Sm−Nd and Pb isotopic study of mafic rocks associated with early Proterozoic continental rifting: the Peröpohja schist belt in northern Finland     

Hannu Huhma  Robert A. Cliff  Vesa Perttunen  Matti Sakko 《Contributions to Mineralogy and Petrology》1990,104(3):369-379

The Peräpohja schist belt in northern Finland rests unconformably on Archaean granitoids, and marks the early stages of Proterozoic crustal evolution in the Fennoscandian (Baltic) shield. 2440 Ma old layered mafic intrusions predate the supracrustal , and ca. 2200 Ma old sills of the gabbro-wehrlite association intrude the lowest quartzites and volcanics (Runkaus) of the sequence. The Sm-Nd mineral isochron of the Penikat layered intrusion gives an age of 2410±64 Ma. The initial _Nd-values of the Penikat intrusion (_Nd(2440) = –1.6) and the Runkausvaara sill (_Nd(2200) 0) suggest that these mafic magmas were contaminated by older crustal material. The Sm-Nd and Pb isotopic results on the 2.44–2.2 Ga old Runkaus volcanics indicate mobility of Pb, fractionation of Sm/Nd during late greenschist facies metamorphism, and crustal contamination. The Pb-Pb data provide an age of 1972±80 Ma with a high initial ²⁰⁷Pb/²⁰⁴Pb ratio (₁ = 8.49), while scattered Sm-Nd data result in an imprecise age of 2330±180 Ma, with an initial _Nd-value of about zero. Secondary titanite gives an U-Pb age of ca. 2250 Ma. The Jouttiaapa basalts, in contrast, ascended from the mantle without interaction with older crust. These LREE depleted tholeiites mark a break in continental sedimentation, and yield a Sm-Nd age of 2090±70 Ma. Their initial _Nd = + 4.2 ±0.5 implies that the subcontinental early Proterozoic mantle had been depleted in LREE for a long period of time. The first lava flows are strongly depleted in LREE, suggesting that their source was significantly more depleted than the source of mid-ocean ridge basalts today.  相似文献   

Flood seasonality across Scandinavia—Evidence of a shifting hydrograph?          下载免费PDF全文

Bettina Matti  Helen E. Dahlke  Bastien Dieppois  Damian M. Lawler  Steve W. Lyon 《水文研究》2017,31(24):4354-4370

Fluvial flood events have substantial impacts on humans, both socially and economically, as well as on ecosystems (e.g., hydroecology and pollutant transport). Concurrent with climate change, the seasonality of flooding in cold environments is expected to shift from a snowmelt‐dominated to a rainfall‐dominated flow regime. This would have profound impacts on water management strategies, that is, flood risk mitigation, drinking water supply, and hydro power. In addition, cold climate hydrological systems exhibit complex interactions with catchment properties and large‐scale climate fluctuations making the manifestation of changes difficult to detect and predict. Understanding a possible change in flood seasonality and defining related key drivers therefore is essential to mitigate risk and to keep management strategies viable under a changing climate. This study explores changes in flood seasonality across near‐natural catchments in Scandinavia using circular statistics and trend tests. Results indicate strong seasonality in flooding for snowmelt‐dominated catchments with a single peak occurring in spring and early summer (March through June), whereas flood peaks are more equally distributed throughout the year for catchments located close to the Atlantic coast and in the south of the study area. Flood seasonality has changed over the past century seen as decreasing trends in summer maximum daily flows and increasing winter and spring maximum daily flows with 5–35% of the catchments showing significant changes at the 5% significance level. Seasonal mean daily flows corroborate those findings with higher percentages (5–60%) of the catchments showing statistically significant changes. Alterations in annual flood occurrence also point towards a shift in flow regime from snowmelt‐dominated to rainfall‐dominated with consistent changes towards earlier timing of the flood peak (significant for 25% of the catchments). Regionally consistent patterns suggest a first‐order climate control as well as a local second‐order catchment control, which causes inter‐seasonal variability in the streamflow response.  相似文献   

Atmospheric sulfur deposition and streamwater quality in Finland     

P. W. Lahermo  T. Tarvainen  J. -P. Tuovinen 《Environmental Geology》1994,24(2):90-98

The correlation between sulfate concentrations in Finnish headwater streams and atmospheric sulfate deposition has been studied by using data from the streamwater chemistry in August–September 1990 and computed S deposition from the anthropogenic emissions. The sulfate concentrations and acidity in water are interpolated and smoothed into a deposition model grid. These data are compared with geological and pedogeochemical (glacial till) background information. The areas where the streamwater SO₄ concentrations are mainly controlled by either anthropogenic S deposition or sulfur in till is estimated by applying the fuzzy Gustafsson-Kessel algorithm, which provides a soft clustering suitable for overlapping control factors. Residual areas can be well explained by the SO₄-rich Littorina clay deposits. The higher overall background SO₄ concentrations in streams in south Finland compared with central and northern Finland are an indisputable consequence of the heavier S deposition load in the south. However, anthropogenic sulfur deposition has a clear correlation with the sulfates in streamwaters only in northeastern Lapland impacted by the large industrial emissions in the Kola Peninsula. The secondary sulfide and sulfate minerals of marine Littorina sediments are dominating sources in the broad coastal belts, as are the primary sulfide minerals locally in the Pori-Vammala area, at the eastern end of the main sulfide ore belt between Lake Ladoga and the Gulf of Bothnia, in the Outokumpu area, and in the Peräpohja and central Lapland schist belts. Consequently, in addition to the anthropogenic deposition, there are natural sources of sulfur which cause acidity of streamwaters.  相似文献   

Evaluation of drilling priorities using lead isotopes at the Lady Loretta lead-zinc-silver deposit, Australia     

Matti Vaasjoki  Brian L. Gulson 《Journal of Geochemical Exploration》1985,24(3):305-316

The weathered surface expression of the Lady Loretta lead-zinc-silver deposit outcrops almost continuously over a distance of about 4 km. Lead isotope ratios have been determined for samples, some of which contain > 4000 ppm Pb, from geochemically anomalous areas in order to assign drilling priorities to the anomalies.Twelve of the 43 samples analyzed contain isotopically homogeneous lead with ratios (²⁰⁷Pb/²⁰⁶Pb 0.9532–0.9549) similar to the expected targets for major ore deposits in the Mount Isa-McArthur River metallogenic province (²⁰⁷Pb/²⁰⁶Pb 0.955–0.962). Three main zones of interest can be outlined on the basis of lead isotopic data. The top priority is assigned to a 100-m-long section of the ironstone which coincides with the known outcrop of the ore. Lower priority for drilling is given to the two other zones which outcrop over smaller areas and have more radiogenic lead in their immediate surroundings. Several samples with anomalously high lead contents (> 1000 ppm) contain more radiogenic lead (²⁰⁷Pb/²⁰⁶Pb < 0.950) which was most likely derived from the weathering country rocks by supergene leaching and redeposition. Of the 22 samples containing ≥ 380 ppm Pb, lead isotopic analyses would have reduced the number deserving further attention to 10. Lead isotopic analyses in the early stages of exploration could have assisted in minimizing exploration expenditure at Lady Loretta.  相似文献   

Lithology and trace-metal content in till in the kuhmo granite-greenstone terrain, eastern Finland     

Matti Saarnisto  Kalle Taipale 《Journal of Geochemical Exploration》1985,24(3):317-336

Rocks of the Archaean Kuhmo greenstone belt and the fine fraction (− 63 μm) of 236 till samples were analysed for Co, Cr, Cu, Mn, Ni, Pb, Zn and Fe mainly with the AAS method. The influence of bedrock upon the lithology and geochemistry of till is clear, and can be seen immediately at the proximal contact. Expected trace-metal contents for the fine fraction of till were calculated using the average metal contents of the rock types and the proportions of these rock types in the till (2–6 cm pebbles). The expected values were then compared with the measured values in the fine fraction of till at the same locality. This approach seems effective for lithological comparison between various grain-size fractions of till.In general, the measured metal contents are clearly lower than expected. This indicates that the proportion of the greenstone material in the fine fraction of the till is smaller than in the coarse fraction. Correlations between measured and expected values of individual trace metals as well as their correlation with the different rock types are low, in most cases indicating inconsistent variation in the lithology of the coarse and fine fraction of the till. Good positive correlations between the number of pebbles of mafic metavolcanics and contents of Cu, Co, Mn and Fe in the fine fraction of till show that the influence of these rocks on the trace-element geochemistry of the tills in the study area is most significant as might be expected.  相似文献   

Mode of occurrence of Cu and Zn in till over three mineralized areas in Finland     

Maria Nikkarinen  Eeva Kallio  Pekka Lestinen  Matti Ayrs 《Journal of Geochemical Exploration》1984,21(1-3)

The variation of Cu and Zn contents with grain size was studied in the size fractions: 2000-500 μm, 500-64 μm, 64-2 μm and minus 2 μm. The fixation to different minerals was investigated in the 500-64 μm and minus 64 μm fractions with microscope, microprobe, electron microscope and X-ray diffraction after heavy-liquid separation.The distribution of Cu and Zn between the four size fractions is very similar in all target areas. The contents tend to be highest in the minus 2 μm fraction, and to decrease with increasing grain size except for an increase in the coarsest material. This feature is typical in mineralized areas with till having anomalously high Cu and Zn contents.The anomalous Cu and Zn in the till of Talvivaara are mainly fixed to chalcopyrite and sphalerite, respectively, which indicates that the main part of the material originates from fresh bedrock and that postglacial alterations are slight. In the till of Outokumpu and Maaselkä sulphides are rare. We assume that in Outokumpu the reason for this is the postglacial weathering of sulphides and that in Maaselkä a great deal of till derives from highly weathered, sulphide-poor, preglacial regolith. In both target areas Cu in till seems to fix to limonite and also to clay minerals, particularly in Maaselkä. Zinc seems mainly to be hosted by limonite in Outokumpu.  相似文献   

The chemistry of bottled mineral and spring waters from Norway,Sweden, Finland and Iceland     

Björn S. Frengstad  Kaj Lax  Timo Tarvainen  Øystein Jæger  Börge J. Wigum 《Journal of Geochemical Exploration》2010

Twenty-two bottled mineral and spring waters from Norway, Sweden, Finland and Iceland have been analysed for 71 inorganic chemical parameters with low detection limits as a subset of a large European survey of bottled groundwater chemistry (N = 884). The Nordic bottled groundwaters comprise mainly Ca–Na–HCO₃–Cl water types, but more distinct Ca–HCO₃, Na HCO₃ and Na–Cl water types are also offered. The distributions for most elements fall between groundwater from Fennoscandian Quaternary unconsolidated aquifers and groundwater from Norwegian crystalline bedrock boreholes. Treated tap waters have slightly lower median values for many parameters, but elements associated with plumbing have significantly higher concentrations in tap waters than in bottled waters. The small dataset is able to show that excessive fluoride and uranium contents are potential drinking water problems in Fennoscandia. Nitrate and arsenic displayed low to moderate concentrations, but the number of samples from Finland and Northern Sweden was too low to detect that elevated concentrations of arsenic occur in bedrock boreholes in some regions. The data shows clearly that water sold in plastic bottles is contaminated with antimony. Antimony is toxic and suspected to be carcinogenic, but the levels are well below the EU drinking water limit. The study does not provide any health-based arguments for buying bottled mineral and spring waters for those who are served with drinking water from public waterworks. Drinking water from crystalline bedrock aquifers should be analysed. In case of elevated concentrations of fluoride, uranium or arsenic, most bottled waters, but not all, will be better alternatives when treatment of the well water is not practicable.  相似文献   

Geochemical studies on urban soil from two sampling depths in Tampere Central Region,Finland   总被引：1，自引：0，他引：1  

Jaana Jarva  Rolf Tore Ottesen  Timo Tarvainen 《Environmental Earth Sciences》2014,71(11):4783-4799

Preliminary geochemical mapping was carried out within urban areas in Tampere Central Region, Finland, to gain a better understanding of element concentrations in urban soil and to provide information on baselines in soil within urban centres for soil contamination assessment purposes. The soil samples were taken from central city parks, day-care centres and school yards, and residential areas. Various sampling depths have generally been used in urban geochemical surveys. The aim of this study was to compare the results from two commonly used sample types taken from the same sites in urban soil: single samples of minerogenic topsoil from the 0–25 cm layer and composite samples of minerogenic topsoil from a depth of 0–2 cm. The concentrations of most of the studied trace elements showed a significant correlation between samples from 0 to 2 and 0 to 25 cm, but element concentrations differed between the two studied sample depths. For most of the studied elements, the median concentrations were higher in the 0–25 cm samples, but anomalous concentrations were more often found in the 0–2 cm samples. Some elements had elevated concentrations when compared with the Finnish guideline values for soil contamination assessment. This study did not conclusively establish whether a sampling depth of 0–2 or 0–25 cm should be recommended for similar studies in the future. Selection of the sampling depth in geochemical studies greatly depends on the aim of the project. In order to determine the upper limits of geochemical baseline variation, the deeper sampling depth appears to be more feasible. However, for the preliminary health risk assessment of areas with sensitive land uses, e.g. children’s playgrounds, samples from 0–2 cm depth are considered informative. Such samples may also be used to indicate local sources of dusting creating site-specific hotspots of potentially harmful elements in urban topsoil.  相似文献   

Characterizing changes in the sedimentary environment of a varved lake sediment record in southern central Finland around 8000 cal. yr BP     

Antti E. K. Ojala  Atko Heinsalu  Tommi Kauppila  Teija Alenius  Matti Saarnisto 《第四纪科学杂志》2008,23(8):765-775

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Palaeoecological evidence of changes in vegetation and climate during the Holocene in the pre‐Polar Urals,northeast European Russia     

Seija Kultti  Minna Vliranta  Kaarina Sarmaja‐Korjonen  Nadia Solovieva  Tarmo Virtanen  Tommi Kauppila  Matti Eronen 《第四纪科学杂志》2003,18(6):503-520

This study investigated Holocene tree‐line history and climatic change in the pre‐Polar Urals, northeast European Russia. A sediment core from Mezhgornoe Lake situated at the present‐day alpine tree‐line was studied for pollen, plant macrofossils, Cladocera and diatoms. A peat section from Vangyr Mire in the nearby mixed mountain taiga zone was analysed for pollen. The results suggest that the study area experienced a climatic optimum in the early Holocene and that summer temperatures were at least 2°C warmer than today. Tree birch immigrated to the Mezhgornoe Lake area at the onset of the Holocene. Mixed spruce forests followed at ca. 9500–9000 ¹⁴C yr BP. Climate was moist and the water level of Mezhgornoe Lake rose rapidly. The hypsithermal phase lasted until ca. 5500–4500 ¹⁴C yr BP, after which the mixed forest withdrew from the Mezhgornoe catchment as a result of the climate cooling. The gradual altitudinal downward shift of vegetation zones resulted in the present situation, with larch forming the tree‐line. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献