Implications of Analcime Hydrothermally Formed from Na-alumino-borosilicate Glasses Containing Cs and Sr for the Stability of High-level Radioactive Waste Form     

Wook Sohn    Tetsuya Shoji  Hiroaki Kaneda  Teruaki Ishii 《Resource Geology》2003,53(1):51-59

Abstract. In order to know the behaviors of radioactive elements such as cesium and strontium during a hydrothermal alteration of borosilicate glass of radioactive waste, some alumino-borosilicate glasses belonging to the systems Na₂O-Al₂O₃-B₂O₃-SiO₂-SrO, Na₂O-Al₂O₃-B₂O₃-SiO₂-Cs₂O and Na₂O-Al₂-O₃-B₂O₃-SiO₂-SrO-Cs₂O have been treated hydrothermally at 200C under a vapor pressure of 1.54 MPa. The result shows that all glasses are changed into crystalline phases with running time up to 60 days, and that analcime-type zeolite is formed as a major product. The formed zeolite is shown to contain cesium and/or strontium. Considering the fact that natural zeolite occurs in wide physicochemical conditions including hydrothermal one, the analcime-type zeolite is expected to fix stably the radioactive elements in the disposal site. Since aluminum is necessary for the formation of the analcime-type zeolite, the waste glass should have aluminum as one of major components.  相似文献   

Co-located monogenetic eruptions ~200 kyr apart driven by tapping vertically separated mantle source regions,Chagwido, Jeju Island,Republic of Korea     

Marco Brenna  Károly Németh  Shane J. Cronin  Young Kwan Sohn  Ian E. M. Smith  Jan Wijbrans 《Bulletin of Volcanology》2015,77(5):1-17

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Geology of Tok Island,Korea: eruptive and depositional processes of a shoaling to emergent island volcano     

Y. K. Sohn 《Bulletin of Volcanology》1995,56(8):660-674

Detailed mapping of Tok Island, located in the middle of the East Sea (Sea of Japan), along with lithofacies analysis and K-Ar age determinations reveal that the island is of early to late Pliocene age and comprises eight rock units: Trachyte I, Unit P-I, Unit P-II, Trachyandesite (2.7±0.1 Ma), Unit P-III, Trachyte II (2.7±0.1 Ma), Trachyte III (2.5±0.1 Ma) and dikes in ascending stratigraphic order. Trachyte I is a mixture of coherent trachytic lavas and breccias that are interpreted to be subaqueous lavas and related hyaloclastites. Unit P-I comprises massive and inversely graded basaltic breccias which resulted from subaerial gain flows and subaqueous debris flows. A basalt clast from the unit, derived from below Trachyte I, has an age of 4.6±0.4 Ma. Unit P-II is composed of graded and stratified lapilli tuffs with the characteristics of proximal pyroclastic surge deposits. The Trachyandesite is a massive subaerial lava ponded in a volcano-tectonic depression, probably a summit crater. A pyroclastic sequence containing flattened scoria clasts (Unit P-III) and a small volume subaerial lava (Trachyte II) occur above the Trachyandesite, suggesting resumption of pyroclastic activity and lava effusion. Afterwards, shallow intrusion of magma occurred, producing Trachyte III and trachyte dikes.The eight rock units provide an example of the changing eruptive and depositional processes and resultant succession of lithofacies as a seamount builds up above sea level to form an island volcano: Trachyte I represents a wholly subaqueous and effusive stage; Units P-I and P-II represent Surtseyan and Taalian eruptive phases during an explosive transitional (subaqueous to emergent) stage; and the other rock units represent later subaerial effusive and explosive stages. Reconstruction of volcano morphology suggests that the island is a remnant of the south-western crater rim of a volcano the vent of which lies several hundred meters to the north-east.  相似文献   

Distinct sedimentary processes reflected in the isotopic signatures of dolomitic concretions in the Miocene Pohang Basin (southwestern East Sea)     

Boo-Keun Khim  Kyung Sik Woo  Young Kwan Sohn 《Journal of Asian Earth Sciences》2007,29(5-6):939-946

Dolomitic concretions in diatomaceous hemipelagic sediments of the Miocene Pohang Basin in the southwestern East Sea (Sea of Japan) preserve distinct signals of two independent sedimentary processes, which controlled the extents of isotopic compositions. Variable δ¹⁸O (−9.1‰ to +0.7‰) and high δ¹³C (+3.1‰ to +17.9‰) values suggest that the concretions formed in the methanogenic zone with alteration of the residual mid-Miocene seawater by volcanogenic sediments. Remarkable δ¹⁸O and δ¹³C values show a strong linear relationship, indicating that distinctly independent depositional processes operated during the formation of the concretions. The degree of methanogenesis was enhanced during rapid hemipelagic sedimentation of organic-rich particles, resulting in higher δ¹³C values, and the effect of volcaniclastics was diluted, maintaining the original properties of ambient mid-Miocene seawater. In contrast, lower δ¹⁸O and ⁸⁷Sr/⁸⁶Sr values characterize the effect of volcaniclastic sediments that were transported by intermittent gravity flows and interacted with mid-Miocene seawater. The input of volcaniclastic sediment probably degraded the role of methanogenesis by lowering the contents of organic matter and thereby decreased the δ¹³C values within the concretions. Isotopic signals recorded within the concretions highlight understanding of the depositional environment and evolution of the pore-water chemistry.  相似文献   

Seasonal prediction of June rainfall over South China: Model assessment and statistical downscaling     

Kun-Hui Ye  Chi-Yung Tam  Wen Zhou  Soo-Jin Sohn 《大气科学进展》2015,32(5):680-689

The performances of various dynamical models from the Asia-Pacific Economic Cooperation(APEC) Climate Center(APCC) multi-model ensemble(MME) in predicting station-scale rainfall in South China(SC) in June were evaluated.It was found that the MME mean of model hindcasts can skillfully predict the June rainfall anomaly averaged over the SC domain.This could be related to the MME's ability in capturing the observed linkages between SC rainfall and atmospheric large-scale circulation anomalies in the Indo-Pacific region.Further assessment of station-scale June rainfall prediction based on direct model output(DMO) over 97 stations in SC revealed that the MME mean outperforms each individual model.However,poor prediction abilities in some in-land and southeastern SC stations are apparent in the MME mean and in a number of models.In order to improve the performance at those stations with poor DMO prediction skill,a station-based statistical downscaling scheme was constructed and applied to the individual and MME mean hindcast runs.For several models,this scheme can outperform DMO at more than 30 stations,because it can tap into the abilities of the models in capturing the anomalous Indo-Paciric circulation to which SC rainfall is considerably sensitive.Therefore,enhanced rainfall prediction abilities in these models should make them more useful for disaster preparedness and mitigation purposes.  相似文献   

Partitioning of dioxins (PCDDs/Fs) in ambient air at urban residential locations     

Md. M. Rahman  Z.-H. Shon  C.-J. Ma  R. J. C. Brown  S. K. Pandey  C. G. Park  I. S. Bae  J. R. Sohn  H.-O. Yoon  K.-H. Kim 《International Journal of Environmental Science and Technology》2014,11(7):1897-1910

In this work, 17-polychlorinated dibenzo-p-dioxin/furan (PCDD/Fs) isomers were measured in ambient air at four urban sites in Seoul, Korea (from February to June 2009). The concentrations of their summed values (ΣPCDD/Fs) across all four sites ranged from 1,947 (271 WHO₀₅ TEQ) (Jong Ro) to 2,600 (349 WHO₀₅ TEQ) fg/m³ (Yang Jae) with a mean of 2,125 (± 317) fg/m³ (292 WHO₀₅ TEQ fg/m³). The sum values for the two isomer groups of ΣPCDD and ΣPCDF were 527 (30 WHO₀₅ TEQ) and 1,598 (263 WHO₀₅ TEQ) fg/m³, respectively. The concentration profile of individual species was dominated by the 2,3,4,7,8-PeCDF isomer, which contributed approximately 36 % of the ΣPCDD/Fs value. The observed temporal trends in PCDD/F concentrations were characterized by relative enhancement in the winter and spring. The relative contribution of different sources, when assessed by principal component analysis, is explained by the dominance of vehicular emissions along with coal (or gas) burning as the key source of ambient PCDD/Fs in the residential areas studied.  相似文献   

Double injection events of mafic magma into supersolidus Yucheon granites to produce two types of mafic enclaves in the Cretaceous Gyeongsang Basin,SE Korea     

Jong-Sun Kim  Moon Son  Byoung-Hoon Hwang  Ki-Cheol Shin  Hyeongseong Cho  Young Kwan Sohn 《Mineralogy and Petrology》2014,108(2):207-229

Petrographic and geochemical features of the Cretaceous Yucheon granites and their mafic microgranular/magmatic enclaves (MMEs), SE Korea, reveal that the MMEs originated from magma mixing. Mesoscopic and microscopic features indicate that mechanical mixing operated heterogeneously to produce the MMEs with a wide range of sizes and textures. Chemical compositions of amphibole, biotite, and plagioclase rims of both the MMEs and host granites are almost identical, indicating that chemical homogenization took place to some extent after the mechanical mixing. Plagioclase cores, however, have various compositions depending on the host rocks and/or sampling locations, suggesting their sluggish re-equilibration. The MMEs are divided into Type A (low TiO₂, very fine-grained, chilled margins) and Type B (high TiO₂, fine- to medium-grained, no chilled margins). The lower TiO₂ MMEs cooled more rapidly and interacted with granitic magma for a shorter period of time than the higher TiO₂ MMEs. Additionally, the former are less enriched in HREEs than the latter. Zoned plagioclase has two zones of increased An content. These features are indicative of double injection events of mafic magma. A previous model explains the magma mixing as resulting from the generation of a slab window due to Kula-Pacific ridge subduction. The model cannot, however, explain the eastward younging of the granites in Korea, necessitating a new, more elaborate model of Cretaceous geodynamics and magmatism in East Asia.  相似文献   

The influence of magma plumbing complexity on monogenetic eruptions,Jeju Island,Korea     

Marco Brenna  Shane J. Cronin  Károly Németh  Ian E. M. Smith  Young Kwan Sohn 《地学学报》2011,23(2):70-75

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Validating a rapid-update satellite precipitation analysis across telescoping space and time scales     

Francis Joseph Turk  Byung-Ju Sohn  Hyun-Jong Oh  Elizabeth E. Ebert  Vincenzo Levizzani  Eric A. Smith 《Meteorology and Atmospheric Physics》2009,105(1-2):99-108

In order to properly utilize remotely sensed precipitation estimates in hydrometeorological applications, knowledge of the accuracy of the estimates are needed. However, relatively few ground validation networks operate with the necessary spatial density and time-resolution required for validation of high-resolution precipitation products (HRPP) generated at fine space and time scales (e.g., hourly accumulations produced on a 0.25° spatial scale). In this article, we examine over-land validation statistics for an operationally designed, meteorological satellite-based global rainfall analysis that blends intermittent passive microwave-derived rainfall estimates aboard a variety of low Earth-orbiting satellite platforms with sub-hourly time sampling capabilities of visible and infrared imagers aboard operational geostationary platforms. The validation dataset is comprised of raingauge data collected from the dense, nearly homogeneous, 1-min reporting Automated Weather Station (network of the Korean Meteorological Administration during the June to August 2000 summer monsoon season. The space-time RMS error, mean bias, and correlation matrices were computed using various time windows for the gauge averaging, centered about the satellite observation time. For ±10 min time window, a correlation of 0.6 was achieved at 0.1° spatial scale by averaging more than 3 days; coarsening the spatial scale to 1.8° produced the same correlation by averaging over 1 h. Finer than approximately 24-h and 1° time and space scales, respectively, a rapid decay of the error statistics was obtained by trading-off either spatial or time resolution. Beyond a daily time scale, the blended estimates were nearly unbiased and with an RMS error of no worse than 1 mm day^?1.  相似文献   

Ternary forecast of heavy snowfall in the Honam area,Korea     

Keon Tae SOHN  Jeong Hyeong LEE  Young Seuk CHO 《大气科学进展》2009,26(2):327-332

The objective of this study is to improve the statistical modeling for the ternary forecast of heavy snowfall in the Honam area in Korea. The ternary forecast of heavy snowfall consists of one of three values, 0 for less than 50 mm, 1 for an advisory (50–150 mm), and 2 for a warning (more than 150 mm). For our study, the observed daily snow amounts and the numerical model outputs for 45 synoptic factors at 17 stations in the Honam area during 5 years (2001 to 2005) are used as observations and potential pre...  相似文献