Sulfide-driven arsenic mobilization from arsenopyrite and black shale pyrite   总被引：1，自引：0，他引：1  

Wenyi Zhu  Nathan Yee  E. Danielle Rhine  John R. Reinfelder 《Geochimica et cosmochimica acta》2008,72(21):5243-5250

We examined the hypothesis that sulfide drives arsenic mobilization from pyritic black shale by a sulfide-arsenide exchange and oxidation reaction in which sulfide replaces arsenic in arsenopyrite forming pyrite, and arsenide (As−1) is concurrently oxidized to soluble arsenite (As+3). This hypothesis was tested in a series of sulfide-arsenide exchange experiments with arsenopyrite (FeAsS), homogenized black shale from the Newark Basin (Lockatong formation), and pyrite isolated from Newark Basin black shale incubated under oxic (21% O₂), hypoxic (2% O₂, 98% N₂), and anoxic (5% H₂, 95% N₂) conditions. The oxidation state of arsenic in Newark Basin black shale pyrite was determined using X-ray absorption-near edge structure spectroscopy (XANES). Incubation results show that sulfide (1 mM initial concentration) increases arsenic mobilization to the dissolved phase from all three solids under oxic and hypoxic, but not anoxic conditions. Indeed under oxic and hypoxic conditions, the presence of sulfide resulted in the mobilization in 48 h of 13-16 times more arsenic from arsenopyrite and 6-11 times more arsenic from isolated black shale pyrite than in sulfide-free controls. XANES results show that arsenic in Newark Basin black shale pyrite has the same oxidation state as that in FeAsS (−1) and thus extend the sulfide-arsenide exchange mechanism of arsenic mobilization to sedimentary rock, black shale pyrite. Biologically active incubations of whole black shale and its resident microorganisms under sulfate reducing conditions resulted in sevenfold higher mobilization of soluble arsenic than sterile controls. Taken together, our results indicate that sulfide-driven arsenic mobilization would be most important under conditions of redox disequilibrium, such as when sulfate-reducing bacteria release sulfide into oxic groundwater, and that microbial sulfide production is expected to enhance arsenic mobilization in sedimentary rock aquifers with major pyrite-bearing, black shale formations.  相似文献   

Crustal structure of the Rhenish Massif: results of deep seismic reflection lines Dekorp 2-North and 2-North-Q   总被引：1，自引：1，他引：0  

Prof. Dr. W. Franke  Prof. Dr. R. K. Bortfeld  Dr. M. Brix  Dr. G. Drozdzewski  Prof. Dr. H. J. Dürbaum  Prof. Dr. P. Giese  Dr. W. Janoth  Dr. H. Jödicke  Chr Reichert Dipl.-Geophys.  Dr. A. Scherp  J. Schmoll Dipl.-Geophys.  R. Thomas Dipl.-Geophys.  Dr. M. Thünker  Prof. Dr. K. Weber  Dr. M. G. Wiesner  Prof. Dr. H. K. Wong 《International Journal of Earth Sciences》1990,79(3):523-566

The reflection seismic line DEKORP 2-N reveals an almost complete cross section through the Rhenohercynian Zone, the most external part of the Variscan orogen in Europe.The northern part of DEKORP 2-N and a NE-directed branch (2-N-Q) reveal the Cretaceous of the Münsterland basin and the underlying folded Palaeozoic rocks. The northward decreasing intensity of folding is depicted in great detail by the highly reflective Late Carboniferous coal-measures and deeper reflections down to the level of the Givetian/Frasnian shallow-water carbonates.In the Devonian and older rocks of the Rhenish Massif, bedding is only represented by relatively weak, short and irregular reflections. These are truncated by stronger, southward dipping reflections, which exhibit the listric curvature and flat/ramp geometry characteristic of faults. In the northern part of the section, the thrusts appear to be blind. From the Ebbe Anticline southwards, prominent reflections can be correlated with important thrust faults known from the surface, such as the Ebbe-, Siegen-, Müsen- and Sackpfeife- Thrusts, as well as further important thrust faults in the Lahn- and Dill Synclines. The basal thrust of the extremely thin-skinned Giessen Nappe is only recognizable for a very short distance.At depth, the thrusts flatten out in a relatively transparent zone between 3–5 s TWT, with strongly reflective bands at its bottom and top. The transparent zone might correlate with a high-conductivity layer detected in a magnetotelluric survey; it represents either graphitic metapelites or a zone with an interconnected, brine-filled pore space. The seismic record relates either to lithological differences, or to rheological boundaries.The lower crust in the north is characterized by a relatively transparent zone, which wedges out towards south under the northern margin of the Siegen Anticline. Comparisons with a similar feature in the ECORS profile »Nord de la France« suggest that the transparent zones in both sections correspond to a pre-Palaeozoic basement, such as it underlies the Brabant Massif. Further south, the lower crust is increasingly reflective.The curvilinear, thrust-related reflections are cut by a conjugate set of much weaker, N- and S-dipping reflectors indicating a later deformation with pure shear. Displacement of some marker reflections suggests late- or post-Variscan compression.In an alternative interpretation, these straight and weak reflections represent the only thrust faults, while the curvilinear elements might relate to bedding.A southward rise of the Moho from approx. 11 to 8.5 s TWT is probably due to Tertiary rifting.

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Zusammenfassung Das reflexionsseismische Profil DEKORP 2-N stellt einen fast vollständigen Querschnitt durch das Rhenohercynikum dar.Der nördliche Teil des Profiles 2-N sowie ein SW/NE-verlaufender Abzweig (2-N-Q) zeigen die Transgression der Münsterländer Kreide und das unterlagernde gefaltete Paläozoikum. Schichtgebundene Reflektoren (flözführendes Karbon, devonischer Massenkalk) bilden das Ausklingen der variscischen Faltung nach NW detailliert ab.In den devonischen und vordevonischen Sedimenten des rechtsrheinischen Schiefergebirges erzeugt die Schichtung nur relativ schwache, kurze und unregelmäßige Reflexionen. Diese werden von stärkeren, südfallenden Reflektoren abgeschnitten, die aufgrund ihrer listrischen Krümmung und flat/ramp-Geometrie wahrscheinlich als Überschiebungen zu interpretieren sind. Im Nordteil des Schiefergebirges sind diese Überschiebungen offenbar blind, werden also nahe der Oberfläche durch Faltung kompensiert. Im Ebbe-Sattel und weiter südlich lassen sich die meisten der starken, südfallenden Reflektoren zweifelsfrei mit bekannten Großüberschiebungen korrelieren (Ebbe-, Siegen-, Müsen-, Sackpfeife-Ü, sowie weitere Überschiebungen in der Lahn- u. Dill-Mulde). Die Basisüberschiebung der Giessen-Decke wird nur teilweise abgebildet.Zur Tiefe hin zeigen die Überschiebungen ein zunehmend flacheres Einfallen, und verschwinden in einer relativ transparenten Zone zwischen 3 und 5 s TWT, die im Hangenden und Liegenden durch dünne, stark reflektive Zonen begrenzt ist. Diese transparente Zone entspricht möglicherweise einer Zone hoher integrierter Leitfähigkeit, die in einem begleitenden magnetotellurischen Experiment nachgewiesen worden ist; es handelt sich entweder um einen Graphit-führenden Phyllit-Horizont oder eine mächtigere permeable Zone mit Elektrolyt-gefülltem Porenraum. Die hochreflektiven Bänder über und unter der transparenten Zone entsprechen entweder lithologischen Kontrasten oder rheologischen Grenzen, die vermutlich von einer scherenden Verformung überprägt worden sind.Die Unterkruste im N-Teil des Profiles enthält einen relativ transparenten Bereich, der nach Süden hin unter dem Nordteil des Siegener Sattels keilförmig ausläuft. Ein ähnliches Bild zeigt der Nordteil des ECORS-Profiles »Nord de la France«. Die transparenten Bereiche beider Profile entsprechen wahrscheinlich einem prä-paläozoischen kristallinen Basement, das das Brabanter Massif unterlagert und sich rechtsrheinisch fortsetzt. Südlich des transparenten Keiles wird die Unterkruste zunehmend reflexionsreicher. Die listrisch gekrümmten, an Überschiebungen gebundenen Reflektoren werden von einem konjugierten System schwächerer, N- u. S-fallender Reflektoren abgeschnitten, die auf eine jüngere, bruchhafte Verformung durch reine Scherung hindeuten. Der Versatz einiger älterer Reflektoren deutet auf spät- oder postvariscische Kompression hin.In einer alternativen Interpretation werden nur diese jüngeren Reflektoren als Überschiebungen gedeutet; die älteren, gekrümmten Elemente müßten dann primären lithologischen Grenzen entsprechen.Die Moho steigt von ca. 11 s TWT im N auf 8.5 s TWT unter dem Taunus an. Die Krustenverdünnung im Süden geht wahrscheinlich auf Dehnung im Tertiär zurück.

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Résumé Le profil sismique par réflexion DEKORP-2-N représente une transversale quasiment complète à travers la zone rhénohercynienne. La partie septentrionale du DEKORP-2-N ainsi qu'une branche de direction SW-NE (2-N-Q) mettent en évidence la transgression du Crétacé du Münsterland sur le Paléozoïque sous-jacent plissé. Des réflecteurs liés à la stratification (à savoir: le Houiller et les calcaires de plate-forme dévoniens) illustrent de façon détaillée la diminution vers le nord de l'intensité du plissement varisque.Dans les sédiments dévoniens et pré-dévoniens du Massif Rhénan à l'est du Rhin, la stratification ne fournit que que des réflexions relativement faibles, courtes et irrégulières. Elles sont tronquées par des réflecteurs plus intenses, à pendage sud qui, en raison de leur courbure listrique et de leur géométrie en «flat/ramp», doivent être interprétés comme des chevauchements. Dans la partie septentrionale du Massif, ces chevauchements sont apparemment aveugles, c'est-à-dire qu'ils sont compensés, près de la surface, par le plissement. Dans l'anticlinal d'Ebbe, ainsi que plus au sud, la plupart des réflecteurs intenses à plongement sud peuvent être corrélés avec des chevauchements majeurs connus, tels ceux de Ebbe, Siegen, Müsen, Sackpfeife et d'autres encore dans les synclinaux de la Lahn et de la Dill. Le chevauchement basai de la nappe de Giessen n'est que partiellement représenté.Les chevauchements deviennent de plus en plus plats en profondeur pour disparaître dans une zone relativement transparente qui se situe entre 3–5 sec TWT. Celle-ci est prise en sandwich par des zones minces à forte réflectivité. La zone transparente correspond probablement à une zone de conductivité intégrée élevée dont l'existence a par ailleurs été démontrée dans un essai magnétotellurique mené parallèlement. Il s'agit soit d'un horizon phyllitique graphiteux, soit d'une zone perméable plus épaisse dont les pores sont remplis d'électrolyte. Les bandes à haute réflectivité au-dessus et en-dessous de la zone transparente correspondent soit à des contrastes lithologiques, soit à des limites rhéologiques probablement accentuées par la déformation cisaillante.La croûte inférieure dans la partie septentrionale du profil comporte un domaine relativement transparent qui s'amincit vers le S et se termine, en dessous de la partie nord de l'anticlinal de Siegen, en forme de coin. La partie nord du profil ECORS «Nord de la France» montre une image semblable.Les domaines transparents des deux profils correspondent vraisemblablement à un soubassement cristallin pré-paléozoïque qui est sousjacent au Paléozoïque du Massif du Brabant et se prolonge vers l'est au-delà du Rhin. Au sud du coin transparent, la réflectivité de la croûte inférieure va en augmentant. Les réflecteurs listriques liés à des chevauchements sont recoupés par un système conjugué de réflecteurs plus faibles à plongement nord et sud qui indiquent des failles plus récentes. Le déplacement de quelques réflecteurs plus anciens suggère l'effet d'une compression tardiou post-varisque.Dans une interprétation alternative, seuls ces réflecteurs plus récents sont considérés comme correspondant à des chevauchements. Dans ce cas, les éléments courbes plus anciens devraient représenter des limites lithologiques primaires.Le Moho s'élève à partir de 11 sec TWT environ au nord jusqu'à 8.5 sec TWT en-dessous du Taunus. L'amincissement crustal au sud résulterait du régime de distension survenu au Tertiaire.

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DEKORP 2 Nord. x-t- ray-tracing'a. 6,0 6,6 /, — 7,0 8,2 /. 6,25 /. 28 30 . , .

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Abbreviations MORB Mid-Ocean Ridge Basalt - TWT two-way travel time, seconds (s) - CMP common mid-point - VP vibration point - SNR signal to noise ratio  相似文献   

A comparison of three image-object methods for the multiscale analysis of landscape structure   总被引：4，自引：0，他引：4  

Geoffrey J. Hay  Thomas Blaschke  Danielle J. Marceau  Andr Bouchard 《ISPRS Journal of Photogrammetry and Remote Sensing》2003,57(5-6):327

Within the conceptual framework of Complex Systems, we discuss the importance and challenges in extracting and linking multiscale objects from high-resolution remote sensing imagery to improve the monitoring, modeling and management of complex landscapes. In particular, we emphasize that remote sensing data are a particular case of the modifiable areal unit problem (MAUP) and describe how image-objects provide a way to reduce this problem. We then hypothesize that multiscale analysis should be guided by the intrinsic scale of the dominant landscape objects composing a scene and describe three different multiscale image-processing techniques with the potential to achieve this. Each of these techniques, i.e., Fractal Net Evolution Approach (FNEA), Linear Scale-Space and Blob-Feature Detection (SS), and Multiscale Object-Specific Analysis (MOSA), facilitates the multiscale pattern analysis, exploration and hierarchical linking of image-objects based on methods that derive spatially explicit multiscale contextual information from a single resolution of remote sensing imagery. We then outline the weaknesses and strengths of each technique and provide strategies for their improvement.  相似文献   

Richtlinien zur stratigraphischen Nomenklatur     

Jürgen Remane&#;  Thierry Adatte  Jean-Pierre Berger  Reto Burkhalter  Stephan Dall&#;Agnolo  Danielle Decrouez  Hermann Fischer  Hanspeter Funk  Heinz Furrer  Hans-Rudolf Graf  Yves Gouffon  Werner Heckendorn  Wilfried Winkler 《Eclogae Geologicae Helvetiae》2005,98(3):385-405

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PCA and SVM as geo-computational methods for geological mapping in the southern of Tunisia,using ASTER remote sensing data set     

Anis Gasmi  Cécile Gomez  Hédi Zouari  Antoine Masse  Danielle Ducrot 《Arabian Journal of Geosciences》2016,9(20):753

The purpose of this study was to examine the efficiency of Advanced Space Borne Thermal Emission and Reflection Radiometer (ASTER) data in the discrimination of geological formations and the generation of geological map in the northern margin of the Tunisian desert. The nine ASTER bands covering the visible (VIS), near-infrared (NIR) and short-wave infrared (SWIR) spectral regions (wavelength range of 400–2500 nm) have been treated and analyzed. As a first step of data processing, crosstalk correction, resampling, orthorectification, atmospheric correction, and radiometric normalization have been applied to the ASTER radiance data. Then, to decrease the redundancy information in highly correlated bands, the principal component analysis (PCA) has been applied on the nine ASTER bands. The results of PCA allow the validation and the rectification of the lithological boundaries already published on the geologic map, and gives a new information for identifying new lithological units corresponding to superficial formations previously undiscovered. The application of a supervised classification on the principal components image using a support vector machine (SVM) algorithm shows good correlation with the reference geologic map. The overall classification accuracy is 73 % and the kappa coefficient equals to 0.71. The processing of ASTER remote sensing data set by PCA and SVM can be employed as an effective tool for geological mapping in arid regions.  相似文献   

Ecotoxicological evaluation of dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro State,Brazil) using bioassays with earthworms and collembolans     

Mariana Vezzone  Ricardo Cesar  Helena Polivanov  Aline Serrano  Danielle Siqueira  Leticia Abreu  Miriam Bianchi  Maria Elizabeth Correia  Zuleica Castilhos  Tácio de Campos 《Environmental Earth Sciences》2018,77(21):743

The toxicity and metal bioavailability were studied in dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro, RJ, Brazil) using acute and avoidance tests with Eisenia andrei, and reproduction tests with Folsomia candida. The sediment was mixed with an artificial soil, and two natural soils (ferralsol and chernosol—representative Brazilian tropical soils) to obtain the following doses: 1, 3, 6, 12, 18, 24 and 30%. Total metal concentrations were determined in the sediment to support the interpretation of ecotoxicological data. Metal concentrations in the mixtures were in agreement with the threshold limits established by Brazilian law. However, significant avoidance responses were found on doses ≥?3% and were the most sensitive endpoint. Earthworm mortality found in artificial soil mixtures (LC50?=?3.9) suggests higher toxicity levels than those obtained in ferralsol (LC50?=?7.6%) and chernosol (11.0%) treatments. Earthworm mortality, avoidance responses and collembolan reproduction levels found in ferralsol mixtures (LC50?=?9.2; avoidance EC50?=?2.3%; reproduction EC50?=?2.8%) were higher compared to chernosol treatments (LC50?=?11.0%; avoidance EC50?=?4.3%; reproduction EC50?=?4.9%). The reduction of toxicity levels in chernosol mixtures is probably due to the abundance of expansive clay minerals in chernosols with capacity of adsorbing metals and other xenobiotic substances from soil pore water, decreasing metal bioavailability. Finally, threshold limits defined by Brazilian legislation for soil quality and land disposal of dredged sediments are not sufficient to prevent noxious effects on soil fauna and should be complemented with a preliminary ecotoxicological evaluation.  相似文献   

Die Wurzel der Osning-Überschiebung und der Mechanismus herzynischer Inversionsstörungen in Mitteleuropa     

Dr. G. Drozdzewski 《International Journal of Earth Sciences》1988,77(1):127-141

Zusammenfassung Neuere Untersuchungen ergaben, daß die Osning-Überschiebung als flache Störung in der steilen südlichen Randverwerfung der Ibbenbürener Karbonscholle wurzelt. Die Karbonscholle selbst ist von fiedrig angeordneten Randbrüchen begrenzt, die offenbar Teil eines varistischen Osning-Lineamentes sind. Das tektonische Inventar der Karbonscholle und die Osning-Überschiebung im Deckgebirge des südlichen Vorlandes werden als Folge einer Einengung und Heraushebung der Scholle in der Oberkreide gesehen, wobei die fiedrige Anordnung der Randstörungen eine Umsetzung horizontaler Seitenverschiebungen in Vertikalbewegungen bewirkte. Es wird angenommen, daß die Osning-Überschiebung generell in einem steilen Tiefenbruch wurzelt. Die Osning-Zone und andere herzynisch streichende Bruchsysteme mit daran gebundenen Falten und Überschiebungen dürften ihre Ursache in konvergierenden Schollenbewegungen mit horizontalen Seitenverschiebungen haben.

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Recent investigations revealed that the Osning thrust originates as a low angle plane in the southern marginal fault of the Ibbenbüren Carboniferous block. The fault block itself is limited by steep faults, which are considered to be en echelon faults as part of the variscan Osning lineament.The structures of the fault block indicate a compression and uplift of the Ibbenbüren fault block by strike-slip movements at the en echelon Osning lineament. In connection with the uplift compressional and lateral shearing movements produced the south vergent Osning thrust within the overlaying strata. Thus, it is concluded, that the flat Osning thrust in their total extension originates in steep faults. It is further presumed that Osning Zone as well as other NW-SE striking fault systems connected with folds and thrusts in Middle Europe are caused by transpression.

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Résumé Des études récentes amènent à regarder le charriage de l'Osning comme un accident faiblement incliné qui s'enracine dans la faille redressée formant la bordure sud du bloc carbonifère d'Ibbenbüren. Le bloc carbonifère est lui-même limité par des failles marginales en échelons, considérées comme faisant partie du linéament hercynien de l'Osning. L'inventaire tectonique du bloc carbonifère et le charriage de l'Osning dans la couverture de l'avant-pays méridional sont interprétés comme les effets d'un raccourcissement et d'une montée du bloc pendant le Crétacé supérieur, la configuration des failles marginales en échelons étant responsable de la transformation des déplacements horizontaux en mouvements verticaux. On conclut que le charriage de l'Osning, dans son ensemble, s'enracine dans une fracture profonde à fort pendage. La zone de l'Osning ainsi que d'autres zones failleuses WNW-ESE d'Europe Centrale avec les plis et les charriages qui leur sont associés sont considérés comme le résultat de mouvements convergents de blocs liés à des décrochements.

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Geochemical comparison between minettes and kersantites from the Western European Hercynian orogen: trace element and PbSrNd isotope constraints on their origin     

Laurent Turpin  Danielle Velde  Guy Pinte   《Earth and Planetary Science Letters》1988,87(1-2)

Trace element and isotopic characteristics of late Carboniferous to early Permian minettes and kersantites have been determined. These lamprophyres have been sampled throughout the Western European Hercynian orogen, from Brittany to the west to Schwarzwald to the east. In spite of sharp petrological differences reflected by mineralogy and major element geochemistry, minettes and kersantites exhibit close identity with respect to trace element and isotopic features. These features comprise enrichment in incompatible elements, highCs/Rb and lowCe/Pb ratios, Ta and Ti relative depletion, high abundance in transition elements and highNi/Mg ratios. Pb isotope ratios are undistinguishable from those measured on Hercynian continental crust. Initial¹⁴³Nd/¹⁴⁴Nd ratios are between0.5120 (ε_i −5) and0.5122 (ε_i −1) for minettes and kersantites whereas initial⁸⁷Sr/⁸⁶Sr ratios vary between 0.7055–0.710 for minettes and 0.707–0.708 for kersantites. No simple mixing relations are visible on RbSr and SmNd isochron diagrams. The exceptional homogeneity of these geochemical characteristics along a 1000 km traverse does not allow for an hypothesis of enrichment through upper level assimilation and thus leads to propose that these rocks originated through melting of a mantle enriched by recycling of crustal material.  相似文献   

Building Temporal Topology in a GIS Database to Study the Land‐Use Changes in a Rural‐Urban Environment     

Danielle J. Marceau  Luc Guindon  Mireille Bruel  Claude Marois 《The Professional geographer》2001,53(4):546-558

This article addresses the issue of linking temporal and spatial information into a GIS database structure to investigate the land‐use changes in a rural‐urban region over a thirty‐five‐year period. More specifically, it describes the application of a programming package developed to build temporal topology in an historical land‐use GIS database to efficiently perform spatiotemporal queries. The program was created within the MapInfo environment using MapBasic language. Different types of information, such as the rate of change, the relationship between the change of land use and zoning regulations, and land‐use succession were extracted from the database. A user‐friendly interface was also developed to easily address spatiotemporal queries to the database. This approach represents a flexible and performing tool for scientists and planners who need to efficiently capture essential spatiotemporal information required for geographical inquiry and decision‐making.  相似文献   

Fighting Fire with Fire: Does a Policy of Broad-Scale Prescribed Burning Improve Community Safety?     

Danielle Clode  Mark A. Elgar 《社会与自然资源》2014,27(11):1192-1199

Wildfires cause enormous damage worldwide, particularly in Victoria, Australia, with growing populations in fire-prone ecosystems. Broad-scale prescribed burning is an established, yet controversial, wildfire management policy in Victoria and Australia. But does broad-scale prescribed burning reduce fire damage? The answer depends on how damage is measured. We propose that different perceptions about the efficacy of broad-scale prescribed burning derive from different disciplinary measures of damage (e.g., biodiversity, area burned, or fatalities). Although broad-scale prescribed burning reduces subsequent wildfire size, there is little evidence that it saves human lives and homes. Evidence suggests that small-scale fuel reduction may be more effective at saving lives. The prescribed burning debate might be better focused on what damage we wish to limit, and which measures are most effective at limiting this damage. In this context, the current policy focus on broad-scale prescribed burning targets may distract efforts from more effective lifesaving strategies.  相似文献