Chemical abundances determined from meteor spectra: I. Ratios of the main chemical elements     

Josep M. Trigo‐Rodriguez  Jordi Llorca  Jiri Borovi ka  Juan Fabregat 《Meteoritics & planetary science》2003,38(8):1283-1294

Abstract— Relative chemical abundances of 13 meteoroids were determined by averaging the composition of the radiating gas along the fireball path that originated during their penetration into the Earth's atmosphere. Mg, Fe, Ni, Cr, Mn, and Co abundances, relative to Si, are similar to those reported for CI and CM carbonaceous chondrites and interplanetary dust particles. In contrast, relative abundances of Ca and Ti in meteor spectra indicate that these elements suffer incomplete evaporation processes. The chemical composition of all meteoroids studied in this work differs from that of 1P/Halley dust.  相似文献   

The passivation of calcite by acid mine water. Column experiments with ferric sulfate and ferric chloride solutions at pH 2   总被引：2，自引：1，他引：1  

Josep M. Soler  Marco Boi  Jos Luis Mogolln  Jordi Cama  Carlos Ayora  Peter S. Nico  Nobumichi Tamura  Martin Kunz 《Applied Geochemistry》2008,23(12):3579-3588

Column experiments, simulating the behavior of passive treatment systems for acid mine drainage, have been performed. Acid solutions (HCl or H₂SO₄, pH 2), with initial concentrations of Fe(III) ranging from 250 to 1500 mg L⁻¹, were injected into column reactors packed with calcite grains at a constant flow rate. The composition of the solutions was monitored during the experiments. At the end of the experiments (passivation of the columns), the composition and structure of the solids were measured. The dissolution of calcite in the columns caused an increase in pH and the release of Ca into the solution, leading to the precipitation of gypsum and Fe–oxyhydroxysulfates (Fe(III)–SO₄–H⁺ solutions) or Fe–oxyhydroxychlorides (Fe(III)–Cl–H⁺ solutions). The columns worked as an efficient barrier for some time, increasing the pH of the circulating solutions from 2 to 6–7 and removing its metal content. However, after some time (several weeks, depending on the conditions), the columns became chemically inert. The results showed that passivation time increased with decreasing anion and metal content of the solutions. Gypsum was the phase responsible for the passivation of calcite in the experiments with Fe(III)–SO₄–H⁺ solutions. Schwertmannite and goethite appeared as the Fe(III) secondary phases in those experiments. Akaganeite was the phase responsible for the passivation of the system in the experiments with Fe(III)–Cl–H⁺ solutions.  相似文献   

Coupled hydrogeological and reactive transport modelling of the Simpevarp area (Sweden)     

Jorge Molinero  Juan R. Raposo  Juan M. Galíndez  David Arcos  Jordi Guimerá 《Applied Geochemistry》2008

The Simpevarp area is one of the alternative sites being considered for the deep geological disposal of high level radioactive waste in Sweden. In this paper, a coupled regional groundwater flow and reactive solute transport model of the Simpevarp area is presented that integrates current hydrogeological and hydrochemical data of the area. The model simulates the current hydrochemical pattern of the groundwater system in the area. To that aim, a conceptual hydrochemical model was developed in order to represent the dominant chemical processes. Groundwater flow conditions were reproduced by taking into account fluid-density-dependent groundwater flow and regional hydrogeologic boundary conditions. Reactive solute transport calculations were performed on the basis of the velocity field so obtained. The model was calibrated and sensitivity analyses were carried out in order to investigate the effects of heterogeneities of hydraulic conductivity in the subsurface medium. Results provided by the reactive transport model are in good agreement with much of the measured hydrochemical data. This paper emphasizes the appropriateness of the use of reactive solute transport models when water-rock interaction reactions are involved, and demonstrates what powerful tools they are for the interpretation of hydrogeological and hydrochemical data from site geological repository characterization programs, by providing a qualitative framework for data analysis and testing of conceptual assumptions in a process-oriented approach.  相似文献   

The spatial implications of the functional proximity deriving from air passenger flows between European metropolitan urban regions     

Malcolm C. Burns  Josep Roca Cladera  Montserrat Moix Bergadà 《GeoJournal》2008,71(1):37-52

Until recently the traditional spatial configuration of the European geography was based upon the core-periphery model. The ‘pentagon’, broadly defined as lying between London, Paris, Milan, Munich and Hamburg, was seen as the core area characterised by having the highest concentration of economic development in the European Union (EU), with the remainder of the European territory viewed as peripheral, albeit to varying degrees. In a number of cases such peripheral areas equated with clear regional disparities. The elaboration of the European Spatial Development Perspective (ESDP) (CEC, European spatial development perspective, towards balanced and sustainable development in the territory of the European Union, 1999) challenged this core-periphery model. European spatial planning policies, aimed at encouraging social and economic, and with ever increasing importance, territorial cohesion, seek amongst other aspects to encourage the development of a balanced and polycentric urban system. This paper adopts a network analysis approach to the analysis of air passenger flows between some 28 principal European metropolitan urban regions. The evaluation of these flows contributes to an enhanced comprehension of the spatial dynamics of the European metropolitan territory which goes beyond that deriving from the more standard analyses of the individual components of the urban system. Several indicators are used, deriving from gravitational modelling techniques, to analyse the complexity of the air passenger flows. A multidimensional scaling (MDS) technique is introduced in order to interpret and visualise the resulting spatial configuration and positioning of the different metropolitan centres within the conceptual European ‘space of air passenger flows’, thereby contrasting with the more traditional map-based geographical image of Europe, based upon Cartesian coordinates.

Malcolm C. BurnsEmail:

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Gas hydrate disturbance fabrics of southern Hydrate Ridge sediments (ODP Leg 204): Relationship with texture and physical properties   总被引：1，自引：0，他引：1  

Elena Piñero  Eulàlia Gràcia  Francisca Martínez-Ruiz  Juan Cruz Larrasoaña  Alexis Vizcaino  Gemma Ercilla 《Geo-Marine Letters》2007,27(2-4):279-288

Soupy and mousse-like fabrics are disturbance sedimentary features that result from the dissociation of gas hydrate, a process that releases water. During the core retrieval process, soupy and mousse-like fabrics are produced in the gas hydrate-bearing sediments due to changes in pressure and temperature conditions. Therefore, the identification of soupy and mousse-like fabrics can be used as a proxy for the presence of gas hydrate in addition to other evidence, such as pore water freshening or anomalously cool temperature. We present here grain-size results, mineralogical composition and magnetic susceptibility data of soupy and mousse-like samples from the southern Hydrate Ridge (Cascadia accretionary complex) acquired during Leg 204 of the Ocean Drilling Program. In order to study the relationship between sedimentary texture and the presence of gas hydrates, we have compared these results with the main textural and compositional data available from the same area. Most of the disturbed analyzed samples from the summit and the western flank of southern Hydrate Ridge show a mean grain size coarser than the average mean grain size of the hemipelagic samples from the same area. The depositional features of the sediments are not recognised due to disturbance. However, their granulometric statistical parameters and distribution curves, and magnetic susceptibility logs indicate that they correspond to a turbidite facies. These results suggest that gas hydrates in the southern Hydrate Ridge could form preferentially in coarser grain-size layers that could act as conduits feeding gas from below the BSR. Two samples from the uppermost metres near the seafloor at the summit of the southern Hydrate Ridge show a finer mean grain-size value than the average of hemipelagic samples. They were located where the highest amount of gas hydrates was detected, suggesting that in this area the availability of methane gas was high enough to generate gas hydrates, even within low-permeability layers. The mineralogical composition of the soupy and mousse-like sediments does not show any specific characteristic with respect to the other samples from the southern Hydrate Ridge.  相似文献   

红海湾水域溶解氧、pH值、盐度和营养盐分布特征及相互关系研究   总被引：10，自引：0，他引：10  

王小平  贾晓平  林钦  李纯厚  甘居利  蔡文贵  王增焕  吕晓瑜 《海洋通报》1999,18(5):35-40

通过１９９８年６月对广东省红海湾海水养殖水域环境因子的调查,阐述了海水中溶解氧、盐度、ｐＨ值和营养盐的分布特征及其变化规律,并讨论了它们之间的相互关系,结果表明,溶解氧及海水ｐＨ值随温度由北（除１５￣１７号站）向南（除６号站）增高而增高。同时证实了光合作用是导致溶解氧含量和ｐＨ值增高的主要原因。而营养盐与盐度呈密度的负相关,浮游植物总量随营养盐由北向南降低而明显增高。  相似文献   

Asteroid “clans”: Super-families or multiple events?     

Alberto Cellino  Vincenzo Zappalà 《Celestial Mechanics and Dynamical Astronomy》1993,57(1-2):37-47

Among the recently determined asteroid families (Zappala' et al., 1992) a number of very large clusterings are recognized. Some of them agglomerate few families previously identified as single groupings. In most cases, the new big families (called clans) seem to be composed by different sub-clusterings connected each other by very narrow bridges. In the present paper we analyze their possible origin and evolution: a primordial single event followed by subsequent collisions of the fragments, a super-catastrophic original impact or different collisional events overlapping by chance.  相似文献   

The rotations of 128 Nemesis and 393 Lampetia: The longest known periods to date     

F. Scaltriti  V. Zappalà  H.J. Schober 《Icarus》1979,37(1):133-141

Extensive photoelectric lightcurves of the asteroids 128 Nemesis and 393 Lampetia show for both objects extremely long rotational periods, the longest known to date for minor planets. For 393 Lampetia the combined results suggest with high probability a period of 38.7 hr with a maximal amplitude of 0.14 mag; a double-wave characteristic of the lightcurve must be assumed. For 128 Nemesis the complete double-wave lightcurve was observed and a period of 39.0 hr with a total amplitude of only 0.10 mag was deduced. Observations of 128 Nemesis confirm without doubt the presence of small-scale features of amplitude 0.01 to 0.02 mag, corresponding to small topographic features of about 15 km in height and width on the surface.  相似文献   

Photoelectric lightcurve and period of rotation of the asteroid 182 Elsa     

A.W. Harris  J.W. Young  F. Scaltriti  V. Zappalà 《Icarus》1980,41(2):316-317

Photoelectric observations on five consecutive nights yield a period of rotation of 80 ± 2 hr with an amplitude of 0.7 magnitude for 182 Elsa, making it the longest period of rotation known to date. 182 Elsa is classed as an S object with a diameter of 48 km.  相似文献   

Strömgren photometry of a-stars: A test of physical parameter determination     

J. Torra  F. Figueras  C. Jordi  G. Rosselló 《Astrophysics and Space Science》1990,170(1-2):251-255

By use of known published values forT _eff, logg, andM _v, a check on our procedure for determining the physical parameters of A v-type stars from Strömgren photometry has been performed. External errors for our calculated physical parameters have been obtained.Paper presented at the 11th European Regional Astronomical Meetings of the IAU on New Windows to the Universe, held 3–8 July, 1989, Tenerife, Canary Islands, Spain.  相似文献