Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Optical flashes and very early afterglows in wind environments     

X. F. Wu  Z. G. Dai  Y. F. Huang  T. Lu 《Monthly notices of the Royal Astronomical Society》2003,342(4):1131-1138

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ECOLOGICAL SERIES OF SOIL ANIMALS IN DARLIDAI MOUNTAIN   总被引：1，自引：0，他引：1  

HOUWei-ling FANHong 《中国地理科学(英文版)》2002,12(4):378-382

The ecological series of soil animals under the broad-leaved and pine mixed forest in Darlidai Mountainwas studied. Seven sample plots were selected according to different altitude gradients, which belong to different vegeta-tion types. By investigating and analyzing soil animals in every sample plot it is found that there are 45 groups and 1956individuals, which axe involved in 3 phylums, 7 classes, 16 orders, respectively. The altitude is a key factor which af-fects ecological series of soil animals. Both the groups and individuals of soil animals increase with altitude increasingunder certain conditions, which contrastes with ordinary cases, resulting from special micro-climate in studied area. Thegroups and individuls of soil animals are the most under the broad-leaved and pine forest on the top of the mountain, andthe least under Picea-Abies forest in the foot of the mountain.  相似文献   

CORROSION RESISTANCE OF INTERFERENCE FILM ON STAINLESS STEEL     

张经磊  侯保荣 《中国海洋湖沼学报》1997,15(4):363-368

IwrRODUcrlONStainlessstalhasbeenusedwidelyasbuildingrnateria1,especiallyasdecoratingrnate-rialinbuildings.Ordinarystainlesssteehasonlyonemonot0noussilverywhitCcolourwhichsomeimesdoesnotrnatchwithitSsurmundingenvironment.lnordert0improveitSdereratingperfonnaneeandexpanditsuse,muchresearchhasbeenconductedsincethe4O'st0trytoformabright,uniform,highcorrosi0nandwearresistantco1ourfilmonastainlesssteesurface.Duringtheeariystage,anirnmersionedhodwasused,i.e.inimrs-ingthestainlesssteelinahots0luti…  相似文献   

Five WC9 stars discovered in the AAO/UKST Hα survey     

E. C. Hopewell  M. J. Barlow  J. E. Drew  Y. C. Unruh  Q. A. Parker  M. J. Pierce  P. A. Crowther  C. Knigge  S. Phillipps  A. A. Zijlstra 《Monthly notices of the Royal Astronomical Society》2005,363(3):857-866

We report the discovery of five massive Wolf–Rayet (WR) stars resulting from a programme of follow-up spectroscopy of candidate emission-line stars in the Anglo-Australian Observatory United Kingdom Schmidt Telescope (AAO/UKST) Southern Galactic Plane Hα survey. The 6195–6775 Å spectra of the stars are presented and discussed. A WC9 class is assigned to all five stars through comparison of their spectra with those of known late-type WC stars, bringing the known total number of Galactic WC9 stars to 44. Whilst three of the five WC9 stars exhibit near-infrared (NIR) excesses characteristic of hot dust emission (as seen in the great majority of known WC9 stars), we find that two of the stars show no discernible evidence of such excesses. This increases the number of known WC9 stars without NIR excesses to seven. Reddenings and distances for all five stars are estimated.  相似文献   

Aircraft Observation of CO₂, CO, O₃ and H₂ over the North Pacific during the PACE-7 Campaign     

Y. SAWA  H. MATSUEDA  Y. MAKINO  H. Y. INOUE  S. MURAYAMA  M. HIROTA  Y. TSUTSUMI  Y. ZAIZEN  M. IKEGAMI  K. OKADA 《Tellus. Series B, Chemical and physical meteorology》2004,56(1):2-20

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An approximate method for evaluating the shear band thickness in saturated soils     

X. B. Lu  Wang Shuyun  Wang Yihua  Peng Cui 《国际地质力学数值与分析法杂志》2004,28(15):1533-1541

A formula for the thickness of a shear band formed in saturated soils under a simple shear or a combined stress state has been proposed. It is shown that the shear band thickness is dependent on the pore pressure properties of the material and the dilatancy rate, but is independent of the details of the combined stress state. This is in accordance with some separate experimental observations. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Zircon U–Pb age, trace element and Hf isotope composition of Kongling terrane in the Yangtze Craton: refining the timing of Palaeoproterozoic high-grade metamorphism     

Y.-B. WU  S. GAO  H.-J. GONG  H. XIANG  W.-F. JIAO  S.-H. YANG  Y.-S. LIU  H.-L. YUAN 《Journal of Metamorphic Geology》2009,27(6):461-477

U–Pb age, trace element and Hf isotope compositions of zircon were analysed for a metasedimentary rock and two amphibolites from the Kongling terrane in the northern part of the Yangtze Craton. The zircon shows distinct morphological and chemical characteristics. Most zircon in an amphibolite shows oscillatory zoning, high Th/U and ¹⁷⁶Lu/¹⁷⁷Hf ratios, high formation temperature, high trace element contents, clear negative Eu anomaly, as well as HREE-enriched patterns, suggesting that it is igneous. The zircon yields a weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 2857 ± 8 Ma, representing the age of the magmatic protolith. The zircon in the other two samples is metamorphic. It has low Th/U ratios, low trace element concentrations, variable HREE contents (33.8 ≥ Lu_N≥2213; 14.7 ≤ Lu_N/Sm_N ≤ 354) and ¹⁷⁶Lu/¹⁷⁷Hf ratios (0.000030–0.001168). The data indicate that the zircon formed in the presence of garnet and under upper amphibolite facies conditions. The metamorphic zircon yields a weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 2010 ± 13 Ma. These results combined with previously obtained Palaeoproterozoic metamorphic ages suggest a c. 2.0 Ga Palaeoproterozoic collisional event in the Yangtze Craton, which may result from the assembly of the supercontinent Columbia. The zircon in two samples yields weighted mean two-stage Hf model ( T _DM2) ages of 3217 ± 110 and 2943 ± 50 Ma, respectively, indicating that their protoliths were mainly derived from Archean crust.  相似文献   

Age and early metamorphic history of the Sanbagawa belt: Lu–Hf and P–T constraints from the Western Iratsu eclogite     

S. ENDO  S.WALLIS  T. HIRATA  R. ANCZKIEWICZ  J. PLATT  M. THIRLWALL  Y. ASAHARA 《Journal of Metamorphic Geology》2009,27(5):371-384

Two distinct age estimates for eclogite-facies metamorphism in the Sanbagawa belt have been proposed: (i) c.  120–110 Ma based on a zircon SHRIMP age for the Western Iratsu unit and (ii) c.  88–89 Ma based on a garnet–omphacite Lu–Hf isochron age from the Seba and Kotsu eclogite units. Despite the contrasting estimates of formation ages, petrological studies suggest the formation conditions of the Western Iratsu unit are indistinguishable from those of the other two units—all ∼20 kbar and 600–650 °C. Studies of the associated geological structures suggest the Seba and Western Iratsu units are parts of a larger semi-continuous eclogite unit. A combination of geochronological and petrological studies for the Western Iratsu eclogite offers a resolution to this discrepancy in age estimates. New Lu–Hf dating for the Western Iratsu eclogite yields an age of 115.9 ± 0.5 Ma that is compatible with the zircon SHRIMP age. However, petrological studies show that there was significant garnet growth in the Western Iratsu eclogite before eclogite facies metamorphism, and the early core growth is associated with a strong concentration of Lu. Pre-eclogite facies garnet (Grt1) includes epidote–amphibolite facies parageneses equilibrated at 550–650 °C and ∼10 kbar, and this is overgrown by prograde eclogite facies garnet (Grt2). The Lu–Hf age of c.  116 Ma is strongly skewed to the isotopic composition of Grt1 and is interpreted to reflect the age of the pre-eclogite phase. The considerable time gap ( c.  27 Myr) between the two Lu–Hf ages suggests they may be related to separate tectonic events or distinct phases in the evolution of the Sanbagawa subduction zone.  相似文献   

Observational constraints on the radio and γ-ray emission regions of PSR B1055−52     

H. G. Wang  G. J. Qiao  R. X. Xu  Y. Liu 《Monthly notices of the Royal Astronomical Society》2006,366(3):945-952

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