Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Study of the flood control scheduling scheme for the Three Gorges Reservoir in a catastrophic flood          下载免费PDF全文

Shanghong Zhang  Zhu Jing  Wenda Li  Yujun Yi  Yong Zhao 《水文研究》2018,32(11):1625-1634

The Three Gorges Project is the world's largest water conservancy project. According to the design standards for the 1,000‐year flood, flood diversion areas in the Jingjiang reach of the Yangtze River must be utilized to ensure the safety of the Jingjiang area and the city of Wuhan. However, once these areas are used, the economic and life loss in these areas may be very great. Therefore, it is vital to reduce this loss by developing a scheme that reduces the use of the flood diversion areas through flood regulation by the Three Gorges Reservoir (TGR), under the premise of ensuring the safety of the Three Gorges Dam. For a 1,000‐year flood on the basis of a highly destructive flood in 1954, this paper evaluates scheduling schemes in which flood diversion areas are or are not used. The schemes are simulated based on 2.5‐m resolution reservoir topography and an optimized model of dynamic capacity flood regulation. The simulation results show the following. (a) In accord with the normal flood‐control regulation discharge, the maximum water level above the dam should be not more than 175 m, which ensures the safety of the dam and reservoir area. However, it is necessary to utilize the flood diversion areas within the Jingjiang area, and flood discharge can reach 2.81 billion m³. (b) In the case of relying on the TGR to impound floodwaters independently rather than using the flood diversion areas, the maximum water level above the dam reaches 177.35 m, which is less than the flood check level of 180.4 m to ensure the safety of the Three Gorges Dam. The average increase of the TGR water level in the Chongqing area is not more than 0.11 m, which indicates no significant effect on the upstream reservoir area. Comparing the various scheduling schemes, when the flood diversion areas are not used, it is believed that the TGR can execute safe flood control for a 1,000‐year flood, thereby greatly reducing flood damage.  相似文献   

γ射线暴的logN(>P)～logP分布     

吴枚  宋黎明  余文飞  李惕碚  李毅 《中国天文和天体物理学报》1997,(1)

本文用简单的宇宙学模型 ,在标准烛光和均匀分布的假设下计算了γ射线暴的logN(>P)～logP分布 (大小谱 ) .在考虑了探测效率修正和死时间修正后 ,由宇宙学模型计算的理论结果和BATSE实测的大小谱没有显著的偏离  相似文献   

On penetration depth of the Shoemaker-Levy 9 fragments into the Jovian atmosphere     

Zhong-Wei Hu  Yi Chu  Kai-Jun Zhang 《Earth, Moon, and Planets》1996,73(2):147-155

The actual penetration depth of the Shoemaker-Levy 9 fragments into the Jovian atmosphere is still an open question. From fundamental equations of meteoric physics with variable cross-section, a new analytic model of energy release of the fragments is presented. In use of reasonable parameters, a series of results are calculated for different initial mass of the fragments. The results show that the largest fragment explodes above pressure levels of 3 bars and does not penetrate into the H₂O cloud layer of the Jovian atmosphere, and that airburst of smaller fragments occur even above the upper cloud layer.  相似文献   

First Post-Newtonian Angular Momentum In Relativistic Celestial Mechanics     

Jin-He Tao  Tian-Yi Huang  Zhao-Hua Yi 《Astrophysics and Space Science》1997,254(2):173-186

With a new theory on the 1PN celestial mechanics recently developed by Damour, Soffel and Xu (1991,1992,1993,1994), definitions and expressions of the 1PN spin angular momentum are investigated and analysed. The total spin angular momentum of a system of extended bodies such as the solar system is calculated and expressed as the function of local parameters and observables under reasonable assumptions, which would find its application in the evolution and dynamics of systems of celestial bodies. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

成都及附近地区旅游气候资源研究   总被引：9，自引：0，他引：9  

胡毅  朱克云  江毓忠 《成都信息工程学院学报》2001,16(4):237-242

通过对成都及附近等7个地区多年气候资源及人体舒适指数进行分级比较，得出了7个地区的人体舒适指数的时间分布特征及对当地旅游的影响。  相似文献   

Systematic uncertainties in the analysis of star cluster parameters based on broad-band imaging observations     

R. de Grijs  P. Anders  H. J. G. L. M. Lamers  N. Bastian  U. Fritze-v. Alvensleben  G. Parmentier †  M. E. Sharina  S. Yi 《Monthly notices of the Royal Astronomical Society》2005,359(3):874-894

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彭州市立体农业气候资源的研究(二)热量资源分析   总被引：2，自引：0，他引：2  

周定文  胡毅 《成都信息工程学院学报》2001,16(3):169-173

利用彭州市境内市气象站，新兴，白果坪的日平均气温资料，进行热量资源分析。结果表明，彭州市7－8月为最热月，多年平均温度低于24．9℃，12－2月为最冷月，多年平均温度高于1．7℃。大多数年全年稳定通过0℃，可一年四季进行农业耕作，有利于作物越冬和多年生作物的种植，生长期长，积温丰富。界限温度的初，终日期及持续日数变化较大，积温际变化显著，热量资源随海拔高度增加而减少，各界限温度的初日推迟，终日提前，持续日数和积温减少，温度强度也降低，形成显著的立体农业气候。  相似文献   

彭州市立体农业气候资源的研究(一)降水资源分析   总被引：4，自引：0，他引：4  

周定文  胡毅 《成都信息工程学院学报》2001,16(2):91-96

分析了彭州市境内位于不同海拔高度的4个观测站的降水资料，结果表明，彭州市雨量充沛，但降水量的年际变化显著，雨季起、止时间和雨季长、短的年际变化很大，降水的时间分配极不均匀，因为这4个站具有相同的气候背景、，降水量的年、季、月变化呈现基本一致的规律和趋势，但因为海拔高度不同等气候背的差异，4站的降水特点又显著不同。降水量随海拔高度的升高而增加，降水变幅和雨日也阴海拔高度的升高而增加，大降水过程具有明显的局地性，不同海拔高度的旱、涝情况亦有差异，降水的空间分布表现出明显的立体性特征。  相似文献   

CHARACTERIZATION OF LACTATE DEHYDROGENASE ISOZYME PATTERN AND MORPHOLOGY OF THREE MARINE FISH CELL LINES     

郭华荣  张士璀  李红岩  童裳亮  相建海 《中国海洋湖沼学报》2002,20(3):226-231

Three continuous marine fish cell lines of FG (i. e., Hounder Gill) from flounder (Paralichthys olivaceus) gill, SPH (i. e. , Sea Perch Heart) from sea perch (Lateolabrax japonicus) heart and RSBF (i.e., Red Sea Bream Fin) from red sea bream (Pagrosomus major) fin, were characterized by lactate dehydrogenase (LDH) isozyme and morphological analysis. The LDH isozyme patterns of these three cell lines and their corresponding tissues of origin were investigated and compared. The results showed: (1) No difference was found in the LDH isozyme patterns of FG and flounder gill tissue. However, the LDH isozyme patterns of SPH and RSBF were significantly different from their corresponding tissues of origin; (2) LDH isozyme patterns of FG, SPH and RSBF were markedly different from each other and could serve as genetic markers for species identification and detection of cross contamination. Morphological change analysis of these three cell lines in comparison to their original tissues indicated that FG cells still appeared epithelioid without morphological transformation. However, morphological changes were found in SPH and RSBF compared to their original tissues. Therefore, the cellular morphology was still plastic in the relatively stable culture conditions, and it was possible that change of LDH patterns wasrelated to morphological changes of fish cells in vitro.  相似文献