Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Analytical study of ground motion caused by seismic wave propagation across faulted rock masses          下载免费PDF全文

J.C. Li  N.N. Li  S.B. Chai  H.B. Li 《国际地质力学数值与分析法杂志》2018,42(1):95-109

Studying seismic wave propagation across rock masses and the induced ground motion is an important topic, which receives considerable attention in design and construction of underground cavern/tunnel constructions and mining activities. The current study investigates wave propagation across a rock mass with one fault and the induced ground motion using a recursive approach. The rocks beside the fault are assumed as viscoelastic media with seismic quality factors, Q_p and Q_s. Two kinds of interactions between stress waves and a discontinuity and between stress waves and a free surface are analyzed, respectively. As the result of the wave superposition, the mathematical expressions for induced ground vibration are deduced. The proposed approach is then compared with the existing analysis for special cases. Finally, parametric studies are carried out, which includes the influences of fault stiffness, incident angle, and frequency of incident waves on the peak particle velocities of the ground motions.  相似文献   

The mass ratio of Charon to Pluto from Hubble Space Telescope astrometry with the fine guidance sensors     

C.B Olkin  L.H Wasserman  O.G Franz 《Icarus》2003,164(1):254-259

The mass ratio of Charon to Pluto is a basic parameter describing the binary system and is necessary for determining the individual masses and densities of these two bodies. Previous measurements of the mass ratio have been made, but the solutions differ significantly (Null et al., 1993; Young et al., 1994; Null and Owen, 1996; Foust et al., 1997; Tholen and Buie, 1997). We present the first observations of Pluto and Charon with a well-calibrated astrometric instrument—the fine guidance sensors on the Hubble Space Telescope. We observed the motion of Pluto and Charon about the system barycenter over 4.4 days (69% of an orbital period) and determined the mass ratio to be 0.122±0.008 which implies a density of 1.8 to 2.1 g cm⁻³ for Pluto and 1.6 to 1.8 g cm⁻³ for Charon. The resulting rock-mass fractions for Pluto and Charon are higher than expected for bodies formed in the outer solar nebula, possibly indicating significant postaccretion loss of volatiles.  相似文献   

Warm gas kinematics in shell galaxies     

R. Rampazzo  H. Plana  M. Longhetti  P. Amram  J. Boulesteix  J.-L. Gach  O. Hernandez 《Monthly notices of the Royal Astronomical Society》2003,343(3):819-830

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Cosmological constraints from the local X-ray luminosity function of the most X-ray-luminous galaxy clusters     

S. W. Allen  R. W. Schmidt  A. C. Fabian  H. Ebeling 《Monthly notices of the Royal Astronomical Society》2003,342(1):287-298

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Optical flashes and very early afterglows in wind environments     

X. F. Wu  Z. G. Dai  Y. F. Huang  T. Lu 《Monthly notices of the Royal Astronomical Society》2003,342(4):1131-1138

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Solid solutions in mineral nomenclature     

E. H. Nickel 《Mineralogy and Petrology》1992,46(1):49-53

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An expansion of the Voigt function     

H. A. Harutyunian 《Astrophysics》1996,39(4):370-374

The Voigt function and its derivatives are represented by means of series in Hermite polynomials. The equations obtained can be used both for numerical calculations of these functions and for analytical research.Translated from Astrofizika, Vol. 39, No. 4, pp. 619–625, October–December, 1996.  相似文献   

The MPE X-ray test facility PANTER: Calibration of hard X-ray (15–50 kev) optics     

M. J. Freyberg  H. Bräuninger  W. Burkert  G. D. Hartner  O. Citterio  F. Mazzoleni  G. Pareschi  D. Spiga  S. Romaine  P. Gorenstein  B. D. Ramsey 《Experimental Astronomy》2005,20(1-3):405-412

The Max-Planck-Institut für extraterrestrische Physik (MPE) in Garching, Germany, uses its large X-ray beam line facility PANTER for testing X-ray astronomical instrumentation. A number of telescopes, gratings, filters, and detectors, e.g. for astronomical satellite missions like Exosat, ROSAT, Chandra (LETG), BeppoSAX, SOHO (CDS), XMM-Newton, ABRIXAS, Swift (XRT), have been successfully calibrated in the soft X-ray energy range (< 15keV). Moreover, measurements with mirror test samples for new missions like ROSITA and XEUS have been carried out at PANTER. Here we report on an extension of the energy range, enabling calibrations of hard X-ray optics over the energy range 15–50 keV. Several future X-ray astronomy missions (e.g., Simbol-X, Constellation-X, XEUS) have been proposed, which make use of hard X-ray optics based on multilayer coatings. Such optics are currently being developed by the Osservatorio Astronomico di Brera (OAB), Milano, Italy, and the Harvard-Smithsonian Center for Astrophysics (CfA), Cambridge, MA, USA. These optics have been tested at the PANTER facility with a broad energy band beam (up to 50 keV) using the XMM-Newton EPIC-pn flight spare CCD camera with its good intrinsic energy resolution, and also with monochromatic X-rays between C-K (0.277 keV) and Cu-Kα (8.04 keV). PACS: 95.55.Ka, 95.55.Aq, 41 50.+h, 07.85.Fv  相似文献   

Coronal change at the south-west limb observed by Yohkoh on 9 November 1991, and the subsequent interplanetary shock at Pioneer Venus Orbiter     

Shinichi Watari  Z. Smith  H. A. Garcia  T. Detman  M. Dryer 《Solar physics》1996,167(1-2):357-369

A spectacular change in the lower corona on the south-west limb has been found in solar images taken by the Yohkoh soft X-ray telescope. The event is characterized by a large topological change in magnetic field and a large intensity decrease observed after the X1. 1/1B flare on 9 November, 1991. A coronal mass ejection (CME) was observed by the Mark III K-coronameter (MK3) at the HAO/Mauna Loa Observatory. Both the MK3 (white-light) and soft X-ray observations showed that one leg of this CME was located above the flare site. An interplanetary shock associated with this event was observed by Pioneer Venus Orbiter, and, possibly, by IMP-8.Also Cooperative Institute for Research in the Environmental Sciences (CIRES), University of Colorado, Boulder, CO 80309, U.S.A.  相似文献