Early solar system aqueous activity: K isotope evidence from Allende     

Yun Jiang  Piers Koefoed  Olga Pravdivtseva  Heng Chen  Chun‐Hui Li  Fang Huang  Li‐Ping Qin  Jia Liu  Kun Wang 《Meteoritics & planetary science》2021,56(1):61-76

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.  相似文献   

地理试题透视六大解题思维——以浙江省选考试题为例     

杨明 《地理教学》2020,(1):52-55,39

思维是指人脑借助于语言对客观事物的概括和间接反应的过程,以感知为基础,又超越感知的界限,它探索与发现事物的内部本质联系和规律性,是认识过程的高级阶段。目前国内针对地理解题的思维研究相对较少,本文以浙江省历年选考地理试题为例,总结和提炼出六大解题思维,即:逆向思维、收支平衡思维、比较思维、发散思维、空间思维、辩证思维,旨在帮助学生掌握分析和解答地理问题的方法,从而有效提升高中地理学习和复习效果,增强学生学习地理的兴趣。同时在培养学生的地理解题思维过程中,落实地理学科核心素养的培育。  相似文献   

High‐resolution quantification of earthworm calcite granules from western European loess sequences reveals stadial–interstadial climatic variability during the Last Glacial     

Charlotte Prud'homme  Olivier Moine  Jerome Mathieu  Segolene Saulnier‐Copard  Pierre Antoine 《Boreas: An International Journal of Quaternary Research》2019,48(1):257-268

High concentrations of calcite fossil granules produced by earthworms (ECG) have been identified in most of the stratigraphical units along the loess‐palaeosol reference sequence of Nussloch (Germany). They are particularly abundant in interstadial brown soils and in tundra gley horizons, the latter reflecting short‐term phases of aggradation then degradation of permafrost. These granules are characterized by a radial crystalline structure produced in the earthworms by specific bio‐mineralization processes. In our study, we used this biological indicator combined with ¹⁴C and OSL dating, and sedimentological parameters to characterize millennial‐time scale climatic variations recorded in loess sequences. The approach is based on high‐resolution counts of ECG throughout a 17‐m‐thick loess sequence (332 samples). Strong increases in granule and mollusc concentrations suggest warmer climate conditions during palaeosol formation phases, associated with increasing biodiversity, biological activity and vegetation cover. Decreased granule concentrations occur within primary loess deposits, indicating a strong correlation with palaeoenvironmental conditions and demonstrating the reliability of ECG concentration variations as a new palaeoenvironmental proxy. Finally, this pattern is also recorded in loess sequences located about 600 km westward in northern France demonstrating the large‐scale validity of this new palaeoclimatic proxy.  相似文献   

Northwest Africa 11024—A heated and dehydrated unique carbonaceous (CM) chondrite     

Samuel Ebert  Addi Bischoff  Dennis Harries  Sarah Lentfort  Jean‐Alix Barrat  Andreas Pack  Jrme Gattacceca  Robbin Visser  Peter Schmid‐Beurmann  Stephan Kimpel 《Meteoritics & planetary science》2019,54(2):328-356

Based on the high abundance of fine‐grained material and its dark appearance, NWA 11024 was recognized as a CM chondrite, which is also confirmed by oxygen isotope measurements. But contrary to known CM chondrites, the typical phases indicating aqueous alteration (e.g., phyllosilicates, carbonates) are missing. Using multiple analytical techniques, this study reveals the differences and similarities to known CM chondrites and will discuss the possibility that NWA 11024 is the first type 3 CM chondrite. During the investigation, two texturally apparent tochilinite–cronstedtite intergrowths were identified within two thin sections. However, the former phyllosilicates were recrystallized to Fe‐rich olivine during a heating event without changing the textural appearance. A peak temperature of 400–600 °C is estimated, which is not high enough to destroy or recrystallize calcite grains. Thus, calcites were never constituents of the mineral paragenesis. Another remarkable feature of NWA 11024 is the occurrence of unknown clot‐like inclusions (UCLIs) within fine‐grained rims, which are unique in this clarity. Their density and S concentration are significantly higher than of the surrounding fine‐grained rim and UCLIs can be seen as primary objects that were not formed by secondary alteration processes inside the rims. Similarities to chondritic and cometary interplanetary dust particles suggest an ice‐rich first‐generation planetesimal for their origin. In the earliest evolution, NWA 11024 experienced the lowest degree of aqueous alteration of all known CM chondrites and subsequently, a heating event dehydrated the sample. We suggest to classify the meteorite NWA 11024 as the first type 3 CM chondrite similar to the classification of CV3 chondrites (like Allende) that could also have lost their matrix phyllosilicates by thermal dehydration.  相似文献   

Evaluation of Sludge Digester Effluent as Feeding Solution for the Enrichment of Anammox Bacteria     

&#x;pek elen‐Erdem 《洁净——土壤、空气、水》2020,48(3)

The aim of this study is to evaluate the feasibility of sludge digester effluent as feeding solution to enrich anaerobic ammonium oxidation (anammox) bacteria. The performance of the two parallel pilot scale‐upflow packed bed anammox reactors (UPBAn1 and UPBAn2) are examined in terms of the enrichment of anammox bacteria. The control experiment is set up conducting synthetic wastewater as feeding solution in the UPBAn1 reactor whereas, the sludge digester effluent is fed to the nitritation reactor and then the partially nitrated digester effluent to the UPBAn2 reactor. Anammox activities are evaluated by mass balances based on ammonium (NH₄⁺), nitrite (NO₂^?), and nitrate (NO₃^?) analysis and NRR. Microbial community of anammox bacteria is analyzed using real‐time polymerase chain reaction (PCR). The results demonstrate that UPBAn 1 and UPBAn2 reactors are successfully enriched on days 64 and 40 with NRRs of 19.54 and 19.43 g N m^?3 per day, respectively. This study reveals that both synthetic wastewater and digester effluent are suitable for the enrichment of anammox bacteria; however, digester effluent as feeding solution for enrichment of anammox bacteria based on the ease of process control and process stability is more advisable.  相似文献   

Clinoform architecture and along‐strike facies variability through an exhumed erosional to accretionary basin margin transition     

Miquel Poyatos‐Mor  George D. Jones  Rufus L. Brunt  Daniel E. Tek  David M. Hodgson  Stephen S. Flint 《Basin Research》2019,31(5):920-947

Exhumed basin margin‐scale clinothems provide important archives for understanding process interactions and reconstructing the physiography of sedimentary basins. However, studies of coeval shelf through slope to basin‐floor deposits are rarely documented, mainly due to outcrop or subsurface dataset limitations. Unit G from the Laingsburg depocentre (Karoo Basin, South Africa) is a rare example of a complete basin margin scale clinothem (>60 km long, 200 m‐high), with >10 km of depositional strike control, which allows a quasi‐3D study of a preserved shelf‐slope‐basin floor transition over a ca. 1,200 km² area. Sand‐prone, wave‐influenced topset deposits close to the shelf‐edge rollover zone can be physically mapped down dip for ca. 10 km as they thicken and transition into heterolithic foreset/slope deposits. These deposits progressively fine and thin over tens of km farther down dip into sand‐starved bottomset/basin‐floor deposits. Only a few km along strike, the coeval foreset/slope deposits are bypass‐dominated with incisional features interpreted as minor slope conduits/gullies. The margin here is steeper, more channelized and records a stepped profile with evidence of sand‐filled intraslope topography, a preserved base‐of‐slope transition zone and sand‐rich bottomset/basin‐floor deposits. Unit G is interpreted as part of a composite depositional sequence that records a change in basin margin style from an underlying incised slope with large sand‐rich basin‐floor fans to an overlying accretion‐dominated shelf with limited sand supply to the slope and basin floor. The change in margin style is accompanied with decreased clinoform height/slope and increased shelf width. This is interpreted to reflect a transition in subsidence style from regional sag, driven by dynamic topography/inherited basement configuration, to early foreland basin flexural loading. Results of this study caution against reconstructing basin margin successions from partial datasets without accounting for temporal and spatial physiographic changes, with potential implications on predictive basin evolution models.  相似文献   

Long‐term temporal and spatial patterns in bioeroding sponge distribution at the Abrolhos Bank,Brazil, Southwestern Atlantic     

Fernando Coreixas de Moraes  Fernanda Cervi  Cludia S. Karez  Leonardo T. Salgado  Rodrigo L. Moura  Gabriella A. Leal  Alex C. Bastos  Gilberto M. Amado‐Filho 《Marine Ecology》2019,40(3)

Bioeroding sponges belong to the most dominant bioeroders, significantly contributing to the erosion of coral reefs. Some species are tolerant or even benefit from environmental conditions such as ocean warming, acidification, and eutrophication. In consequence, increases in sponge bioerosion have been observed on some coral reefs over the last decades. The Abrolhos Bank is the largest coral reef system in the South Atlantic. It has been affected by sedimentation, eutrophication, overfishing, and climate change, mainly affecting coastal reefs, and at lesser intensity outer ones as well. This study aimed to describe spatial and temporal patterns in bioeroding sponge distribution in carbonate substrates in the Abrolhos Bank. Photo‐quadrats were used to compare bioeroding sponge abundance between two shallow reefs: a coastal, Pedra de Leste (PL), and an outer reef, Parcel dos Abrolhos (PAB). Each individual was delimitated over the substrate by determining the sponge surface through a line connecting the outermost papillae. The study was conducted over 6 years in 2008–2009 and 2013–2016. Four species of bioeroding sponges were identified: Cliona carteri Ridley, 1881, C. delitrix Pang, 1973, C. cf. schmidtii Ridley, 1881, and Siphonodictyon coralliphagum Rützler, 1971. The distribution and abundance of species varied between the inner and outer reefs and across the years, and displayed certain selectivity for the calcareous substrates recorded. Crustose coralline algae (CCA) were the main substrate excavated by the most abundant bioeroding species, C. carteri, and represented 70% of the substrate types occupied by this sponge (CCA, coral overgrown by CCA and plain coral). The highest abundance of bioeroding sponges observed in photo‐quadrats was 21.3 individuals/m² at the outer reefs (PAB) in 2014. The abundances or areal extents of bioeroding sponges were up to 10 times greater on the outer reefs than on the coastal ones, where sedimentation is higher and more strongly influenced by siliciclastic material. Moreover, a higher herbivorous fish biomass has been reported on outer reefs which could also influence the higher abundance of bioeroding sponges in outer reefs. During the study period of 6 years, an increase in bioeroding sponge abundance was observed at the outer reefs (PAB), with the sea surface temperature increase. As CCA have an important role in reefal cementation and carbonate production in the Abrolhos reefs, a bioerosion impact might be expected, in particular, on the outer reefs.  相似文献   

Zircon fission‐track ages from Newfoundland—A proxy for high geothermal gradients and exhumation before opening of the Central Atlantic Ocean     

Arne P. Willner  Stuart N. Thomson  Johannes Glodny  Hans‐Joachim Massonne  Rolf L. Romer  Cees R. van Staal  Alexandre Zagorevski 《地学学报》2019,31(1):1-10

Following Appalachian orogenesis, metamorphic rocks in central Newfoundland were exhumed and reburied under Tournaisian strata. New zircon fission‐track (ZFT) ages of metamorphic rocks below the Tournaisian unconformity yield post‐depositionally reset ages of 212–235 Ma indicating regional fluid‐absent reheating to at least ≥220°C. Post‐Tournaisian sedimentary thicknesses in surrounding basins show that burial alone cannot explain such temperatures, thus requiring that palaeo‐geothermal gradients increased to ≥30–40°C/km before final late Triassic accelerated cooling. We attribute these elevated palaeo‐geothermal gradients to localized thermal blanketing by insulating sediments overlying radiogenic high‐heat‐producing granitoids. Late Triassic rifting and magmatism before break up of Pangaea likely also contributed to elevated heat flow, as well as uplift, triggering late Triassic accelerated cooling and exhumation. Thermochronological ages of 240–200 Ma are seen throughout Atlantic Canada, and record rifting and basaltic magmatism on the conjugate margins of the Central Atlantic Ocean preceding the onset of oceanic spreading at ~190 Ma.  相似文献   

A comparison of the effectiveness of the roots of two grass species in reducing soil erosion on alluvial fans in south-east China     

Fangshi Jiang  Kaiwen He  Jiahui Lin  Hui Li  Zhenzhi Zhan  Jinshi Lin  Hongli Ge  Ming Kuang Wang  Yanhe Huang 《水文研究》2020,34(1):96-110

The effects of root systems on soil detachment by overland flow are closely related to vegetation types. The objective of this study was to quantify the effects of two gramineous roots (Paspalum mandiocanum with shallow roots and Pennisetum giganteum with deep roots) on soil detachment capacity, rill erodibility, and critical shear stress on alluvial fans of benggang in south-east China. A 4-m-long and 0.12-m-wide flume was used. Slope steepness ranged from 9% to 27%, and unit flow discharge ranged from 1.39 × 10⁻³ to 4.19 × 10⁻³ m² s⁻¹. The mean detachment capacities of P. mandiocanum and P. giganteum lands were 18% and 38% lower than that of bare land, respectively, and the effects of root on reducing soil detachment were mainly reflected in the 0- to 5-cm soil layer. The most important factors in characterizing soil detachment capacity were root length density and soil cohesion, and soil detachment capacity of the two grass lands could be estimated using flow shear stress, soil cohesion, and root length density (NSE = 0.90). With the increase in soil depth, rill erodibility increased, whereas shear stress decreased. The mean rill erodibilities of P. mandiocanum and P. giganteum lands were 81% and 61% as much as that of bare land, respectively. Additionally, rill erodibilities of the two grass lands could be estimated as an exponential function by root length density and soil cohesion (NSE = 0.88). The mean critical shear stress of P. mandiocanum and P. giganteum lands was 1.29 and 1.39 times that of bare land, respectively, and it could be estimated with a linear function by root length density (NSE = 0.76). This study demonstrated that planting of the two grasses P. mandiocanum and P. giganteum could effectively reduce soil detachment and enhance soil resistance to erosion on alluvial fans, with the deep roots of P. giganteum being more effective than the shallow roots of P. mandiocanum. The results are helpful for understanding the influencing mechanism of root systems on soil detachment process.  相似文献   

A comparison of methods to estimate groundwater recharge from bare soil based on data observed by a large-scale lysimeter     

Zaiyong Zhang  Wenke Wang  Chengcheng Gong  Ming Zhang 《水文研究》2020,34(13):2987-2999

Effectively estimating groundwater recharge is critical to manage water resources, especially in arid and semi-arid regions as impacted by intensive human activities and climate changes. Rare insights have been gained into groundwater recharge since direct observation is hard to carry out. Although several methods are currently available to estimate groundwater recharge, the estimated results may cover noticeable bias. The behaviours of different methods based on different conceptual frameworks and exhibiting different levels of complexity should be examined to estimate actual groundwater recharge. This study aims to assess the performance of four common methods to estimate groundwater recharge. For this end, large-scale lysimeters equipped with soil water content sensors and water table sensors were set up at a research site established in Guanzhong Basin of China. The data achieved by 1-year observation were employed to compare four estimation methods. As revealed from the results, the following findings are drawn. (a) Groundwater level fluctuation (GLF) method is simple, whereas its accuracy is determined by specific yield, and adopting a water balance method to estimate specific yield can considerably enhance the accuracy of GLF. (b) The calibrated numerical model can obtain the optimal result compared with the other methods, whereas long-term observation data are required for parameter calibration. (c) In the water balance method, the maximum entropy production (MEP) model and a practical method (estimating evaporation between two rainfall events) were used to calculate evaporation. As indicated by the results, water balance method combined with MEP is capable of obtaining more reliable results of groundwater recharge compared with the practical method. (d) With an analytical model based on linearized Richards' equation, accurate results can be achieved. What is more, the analytical model only needs the measurement of soil moisture near the surface. The limitation of this method is that it is difficult to determine the maximal water flux. The mentioned findings are of critical implications to the management and sustainable development of groundwater.  相似文献