressive failure as well as on the final retrogression distance and the final run‐out distance via parametric studies. Moreover, the effects of the viscosity of sensitive clays on the failure are also investigated for different clay sensitivities.  相似文献   

2060 Chiron back to a minimum of brightness     

Daniela Lazzaro  Marcos A. Florczak  Alberto Betzler  Othon C. Winter  Silvia M. Giuliatti-Winter  Claudia A. Angeli  Dietmar W. Foryta 《Planetary and Space Science》1996,44(12):1547-1550

The results of photometric observations of comet/asteroid 2060 Chiron at the Observatório do Pico dos Dias (Brazil-OPD) and the Observatoire de Haute-Provence (France-OHP) during 1994 and 1995 are presented. The analysis of the data shows a decrease of 2060 Chiron brightness from its peak values of 1988–1991. The absolute magnitude, H_v, varies from a maximum of 6.6 in February 1994 up to a minimum of 6.8 in June 1995. Therefore 2060 Chiron is back to a minimum of activity close to that of 1983–1985. The slope parameter G is found to be G = 0.71 ± 0.15. It is suggested that the H-G magnitude system, generally adopted to present 2060 Chiron brightness, is not the most appropriate due to the cometary activity of this object.  相似文献   

Preface to tropical coastal sedimentary environments     

Chuck Nittrouer  Alberto Figueiredo 《Geo-Marine Letters》1996,16(1):1-2

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On the Nonlinear Thermal Evolution of Solar Corona Structures     

C.A. Mendoza-Briceño 《Astrophysics and Space Science》1997,256(1-2):387-392

The thermal evolution of structures is investigated for different values of the size of structure. A simplified cooling function and a constant heating mechanism are assumed. Analytical criteria for thermal instability are obtained. It is found that the response of the thermal structure not only depends on the amplitude of the disturbances, but also on whether the disturbance increases or decreases the initial steady temperature. Additionally, the evolution of the structure is examined numerically by using a time-dependent code under the assumption that the inertia terms are small. In particular, the analytical criteria obtained for thermal instability are verified.  相似文献   

The Auger Observatory in Argentina     

Alberto Etchegoyen 《Astrophysics and Space Science》2004,290(3-4):379-387

The Auger Project studies the highest energies known in nature with an emphasis on energies ≥5 × 10¹⁹ eV, which are cosmic rays coming from the outer space reaching the Earth's surface with a very low flux. The questions to be elucidated are what are the origin, energy, production mechanism, and chemical composition of these cosmic rays. Auger aims at building two observatories in both the hemispheres and in 2000 the construction of the austral observatory started. Auger's two distinctive features are its exceptional size and its hybrid nature. It spans over an area of 3000 km² and is constituted by 24 fluorescence detector telescopes and 1600 surface detectors. As such, it will provide a large number of events with less systematic detection uncertainties. The construction of the Southern Observatory in Argentina is quite advanced and the buildings at the Central Station in Malargüe city are already operational. So are the telescope buildings at Cerros Los Leones and Coihueco (two prototype telescopes were operational at Los Leones, which have now been dismantled), 32 surface detectors, and the telecommunication and data acquisition systems. About 20-hybrid events/months were detected and currently two events/hours are registered with the surface detector array. The detection of hybrid events is the most important issue since it shows that the equipment operates within the design parameters.  相似文献   

Opposition polarimetry and photometry of S- and E-type asteroids     

Irina N Belskaya  Vasilij G Shevchenko  Yurij N Krugly  Yurij S Efimov  Alberto Cellino 《Icarus》2003,166(2):276-284

The first results of the observational program devoted to simultaneous investigation of asteroid polarimetric and photometric opposition phenomena are presented. UBVRI polarimetric and V-band photometric observations of the S-type Asteroid 20 Massalia and the E-type Asteroids 214 Aschera and 620 Drakonia were carried out in 1996-1999 down to phase angles of 0.08°, 0.7°, and 1.2°, correspondingly. The S-type Asteroid 20 Massalia is characterized by the pronounced brightness opposition surge with an amplitude larger than that observed for the E-type asteroids. A sharp peak of negative polarization at small phase angles was not observed for this asteroid. The value of polarization degree at phase angle α<1° is less than 0.5% for both S and E types. The negative polarization branches of S and especially E-asteroids have an asymmetrical shape. The phase angle at which the polarization minimum occurs is close to the angle at which non-linear increase begins in the asteroid magnitude phase curves. A relation of the observed effects to the mechanism of coherent backscattering is discussed.  相似文献   

Revision of the earthquake catalogue and seismicity of Croatia, 1908–1992     

Marijan Herak  Davorka Herak  Snje&#;ana Marku&#;i&#; 《地学学报》1996,8(1):86-94

The paper presents the results of Croatian earthquake catalogue revision for the period 1908–1992. The revised catalogue lists a total of 4853 events (4486 after 1908), of which 3700 are mainshocks. All primary data sources available to us (seismograms, phase onset time readings, macroseismic questionnaires…) were consulted in order to improve the quality and reliability of magnitude, intensity and location. Along with the most important earthquake parameters the catalogue contains entries that enable assessment of the reliability of location and bibliographic references. Using the temporal analysis of the maximum-likelihood estimate of the b -value in the frequency-magnitude relation, the catalogue is estimated to be complete for events with M ≥ 4.0 throughout the investigated period. The magnitude completeness threshold decreases to 3.8 after the middle of the century, and to about 3.6 in the last three decades. It is noted that the b-value variation with time is closely tied to the seismic activity, as well as that at present there seems to be a lack of seismic energy release corresponding to the M = 6.0–6.5 earthquake.  相似文献   

On the self-consistency of evolutionary synthesis models     

Miguel Cerviño 《Astrophysics and Space Science》2003,284(2):897-900

Evolutionary synthesis models have been used to study the physical properties of unresolved populations in a wide range of scenarios. Unfortunately, their self-consistency is difficult to test and there are some theoretical open questions without an answer: (1) The change of the homology relations assumed in the computation of isochrones due to the effect of stellar winds (or rotation) and the discontinuities in the stellar evolution are not considered. (2) There is no consensus about how the isochrones must be integrated. (3) The discreteness of the stellar populations (that produce an intrinsic statistical dispersion) usually are not taken into account, and model results are interpreted in a deterministic way instead of a statistical one. The objective of this contribution is to present some inconsistencies in the computation and some cautions in the application of the results of such codes. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Carbon biogeochemistry of the Betsiboka estuary (north-western Madagascar)   总被引：1，自引：0，他引：1  

Olivier Harifidy Ralison  Alberto Vieira Borges  Frank Dehairs  J.J. Middelburg  Steven Bouillon   《Organic Geochemistry》2008,39(12):1649

Madagascar’s largest estuary (Betsiboka) was sampled along the salinity gradient during the dry season to document the distribution and sources of particulate and dissolved organic carbon (POC, DOC) as well as dissolved inorganic carbon (DIC). The Betsiboka was characterized by a relatively high suspended matter load, and in line with this, low DOC/POC ratios (0.4–2.5). The partial pressure of CO₂ (pCO₂) was generally above atmospheric equilibrium (270–1530 ppm), but relatively low in comparison to other tropical and subtropical estuaries, resulting in low average CO₂ emission to the atmosphere (9.1 ± 14.2 mmol m⁻² d⁻¹). Despite the fact that C4 vegetation is reported to cover >80% of the catchment area, stable isotope data on DOC and POC suggest that C4 derived material comprises only 30% of both pools in the freshwater zone, increasing to 60–70% and 50–60%, respectively, in the oligohaline zone due to additional lateral inputs. Sediments from intertidal mangroves in the estuary showed low organic carbon concentrations (<1%) and δ¹³C values (average −19.8‰) consistent with important inputs of riverine imported C4 material. This contribution was reflected in δ¹³C signatures of bacterial phospholipid derived fatty acids (i + a15:0), suggesting the potential importance of terrestrial organic matter sources for mineralization and secondary production in coastal ecosystems.  相似文献